Synthesis of two tetra-azolium salts and the recognition performance for guests
One open tetra-benzimidazolium salt ( 1 ) and one cyclic tetra-imidazolium salt ( 2 ) based on tetramethylbenzene were synthesized and characterized. The single crystal structure of 1 was determined by X-ray diffraction. The recognition performance of compounds 1 and 2 for guests ( 1 for o -phenylen...
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| Veröffentlicht in: | New journal of chemistry 2022-11, Vol.46 (46), p.2218-22116 |
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| container_issue | 46 |
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| container_title | New journal of chemistry |
| container_volume | 46 |
| creator | Zhao, Zhi-Xiang Hu, Lin-Hai Yu, Shao-Cong Liu, Qing-Xiang |
| description | One open tetra-benzimidazolium salt (
1
) and one cyclic tetra-imidazolium salt (
2
) based on tetramethylbenzene were synthesized and characterized. The single crystal structure of
1
was determined by X-ray diffraction. The recognition performance of compounds
1
and
2
for guests (
1
for
o
-phenylenediamine (OPD) and
2
for F
−
) was investigated
via
fluorescent spectra, UV/vis spectra,
1
H NMR, HRMS and IR spectra. In particular, a remarkable color change (from colorless to pale brown) was observed in the recognition process of
2
for F
−
, which indicated that this recognition can not only be carried out by using an instrument but also by the naked eye, and this had great convenience in practice.
Two tetra-azolium salts
1
and
2
were synthesized and characterized, and their selective recognition of guests (
o
-phenylenediamine and F
−
) was investigated. |
| doi_str_mv | 10.1039/d2nj04255j |
| format | Article |
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1
) and one cyclic tetra-imidazolium salt (
2
) based on tetramethylbenzene were synthesized and characterized. The single crystal structure of
1
was determined by X-ray diffraction. The recognition performance of compounds
1
and
2
for guests (
1
for
o
-phenylenediamine (OPD) and
2
for F
−
) was investigated
via
fluorescent spectra, UV/vis spectra,
1
H NMR, HRMS and IR spectra. In particular, a remarkable color change (from colorless to pale brown) was observed in the recognition process of
2
for F
−
, which indicated that this recognition can not only be carried out by using an instrument but also by the naked eye, and this had great convenience in practice.
Two tetra-azolium salts
1
and
2
were synthesized and characterized, and their selective recognition of guests (
o
-phenylenediamine and F
−
) was investigated.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d2nj04255j</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Crystal structure ; Fluorescence ; Infrared spectroscopy ; NMR ; Nuclear magnetic resonance ; Phenylenediamine ; Recognition ; Single crystals ; Spectra</subject><ispartof>New journal of chemistry, 2022-11, Vol.46 (46), p.2218-22116</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-1b1e0ff26f5c89dcb7af5df99bc4b304d649182bbb4d8dd3d19cd1c17807fbc73</cites><orcidid>0000-0001-7824-3318</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Zhao, Zhi-Xiang</creatorcontrib><creatorcontrib>Hu, Lin-Hai</creatorcontrib><creatorcontrib>Yu, Shao-Cong</creatorcontrib><creatorcontrib>Liu, Qing-Xiang</creatorcontrib><title>Synthesis of two tetra-azolium salts and the recognition performance for guests</title><title>New journal of chemistry</title><description>One open tetra-benzimidazolium salt (
1
) and one cyclic tetra-imidazolium salt (
2
) based on tetramethylbenzene were synthesized and characterized. The single crystal structure of
1
was determined by X-ray diffraction. The recognition performance of compounds
1
and
2
for guests (
1
for
o
-phenylenediamine (OPD) and
2
for F
−
) was investigated
via
fluorescent spectra, UV/vis spectra,
1
H NMR, HRMS and IR spectra. In particular, a remarkable color change (from colorless to pale brown) was observed in the recognition process of
2
for F
−
, which indicated that this recognition can not only be carried out by using an instrument but also by the naked eye, and this had great convenience in practice.
