Cluster size dependent coordination of formate to free manganese oxide clusters

The interaction of free manganese oxide clusters, Mn x O y + ( x = 1-9, y = 0-12), with formic acid was studied via infrared multiple-photon dissociation (IR-MPD) spectroscopy together with calculations using density functional theory (DFT). Clusters containing only one Mn atom, such as MnO 2 + and...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2023-11, Vol.25 (46), p.32166-32172
Hauptverfasser:	Lang, Sandra M, Bernhardt, Thorsten M, Bakker, Joost M, Barnett, Robert N, Landman, Uzi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelation Chemistry Clusters Configurations Coordination Density functional theory Formic acid Hydroxyl groups Infrared spectroscopy Manganese dioxide Manganese oxides Ring structures
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