A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films
A new organic-inorganic hybrid perovskite ferroelectric, [ClCH 2 CH 2 N(CH 3 ) 3 ][PbBr 3 ] ( CEPbBr ) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH 2 CH 2 N(CH 3 ) 3 ] + Cl − with lead( ii ) bromide in a HBr aqueous solution. CEPbBr could undergo a reversible phas...
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Veröffentlicht in: | New journal of chemistry 2022-10, Vol.46 (4), p.19391-194 |
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container_title | New journal of chemistry |
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creator | Li, Duo-Fu Zhao, Peng-Ju Deng, Xiang-Hong Wu, Yao-Zhen He, Xiao-Li Liu, Dong-Sheng Li, Yong-Xiu Sui, Yan |
description | A new organic-inorganic hybrid perovskite ferroelectric, [ClCH
2
CH
2
N(CH
3
)
3
][PbBr
3
] (
CEPbBr
) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH
2
CH
2
N(CH
3
)
3
]
+
Cl
−
with lead(
ii
) bromide in a HBr aqueous solution.
CEPbBr
could undergo a reversible phase transition at 315/300 K with the space group change from
Cc
to
Pna
2
1
and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization (
P
s
) before and after phase transition for the single crystal sample is 6.20 μC cm
−2
and 0.28 μC cm
−2
, respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted
in situ
growth of
CEPbBr
particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications.
A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted
in situ
growth. |
doi_str_mv | 10.1039/d2nj03613d |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D2NJ03613D</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2725181522</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-4ead6910e6ad6a1600fa68e3b0f5eeef8bdd0222176ee3cca8be3fd862d73d4c3</originalsourceid><addsrcrecordid>eNpdkU9PwkAQxRujiYhevJts4kVNVvdPu5QjFrEYohzUCyHNtjsLi6XF3aLwQfy-FiGaeJo3mV_eZN543ikl15Tw9o1ixYxwQbna8xqUizZuM0H3a019H5PAF4fekXMzQihtCdrwvjqogE9U2oksTIZNsVNouk6tUWgBtvxwb6YCpMHaEnLIKlvPR1EexVH8eBHFl-PRML21YyQLhfqVQ8PXbg_NZc2tsHTOuAoUmprJNF_j0hooNr3OYWXS_L-vNvncHXsHWuYOTna16b307p6jGA-e7vtRZ4AzFtIK-yCVaFMCoq6SCkK0FCHwlOgAAHSYKkUYY_WpADzLZJgC1yoUTLW48jPe9M63vgtbvi_BVcmsXNqiXpmwFgtoSAPGaupqS2W2dM6CThbWzKVdJ5Qkm9iTLnt8-Im9W8NnW9i67Jf7ewv_BhwOgeo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2725181522</pqid></control><display><type>article</type><title>A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Li, Duo-Fu ; Zhao, Peng-Ju ; Deng, Xiang-Hong ; Wu, Yao-Zhen ; He, Xiao-Li ; Liu, Dong-Sheng ; Li, Yong-Xiu ; Sui, Yan</creator><creatorcontrib>Li, Duo-Fu ; Zhao, Peng-Ju ; Deng, Xiang-Hong ; Wu, Yao-Zhen ; He, Xiao-Li ; Liu, Dong-Sheng ; Li, Yong-Xiu ; Sui, Yan</creatorcontrib><description>A new organic-inorganic hybrid perovskite ferroelectric, [ClCH
2
CH
2
N(CH
3
)
3
][PbBr
3
] (
CEPbBr
) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH
2
CH
2
N(CH
3
)
3
]
+
Cl
−
with lead(
ii
) bromide in a HBr aqueous solution.
CEPbBr
could undergo a reversible phase transition at 315/300 K with the space group change from
Cc
to
Pna
2
1
and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization (
P
s
) before and after phase transition for the single crystal sample is 6.20 μC cm
−2
and 0.28 μC cm
−2
, respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted
in situ
growth of
CEPbBr
particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications.
A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted
in situ
growth.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d2nj03613d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aqueous solutions ; Dipoles ; Ferroelectric materials ; Ferroelectricity ; Perovskites ; Phase transitions ; Preferred orientation ; Single crystals ; Thin films</subject><ispartof>New journal of chemistry, 2022-10, Vol.46 (4), p.19391-194</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-4ead6910e6ad6a1600fa68e3b0f5eeef8bdd0222176ee3cca8be3fd862d73d4c3</citedby><cites>FETCH-LOGICAL-c281t-4ead6910e6ad6a1600fa68e3b0f5eeef8bdd0222176ee3cca8be3fd862d73d4c3</cites><orcidid>0000-0003-3522-3186 ; 0000-0002-3936-4026</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Duo-Fu</creatorcontrib><creatorcontrib>Zhao, Peng-Ju</creatorcontrib><creatorcontrib>Deng, Xiang-Hong</creatorcontrib><creatorcontrib>Wu, Yao-Zhen</creatorcontrib><creatorcontrib>He, Xiao-Li</creatorcontrib><creatorcontrib>Liu, Dong-Sheng</creatorcontrib><creatorcontrib>Li, Yong-Xiu</creatorcontrib><creatorcontrib>Sui, Yan</creatorcontrib><title>A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films</title><title>New journal of chemistry</title><description>A new organic-inorganic hybrid perovskite ferroelectric, [ClCH
2
CH
2
N(CH
3
)
3
][PbBr
3
] (
CEPbBr
) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH
2
CH
2
N(CH
3
)
3
]
+
Cl
−
with lead(
ii
) bromide in a HBr aqueous solution.