Two tetra-azolium salts
1
and
2
were synthesized and characterized, and their selective recognition of guests (
o
-phenylenediamine and F
−
) was investigated.</description><subject>Crystal structure</subject><subject>Fluorescence</subject><subject>Infrared spectroscopy</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phenylenediamine</subject><subject>Recognition</subject><subject>Single crystals</subject><subject>Spectra</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpF0EtLAzEUBeAgCtbqxr0QcCeM5iaZR5ZS3xS7UNdDnnWGNqlJitRf79SKru5ZfNwDB6FTIJdAmLgy1PeE07Ls99AIWCUKQSvYHzJwXpCSV4foKKWeEIC6ghGavWx8frepSzg4nD8DzjZHWcivsOjWS5zkIicsvcGDwtHqMPdd7oLHKxtdiEvptcVDwPO1TTkdowMnF8me_N4xeru7fZ08FNPZ_ePkelpoykkuQIElztHKlboRRqtautI4IZTmihFuKi6goUopbhpjmAGhDWioG1I7pWs2Rue7v6sYPrbNbR_W0Q-VLa054QDAmkFd7JSOIaVoXbuK3VLGTQuk3Q7W3tDnp5_BngZ8tsMx6T_3Pyj7Bp89aS0</recordid><startdate>20221128</startdate><enddate>20221128</enddate><creator>Zhao, Zhi-Xiang</creator><creator>Hu, Lin-Hai</creator><creator>Yu, Shao-Cong</creator><creator>Liu, Qing-Xiang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0001-7824-3318</orcidid></search><sort><creationdate>20221128</creationdate><title>Synthesis of two tetra-azolium salts and the recognition performance for guests</title><author>Zhao, Zhi-Xiang ; Hu, Lin-Hai ; Yu, Shao-Cong ; Liu, Qing-Xiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-1b1e0ff26f5c89dcb7af5df99bc4b304d649182bbb4d8dd3d19cd1c17807fbc73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Crystal structure</topic><topic>Fluorescence</topic><topic>Infrared spectroscopy</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phenylenediamine</topic><topic>Recognition</topic><topic>Single crystals</topic><topic>Spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Zhi-Xiang</creatorcontrib><creatorcontrib>Hu, Lin-Hai</creatorcontrib><creatorcontrib>Yu, Shao-Cong</creatorcontrib><creatorcontrib>Liu, Qing-Xiang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Zhi-Xiang</au><au>Hu, Lin-Hai</au><au>Yu, Shao-Cong</au><au>Liu, Qing-Xiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of two tetra-azolium salts and the recognition performance for guests</atitle><jtitle>New journal of chemistry</jtitle><date>2022-11-28</date><risdate>2022</risdate><volume>46</volume><issue>46</issue><spage>2218</spage><epage>22116</epage><pages>2218-22116</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>One open tetra-benzimidazolium salt (
1
) and one cyclic tetra-imidazolium salt (
2
) based on tetramethylbenzene were synthesized and characterized. The single crystal structure of
1
was determined by X-ray diffraction. The recognition performance of compounds
1
and
2
for guests (
1
for
o
-phenylenediamine (OPD) and
2
for F
−
) was investigated
via
fluorescent spectra, UV/vis spectra,
1
H NMR, HRMS and IR spectra. In particular, a remarkable color change (from colorless to pale brown) was observed in the recognition process of
2
for F
−
, which indicated that this recognition can not only be carried out by using an instrument but also by the naked eye, and this had great convenience in practice.
Two tetra-azolium salts
1
and
2
were synthesized and characterized, and their selective recognition of guests (
o
-phenylenediamine and F
−
) was investigated.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2nj04255j</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-7824-3318</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2022-11, Vol.46 (46), p.2218-22116 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2NJ04255J |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystal structure Fluorescence Infrared spectroscopy NMR Nuclear magnetic resonance Phenylenediamine Recognition Single crystals Spectra |
| title | Synthesis of two tetra-azolium salts and the recognition performance for guests |
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