Crossed-beam and theoretical studies of multichannel nonadiabatic reactions: branching fractions and role of intersystem crossing for O(P) + 1,3-butadiene

Atomic oxygen reactions can contribute significantly to the oxidation of unsaturated aliphatic and aromatic hydrocarbons. The reaction mechanism is started by electrophilic O atom addition to the unsaturated bond(s) to form "chemically activated" triplet oxy-intermediate(s), which can evol...

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Veröffentlicht in:	Faraday discussions 2022-10, Vol.238, p.161-182
Hauptverfasser:	Cavallotti, C, Della Libera, A, Zhou, C.-W, Recio, P, Caracciolo, A, Balucani, N, Casavecchia, P
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic hydrocarbons Atomic oxygen Butadiene Channels Chemical bonds Fractions Molecular beams Oxidation Potential energy Rate constants Reaction mechanisms
Online-Zugang:	Volltext
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