Manganese() thiophosphate (MnPS) intercalates with lanthanide (Pr and Nd) complexes: optical and magnetic properties
We report the intercalation of Pr III and Nd III macrocyclic complexes into the layered hexahypothiophosphate MnPS 3 and the effect of this process on the optical and magnetic properties of the layered host. Spontaneous magnetization is observed within the 2040 K temperature range, arising as a cons...
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| Veröffentlicht in: | New journal of chemistry 2022-10, Vol.46 (41), p.19984-1999 |
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| container_end_page | 1999 |
|---|---|
| container_issue | 41 |
| container_start_page | 19984 |
| container_title | New journal of chemistry |
| container_volume | 46 |
| creator | Fuentealba, Pablo Morales, Jeannette Audebrand, Nathalie Magon, Claudio José Eckert, Hellmut Manzur, Jorge Spodine, Evgenia |
| description | We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host. Spontaneous magnetization is observed within the 2040 K temperature range, arising as a consequence of vacancy ordering occurring in the antiferromagnetically coupled host material. The band gap energy values are also modified, all intercalates showing lower values as compared to the pristine phase. Both effects are remarkably sensitive to the nature of the guest species, suggesting an interaction of the organic ligand with the terminal sulfur atoms of the P
2
S
6
4−
ions.
We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host. |
| doi_str_mv | 10.1039/d2nj02303b |
| format | Article |
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III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host. Spontaneous magnetization is observed within the 2040 K temperature range, arising as a consequence of vacancy ordering occurring in the antiferromagnetically coupled host material. The band gap energy values are also modified, all intercalates showing lower values as compared to the pristine phase. Both effects are remarkably sensitive to the nature of the guest species, suggesting an interaction of the organic ligand with the terminal sulfur atoms of the P
2
S
6
4−
ions.
We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d2nj02303b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Antiferromagnetism ; Chemical Sciences ; Energy gap ; Energy value ; Magnetic properties ; Manganese ; Optical properties</subject><ispartof>New journal of chemistry, 2022-10, Vol.46 (41), p.19984-1999</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c310t-2ab08a586ef280624db9f5aae306ec1c52c8cc065f9a46d6e2b7c30a35b953763</cites><orcidid>0000-0003-0581-1243 ; 0000-0002-1725-7182 ; 0000-0002-6536-0117 ; 0000-0001-6457-0094 ; 0000-0002-7089-3145</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03828182$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Fuentealba, Pablo</creatorcontrib><creatorcontrib>Morales, Jeannette</creatorcontrib><creatorcontrib>Audebrand, Nathalie</creatorcontrib><creatorcontrib>Magon, Claudio José</creatorcontrib><creatorcontrib>Eckert, Hellmut</creatorcontrib><creatorcontrib>Manzur, Jorge</creatorcontrib><creatorcontrib>Spodine, Evgenia</creatorcontrib><title>Manganese() thiophosphate (MnPS) intercalates with lanthanide (Pr and Nd) complexes: optical and magnetic properties</title><title>New journal of chemistry</title><description>We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host. Spontaneous magnetization is observed within the 2040 K temperature range, arising as a consequence of vacancy ordering occurring in the antiferromagnetically coupled host material. The band gap energy values are also modified, all intercalates showing lower values as compared to the pristine phase. Both effects are remarkably sensitive to the nature of the guest species, suggesting an interaction of the organic ligand with the terminal sulfur atoms of the P
2
S
6
4−
ions.
