The structure and modified properties of a self-dimerised Cu() inclusion complex in γ-cyclodextrins
Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF 6 units. Quan...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-04, Vol.52 (14), p.4475-448 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Hamaguchi, Tomohiko Ishikawa, Ryuta Mishima, Akio Hayami, Shinya Ohba, Masaaki Satoh, Minoru Kawata, Satoshi |
| description | Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
units. Quantum calculation reveals that
interfragment charge transfer
occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
" exhibit different properties.
Cu fragments in γ-cyclodextrins show different properties from those of unincluded fragments caused by the confinement and the interaction between Cu fragments. |
| doi_str_mv | 10.1039/d3dt00176h |
| format | Article |
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6
units. Quantum calculation reveals that
interfragment charge transfer
occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
" exhibit different properties.
Cu fragments in γ-cyclodextrins show different properties from those of unincluded fragments caused by the confinement and the interaction between Cu fragments.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt00176h</identifier><identifier>PMID: 36919758</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Charge transfer ; Cyclodextrins ; Inclusion complexes ; Molecular properties</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-04, Vol.52 (14), p.4475-448</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c332t-c480990962483ef5fec4d3a084b1c6aeaec4cace9d7730cdaab8fbcfd5aa36593</cites><orcidid>0000-0001-9268-3512 ; 0000-0001-8392-2382 ; 0000-0002-1279-6283 ; 0000-0002-3317-6067 ; 0000-0002-7615-6517</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36919758$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hamaguchi, Tomohiko</creatorcontrib><creatorcontrib>Ishikawa, Ryuta</creatorcontrib><creatorcontrib>Mishima, Akio</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Ohba, Masaaki</creatorcontrib><creatorcontrib>Satoh, Minoru</creatorcontrib><creatorcontrib>Kawata, Satoshi</creatorcontrib><title>The structure and modified properties of a self-dimerised Cu() inclusion complex in γ-cyclodextrins</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
units. Quantum calculation reveals that
interfragment charge transfer
occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
" exhibit different properties.
Cu fragments in γ-cyclodextrins show different properties from those of unincluded fragments caused by the confinement and the interaction between Cu fragments.</description><subject>Charge transfer</subject><subject>Cyclodextrins</subject><subject>Inclusion complexes</subject><subject>Molecular properties</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpd0ctKxDAUBuAgiveNeyXgZhSqubRNs5TxCoKbcV0yyQmToW3GpIWZ5_I9fCajoyO4yuV8nBz-IHRCyRUlXF4bbnpCqChnW2if5kJkkvF8e7Nn5R46iHFOCGOkYLtoj5eSSlFU-8hMZoBjHwbdDwGw6gxuvXHWgcGL4BcQegcRe4sVjtDYzLgWgoupPB5GF9h1uhmi8x3Wvl00sEw3-OM90yvdeAPLPrguHqEdq5oIxz_rIXq9v5uMH7Pnl4en8c1zpjlnfabzikhJZMnyioMtLOjccEWqfEp1qUCls1YapBGCE22UmlZ2qq0plOJlIfkhGq37psnfBoh93bqooWlUB36INROVYJSnJxI9_0fnfghdmi4pmRecCkmTulwrHXyMAWy9CK5VYVVTUn9lX9_y28l39o8Jn_20HKYtmA39DTuB0zUIUW-qf5_HPwHhX4rW</recordid><startdate>20230404</startdate><enddate>20230404</enddate><creator>Hamaguchi, Tomohiko</creator><creator>Ishikawa, Ryuta</creator><creator>Mishima, Akio</creator><creator>Hayami, Shinya</creator><creator>Ohba, Masaaki</creator><creator>Satoh, Minoru</creator><creator>Kawata, Satoshi</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9268-3512</orcidid><orcidid>https://orcid.org/0000-0001-8392-2382</orcidid><orcidid>https://orcid.org/0000-0002-1279-6283</orcidid><orcidid>https://orcid.org/0000-0002-3317-6067</orcidid><orcidid>https://orcid.org/0000-0002-7615-6517</orcidid></search><sort><creationdate>20230404</creationdate><title>The structure and modified properties of a self-dimerised Cu() inclusion complex in γ-cyclodextrins</title><author>Hamaguchi, Tomohiko ; Ishikawa, Ryuta ; Mishima, Akio ; Hayami, Shinya ; Ohba, Masaaki ; Satoh, Minoru ; Kawata, Satoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-c480990962483ef5fec4d3a084b1c6aeaec4cace9d7730cdaab8fbcfd5aa36593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Charge transfer</topic><topic>Cyclodextrins</topic><topic>Inclusion complexes</topic><topic>Molecular properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hamaguchi, Tomohiko</creatorcontrib><creatorcontrib>Ishikawa, Ryuta</creatorcontrib><creatorcontrib>Mishima, Akio</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Ohba, Masaaki</creatorcontrib><creatorcontrib>Satoh, Minoru</creatorcontrib><creatorcontrib>Kawata, Satoshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hamaguchi, Tomohiko</au><au>Ishikawa, Ryuta</au><au>Mishima, Akio</au><au>Hayami, Shinya</au><au>Ohba, Masaaki</au><au>Satoh, Minoru</au><au>Kawata, Satoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The structure and modified properties of a self-dimerised Cu() inclusion complex in γ-cyclodextrins</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-04-04</date><risdate>2023</risdate><volume>52</volume><issue>14</issue><spage>4475</spage><epage>448</epage><pages>4475-448</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
units. Quantum calculation reveals that
interfragment charge transfer
occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF
6
" exhibit different properties.
Cu fragments in γ-cyclodextrins show different properties from those of unincluded fragments caused by the confinement and the interaction between Cu fragments.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36919758</pmid><doi>10.1039/d3dt00176h</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-9268-3512</orcidid><orcidid>https://orcid.org/0000-0001-8392-2382</orcidid><orcidid>https://orcid.org/0000-0002-1279-6283</orcidid><orcidid>https://orcid.org/0000-0002-3317-6067</orcidid><orcidid>https://orcid.org/0000-0002-7615-6517</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-04, Vol.52 (14), p.4475-448 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Charge transfer Cyclodextrins Inclusion complexes Molecular properties |
| title | The structure and modified properties of a self-dimerised Cu() inclusion complex in γ-cyclodextrins |
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