2,7-Diazapyrenes: a brief review on synthetic strategies and application opportunities
2,7-Diazapyrenes are promising azaaromatic scaffolds with a unique structural geometry and supramolecular properties. This core moiety and its derivatives with some N -methyl cations like N -methyl-2,7,-diazapyrenium, and N , N ′-dimethyl-2,7-diazapyrenium attract special attention due to their chal...
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| Veröffentlicht in: | RSC advances 2022-03, Vol.12 (15), p.9323-9341 |
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| creator | Mukherjee, Anindita Akulov, Alexey A Santra, Sougata Varaksin, Mikhail V Kim, Grigory A Kopchuk, Dmitry S Taniya, Olga S Zyryanov, Grigory V Chupakhin, Oleg. N |
| description | 2,7-Diazapyrenes are promising azaaromatic scaffolds with a unique structural geometry and supramolecular properties. This core moiety and its derivatives with some
N
-methyl cations like
N
-methyl-2,7,-diazapyrenium, and
N
,
N
′-dimethyl-2,7-diazapyrenium attract special attention due to their challenging photophysical properties, especially in the context of interactions with DNA and some of its mononucleotides. This review focuses on the analysis of the main synthetic approaches to 2,7-diazapyrene and its functional derivatives employing various strategies under different reaction conditions. The opportunities of applications of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, DNA-bindings, in sensors, molecular electronics, supramolecular systems, and related areas are also highlighted.
This review discusses the synthetic routes for 2,7-diazapyrene derivatives and highlights the opportunities for application of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, in sensors and related areas. |
| doi_str_mv | 10.1039/d2ra00260d |
| format | Article |
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N
-methyl cations like
N
-methyl-2,7,-diazapyrenium, and
N
,
N
′-dimethyl-2,7-diazapyrenium attract special attention due to their challenging photophysical properties, especially in the context of interactions with DNA and some of its mononucleotides. This review focuses on the analysis of the main synthetic approaches to 2,7-diazapyrene and its functional derivatives employing various strategies under different reaction conditions. The opportunities of applications of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, DNA-bindings, in sensors, molecular electronics, supramolecular systems, and related areas are also highlighted.
This review discusses the synthetic routes for 2,7-diazapyrene derivatives and highlights the opportunities for application of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, in sensors and related areas.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d2ra00260d</identifier><identifier>PMID: 35424878</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemistry ; Molecular electronics</subject><ispartof>RSC advances, 2022-03, Vol.12 (15), p.9323-9341</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2022</rights><rights>This journal is © The Royal Society of Chemistry 2022 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-7a7bf0332abea32e0840f912caa6a6b7947a245bd2143c4dde0fb0f20370ad9f3</citedby><cites>FETCH-LOGICAL-c358t-7a7bf0332abea32e0840f912caa6a6b7947a245bd2143c4dde0fb0f20370ad9f3</cites><orcidid>0000-0002-4186-6105 ; 0000-0002-1672-2476 ; 0000-0003-3966-3728 ; 0000-0002-7997-3686</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985108/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985108/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35424878$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mukherjee, Anindita</creatorcontrib><creatorcontrib>Akulov, Alexey A</creatorcontrib><creatorcontrib>Santra, Sougata</creatorcontrib><creatorcontrib>Varaksin, Mikhail V</creatorcontrib><creatorcontrib>Kim, Grigory A</creatorcontrib><creatorcontrib>Kopchuk, Dmitry S</creatorcontrib><creatorcontrib>Taniya, Olga S</creatorcontrib><creatorcontrib>Zyryanov, Grigory V</creatorcontrib><creatorcontrib>Chupakhin, Oleg. N</creatorcontrib><title>2,7-Diazapyrenes: a brief review on synthetic strategies and application opportunities</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>2,7-Diazapyrenes are promising azaaromatic scaffolds with a unique structural geometry and supramolecular properties. This core moiety and its derivatives with some
N
-methyl cations like
N
-methyl-2,7,-diazapyrenium, and
N
,
N
′-dimethyl-2,7-diazapyrenium attract special attention due to their challenging photophysical properties, especially in the context of interactions with DNA and some of its mononucleotides. This review focuses on the analysis of the main synthetic approaches to 2,7-diazapyrene and its functional derivatives employing various strategies under different reaction conditions. The opportunities of applications of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, DNA-bindings, in sensors, molecular electronics, supramolecular systems, and related areas are also highlighted.