We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host.</description><subject>Antiferromagnetism</subject><subject>Chemical Sciences</subject><subject>Energy gap</subject><subject>Energy value</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Optical properties</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkUlPwzAQhS0EEqVw4Y5kiUuLFPCSOAk39oLaUgk4RxPHaVKlTrBdln-P2yI4zfbN02geQseUnFPC04uC6QVhnPB8B_UoF2mQMkF3fU7DMCBRKPbRgbULQiiNBe0hNwE9B62sGgyxq-q2q1rbVeAUHkz07GWIa-2UkdD4lsWftatwA9pVoOvCMzODQRd4WgyxbJddo76UvcRt52q_shktYa6VL3Fn2k4ZVyt7iPZKaKw6-o199HZ_93ozCsbPD483V-NAckpcwCAnCUSJUCVLiGBhkadlBKA4EUpSGTGZSElEVKYQikIolseSE-BRnkY8FryPhlvdCpqsM_USzHfWQp2NrsbZukd4whKasA_q2dMt6898XynrskW7Mtqfl7GYxVGcxv6xfXS2paRprTWq_JOlJFs7kN2y6dPGgWsPn2xhY-Uf9-8Q_wEyKoHR</recordid><startdate>20221024</startdate><enddate>20221024</enddate><creator>Fuentealba, Pablo</creator><creator>Morales, Jeannette</creator><creator>Audebrand, Nathalie</creator><creator>Magon, Claudio José</creator><creator>Eckert, Hellmut</creator><creator>Manzur, Jorge</creator><creator>Spodine, Evgenia</creator><general>Royal Society of Chemistry</general><general>Royal Society of Chemistry [1987-....]</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-0581-1243</orcidid><orcidid>https://orcid.org/0000-0002-1725-7182</orcidid><orcidid>https://orcid.org/0000-0002-6536-0117</orcidid><orcidid>https://orcid.org/0000-0001-6457-0094</orcidid><orcidid>https://orcid.org/0000-0002-7089-3145</orcidid></search><sort><creationdate>20221024</creationdate><title>Manganese() thiophosphate (MnPS) intercalates with lanthanide (Pr and Nd) complexes: optical and magnetic properties</title><author>Fuentealba, Pablo ; Morales, Jeannette ; Audebrand, Nathalie ; Magon, Claudio José ; Eckert, Hellmut ; Manzur, Jorge ; Spodine, Evgenia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c310t-2ab08a586ef280624db9f5aae306ec1c52c8cc065f9a46d6e2b7c30a35b953763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Antiferromagnetism</topic><topic>Chemical Sciences</topic><topic>Energy gap</topic><topic>Energy value</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Optical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fuentealba, Pablo</creatorcontrib><creatorcontrib>Morales, Jeannette</creatorcontrib><creatorcontrib>Audebrand, Nathalie</creatorcontrib><creatorcontrib>Magon, Claudio José</creatorcontrib><creatorcontrib>Eckert, Hellmut</creatorcontrib><creatorcontrib>Manzur, Jorge</creatorcontrib><creatorcontrib>Spodine, Evgenia</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fuentealba, Pablo</au><au>Morales, Jeannette</au><au>Audebrand, Nathalie</au><au>Magon, Claudio José</au><au>Eckert, Hellmut</au><au>Manzur, Jorge</au><au>Spodine, Evgenia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Manganese() thiophosphate (MnPS) intercalates with lanthanide (Pr and Nd) complexes: optical and magnetic properties</atitle><jtitle>New journal of chemistry</jtitle><date>2022-10-24</date><risdate>2022</risdate><volume>46</volume><issue>41</issue><spage>19984</spage><epage>1999</epage><pages>19984-1999</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host. Spontaneous magnetization is observed within the 2040 K temperature range, arising as a consequence of vacancy ordering occurring in the antiferromagnetically coupled host material. The band gap energy values are also modified, all intercalates showing lower values as compared to the pristine phase. Both effects are remarkably sensitive to the nature of the guest species, suggesting an interaction of the organic ligand with the terminal sulfur atoms of the P
2
S
6
4−
ions.
We report the intercalation of Pr
III
and Nd
III
macrocyclic complexes into the layered hexahypothiophosphate MnPS
3
and the effect of this process on the optical and magnetic properties of the layered host.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2nj02303b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-0581-1243</orcidid><orcidid>https://orcid.org/0000-0002-1725-7182</orcidid><orcidid>https://orcid.org/0000-0002-6536-0117</orcidid><orcidid>https://orcid.org/0000-0001-6457-0094</orcidid><orcidid>https://orcid.org/0000-0002-7089-3145</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2022-10, Vol.46 (41), p.19984-1999 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2NJ02303B |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Antiferromagnetism Chemical Sciences Energy gap Energy value Magnetic properties Manganese Optical properties |
| title | Manganese() thiophosphate (MnPS) intercalates with lanthanide (Pr and Nd) complexes: optical and magnetic properties |
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