Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution

A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles, producing a diverse range of chiral allylic products in high yields and...

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Veröffentlicht in:	Organic & biomolecular chemistry 2022-09, Vol.2 (37), p.7415-7418
Hauptverfasser:	Feng, Bin, Fang, Pei-Wen, Lan, Gui-Man, Peng, Li-Yan, Liang, Lu-Fang, You, Ge-Yun
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Ligands Nucleophiles Palladium Selenide Selenium Substitutes
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container_end_page	7418
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container_title	Organic & biomolecular chemistry
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creator	Feng, Bin Fang, Pei-Wen Lan, Gui-Man Peng, Li-Yan Liang, Lu-Fang You, Ge-Yun
description	A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles, producing a diverse range of chiral allylic products in high yields and enantioselectivities (up to 99% yield and 95% ee). A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles.
doi_str_mv	10.1039/d2ob01249a
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Asymmetry Ligands Nucleophiles Palladium Selenide Selenium Substitutes
title	Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution
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