A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films

A new organic-inorganic hybrid perovskite ferroelectric, [ClCH 2 CH 2 N(CH 3 ) 3 ][PbBr 3 ] ( CEPbBr ) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH 2 CH 2 N(CH 3 ) 3 ] + Cl − with lead( ii ) bromide in a HBr aqueous solution. CEPbBr could undergo a reversible phas...

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Veröffentlicht in:New journal of chemistry 2022-10, Vol.46 (4), p.19391-194
Hauptverfasser: Li, Duo-Fu, Zhao, Peng-Ju, Deng, Xiang-Hong, Wu, Yao-Zhen, He, Xiao-Li, Liu, Dong-Sheng, Li, Yong-Xiu, Sui, Yan
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container_title New journal of chemistry
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creator Li, Duo-Fu
Zhao, Peng-Ju
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Wu, Yao-Zhen
He, Xiao-Li
Liu, Dong-Sheng
Li, Yong-Xiu
Sui, Yan
description A new organic-inorganic hybrid perovskite ferroelectric, [ClCH 2 CH 2 N(CH 3 ) 3 ][PbBr 3 ] ( CEPbBr ) was obtained by the reaction of (2-chloroethyl) trimethylammonium chloride [ClCH 2 CH 2 N(CH 3 ) 3 ] + Cl − with lead( ii ) bromide in a HBr aqueous solution. CEPbBr could undergo a reversible phase transition at 315/300 K with the space group change from Cc to Pna 2 1 and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization ( P s ) before and after phase transition for the single crystal sample is 6.20 μC cm −2 and 0.28 μC cm −2 , respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted in situ growth of CEPbBr particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications. A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted in situ growth.
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CEPbBr could undergo a reversible phase transition at 315/300 K with the space group change from Cc to Pna 2 1 and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization ( P s ) before and after phase transition for the single crystal sample is 6.20 μC cm −2 and 0.28 μC cm −2 , respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted in situ growth of CEPbBr particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications. 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CEPbBr could undergo a reversible phase transition at 315/300 K with the space group change from Cc to Pna 2 1 and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization ( P s ) before and after phase transition for the single crystal sample is 6.20 μC cm −2 and 0.28 μC cm −2 , respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted in situ growth of CEPbBr particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications. 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CEPbBr could undergo a reversible phase transition at 315/300 K with the space group change from Cc to Pna 2 1 and exhibit the dielectric, SHG, and ferroelectric triple transitions between high and low states as a response to a temperature stimulus. The experimental spontaneous polarization ( P s ) before and after phase transition for the single crystal sample is 6.20 μC cm −2 and 0.28 μC cm −2 , respectively. In order to solve the problem of randomly distributed dipole orientation of powder-pressed pellet, highly-oriented flexible ferroelectric films were obtained by the method of β-phase dominated PVDF matrix-assisted in situ growth of CEPbBr particles. The protocol of inducing a preferred orientation by a polymer matrix may be key to developing highly-oriented flexible ferroelectric thin films for electronic applications. A hybrid perovskite with dielectric, SHG, and ferroelectric triple transitions was tailored into highly-oriented films using PVDF matrix-assisted in situ growth.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2nj03613d</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-3522-3186</orcidid><orcidid>https://orcid.org/0000-0002-3936-4026</orcidid></addata></record>
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Aqueous solutions
Dipoles
Ferroelectric materials
Ferroelectricity
Perovskites
Phase transitions
Preferred orientation
Single crystals
Thin films
title A new organic-inorganic hybrid perovskite ferroelectric [ClCHCHN(CH)][PbBr] and Its PVDF matrix-assisted highly-oriented flexible ferroelectric films
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