This review discusses the synthetic routes for 2,7-diazapyrene derivatives and highlights the opportunities for application of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, in sensors and related areas.</description><subject>Chemistry</subject><subject>Molecular electronics</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkc1rFTEUxYNYbKnduFcG3EhxNF-TybgQSp_aQkEQdRvuZO60KfOSMcm0PP96U199Vu8mF86Pw7k5hDxj9A2jons78AiUckWHR-SAU6lqTlX3-MG-T45SuqZlVMO4Yk_Ivmgkl7rVB-Q7f93WKwc_Yd5E9JjeVVD10eFYRbxxeFsFX6WNz1eYna1SjpDx0mGqwA8VzPPkLGRXoDDPIebFu1zUp2RvhCnh0f17SL59_PD19Ky--Pzp_PTkorai0bluoe1HKgSHHkFwpFrSsWPcAihQfdvJFrhs-oEzKawcBqRjT0dORUth6EZxSN5vfeelX-Ng0ZeAk5mjW0PcmADO_Kt4d2Uuw43RnW4Y1cXg1b1BDD8WTNmsXbI4TeAxLMnw8mdKN40WBX35H3odlujLeYWSolOC6a5Qx1vKxpBSxHEXhlFz15hZ8S8nvxtbFfjFw_g79E8_BXi-BWKyO_Vv5eIXu-ybyw</recordid><startdate>20220321</startdate><enddate>20220321</enddate><creator>Mukherjee, Anindita</creator><creator>Akulov, Alexey A</creator><creator>Santra, Sougata</creator><creator>Varaksin, Mikhail V</creator><creator>Kim, Grigory A</creator><creator>Kopchuk, Dmitry S</creator><creator>Taniya, Olga S</creator><creator>Zyryanov, Grigory V</creator><creator>Chupakhin, Oleg. N</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-4186-6105</orcidid><orcidid>https://orcid.org/0000-0002-1672-2476</orcidid><orcidid>https://orcid.org/0000-0003-3966-3728</orcidid><orcidid>https://orcid.org/0000-0002-7997-3686</orcidid></search><sort><creationdate>20220321</creationdate><title>2,7-Diazapyrenes: a brief review on synthetic strategies and application opportunities</title><author>Mukherjee, Anindita ; Akulov, Alexey A ; Santra, Sougata ; Varaksin, Mikhail V ; Kim, Grigory A ; Kopchuk, Dmitry S ; Taniya, Olga S ; Zyryanov, Grigory V ; Chupakhin, Oleg. N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-7a7bf0332abea32e0840f912caa6a6b7947a245bd2143c4dde0fb0f20370ad9f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemistry</topic><topic>Molecular electronics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mukherjee, Anindita</creatorcontrib><creatorcontrib>Akulov, Alexey A</creatorcontrib><creatorcontrib>Santra, Sougata</creatorcontrib><creatorcontrib>Varaksin, Mikhail V</creatorcontrib><creatorcontrib>Kim, Grigory A</creatorcontrib><creatorcontrib>Kopchuk, Dmitry S</creatorcontrib><creatorcontrib>Taniya, Olga S</creatorcontrib><creatorcontrib>Zyryanov, Grigory V</creatorcontrib><creatorcontrib>Chupakhin, Oleg. N</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mukherjee, Anindita</au><au>Akulov, Alexey A</au><au>Santra, Sougata</au><au>Varaksin, Mikhail V</au><au>Kim, Grigory A</au><au>Kopchuk, Dmitry S</au><au>Taniya, Olga S</au><au>Zyryanov, Grigory V</au><au>Chupakhin, Oleg. N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>2,7-Diazapyrenes: a brief review on synthetic strategies and application opportunities</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2022-03-21</date><risdate>2022</risdate><volume>12</volume><issue>15</issue><spage>9323</spage><epage>9341</epage><pages>9323-9341</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>2,7-Diazapyrenes are promising azaaromatic scaffolds with a unique structural geometry and supramolecular properties. This core moiety and its derivatives with some
N
-methyl cations like
N
-methyl-2,7,-diazapyrenium, and
N
,
N
′-dimethyl-2,7-diazapyrenium attract special attention due to their challenging photophysical properties, especially in the context of interactions with DNA and some of its mononucleotides. This review focuses on the analysis of the main synthetic approaches to 2,7-diazapyrene and its functional derivatives employing various strategies under different reaction conditions. The opportunities of applications of 2,7-diazapyrenes, including their remarkable photophysical and supramolecular properties, DNA-bindings, in sensors, molecular electronics, supramolecular systems, and related areas are also highlighted.
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| title | 2,7-Diazapyrenes: a brief review on synthetic strategies and application opportunities |
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