CEPbBr
could undergo a reversible phase transition at 315/300 K with the space group change from
Cc
to
Pna
2
1
and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization (
P
s
) before and after phase transition for the single crystal sample is 6.20 μC cm
−2
and 0.28 μC cm
−2
, respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted
in situ
growth of
CEPbBr
particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications.
A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted
in situ
growth.</description><subject>Aqueous solutions</subject><subject>Dipoles</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Perovskites</subject><subject>Phase transitions</subject><subject>Preferred orientation</subject><subject>Single crystals</subject><subject>Thin films</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkU9PwkAQxRujiYhevJts4kVNVvdPu5QjFrEYohzUCyHNtjsLi6XF3aLwQfy-FiGaeJo3mV_eZN543ikl15Tw9o1ixYxwQbna8xqUizZuM0H3a019H5PAF4fekXMzQihtCdrwvjqogE9U2oksTIZNsVNouk6tUWgBtvxwb6YCpMHaEnLIKlvPR1EexVH8eBHFl-PRML21YyQLhfqVQ8PXbg_NZc2tsHTOuAoUmprJNF_j0hooNr3OYWXS_L-vNvncHXsHWuYOTna16b307p6jGA-e7vtRZ4AzFtIK-yCVaFMCoq6SCkK0FCHwlOgAAHSYKkUYY_WpADzLZJgC1yoUTLW48jPe9M63vgtbvi_BVcmsXNqiXpmwFgtoSAPGaupqS2W2dM6CThbWzKVdJ5Qkm9iTLnt8-Im9W8NnW9i67Jf7ewv_BhwOgeo</recordid><startdate>20221017</startdate><enddate>20221017</enddate><creator>Li, Duo-Fu</creator><creator>Zhao, Peng-Ju</creator><creator>Deng, Xiang-Hong</creator><creator>Wu, Yao-Zhen</creator><creator>He, Xiao-Li</creator><creator>Liu, Dong-Sheng</creator><creator>Li, Yong-Xiu</creator><creator>Sui, Yan</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0003-3522-3186</orcidid><orcidid>https://orcid.org/0000-0002-3936-4026</orcidid></search><sort><creationdate>20221017</creationdate><title>A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films</title><author>Li, Duo-Fu ; Zhao, Peng-Ju ; Deng, Xiang-Hong ; Wu, Yao-Zhen ; He, Xiao-Li ; Liu, Dong-Sheng ; Li, Yong-Xiu ; Sui, Yan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-4ead6910e6ad6a1600fa68e3b0f5eeef8bdd0222176ee3cca8be3fd862d73d4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Dipoles</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Perovskites</topic><topic>Phase transitions</topic><topic>Preferred orientation</topic><topic>Single crystals</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Duo-Fu</creatorcontrib><creatorcontrib>Zhao, Peng-Ju</creatorcontrib><creatorcontrib>Deng, Xiang-Hong</creatorcontrib><creatorcontrib>Wu, Yao-Zhen</creatorcontrib><creatorcontrib>He, Xiao-Li</creatorcontrib><creatorcontrib>Liu, Dong-Sheng</creatorcontrib><creatorcontrib>Li, Yong-Xiu</creatorcontrib><creatorcontrib>Sui, Yan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Duo-Fu</au><au>Zhao, Peng-Ju</au><au>Deng, Xiang-Hong</au><au>Wu, Yao-Zhen</au><au>He, Xiao-Li</au><au>Liu, Dong-Sheng</au><au>Li, Yong-Xiu</au><au>Sui, Yan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films</atitle><jtitle>New journal of chemistry</jtitle><date>2022-10-17</date><risdate>2022</risdate><volume>46</volume><issue>4</issue><spage>19391</spage><epage>194</epage><pages>19391-194</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>A new organic-inorganic hybrid perovskite ferroelectric, [ClCH
2
CH
2
N(CH
3
)
3
][PbBr
3
] (
CEPbBr
) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH
2
CH
2
N(CH
3
)
3
]
+
Cl
−
with lead(
ii
) bromide in a HBr aqueous solution.
CEPbBr
could undergo a reversible phase transition at 315/300 K with the space group change from
Cc
to
Pna
2
1
and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization (
P
s
) before and after phase transition for the single crystal sample is 6.20 μC cm
−2
and 0.28 μC cm
−2
, respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted
in situ
growth of
CEPbBr
particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications.
A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted
in situ
growth.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2nj03613d</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-3522-3186</orcidid><orcidid>https://orcid.org/0000-0002-3936-4026</orcidid></addata></record> |
fulltext | fulltext |
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language | eng |
recordid | cdi_crossref_primary_10_1039_D2NJ03613D |
source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Aqueous solutions Dipoles Ferroelectric materials Ferroelectricity Perovskites Phase transitions Preferred orientation Single crystals Thin films |
title | A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films |
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