Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media
Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. In this study, a chemically stable, recoverable, eco-friendly, and magnetic h-BN/Pd/Fe 2 O 3 catalyst was prepared by a one-step c...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-03, Vol.52 (12), p.3567-3574 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3574 |
|---|---|
| container_issue | 12 |
| container_start_page | 3567 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Wang, Jinghan Cheon, Woo Seok Lee, Ju-Yong Yan, Wenqian Jung, Sunghoon Jang, Ho Won Shokouhimehr, Mohammadreza |
| description | Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. In this study, a chemically stable, recoverable, eco-friendly, and magnetic h-BN/Pd/Fe
2
O
3
catalyst was prepared by a one-step calcination process, in which Pd and Fe
2
O
3
nanoparticles (NPs) were uniformly decorated on the surface of h-BN
via
a typical adsorption-reduction procedure. In detail, nanosized magnetic (Pd/Fe
2
O
3
) NPs were derived from a Prussian blue analogue prototype, a well-known porous metal-organic framework, and then further surface-engineered to produce magnetic BN nanoplate-supported Pd nanocatalysts. The structural and morphological features of h-BN/Pd/Fe
2
O
3
were investigated by spectroscopic and microscopic characterization techniques. Moreover, the h-BN nanosheets endow it with stability and appropriate chemical anchoring sites which solve the problems of inefficient reaction rate and high consumption caused by the inevitable agglomeration of precious metal NPs. Under mild reaction conditions, the developed nanostructured h-BN/Pd/Fe
2
O
3
as the catalyst shows high yield and efficient reusability in reducing nitroarenes into the corresponding anilines using sodium borohydride (NaBH
4
) as a reductant.
Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. |
| doi_str_mv | 10.1039/d2dt03920f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D2DT03920F</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2788729419</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-9362e01f3dead7e999b2dab05f3a73946891dfff015ae362577cc11d1801b8c3</originalsourceid><addsrcrecordid>eNpd0c1LHDEYBvBQlPrRXnpvCXiRwtp8zGwm3kRrFZT2sPfhneRNjcwma5JBPPi_m3XtFjy9L-THk4SHkC-cnXAm9Q8rbKlTMPeB7PNGqZkWstnZ7mK-Rw5yvmdMCNaKj2RPzruubnqfPN_C34DFGzrEFAMNviRvkYKNKaClj77c0T-WBghxBanCEfMphUDROW88hkINFBifcqEuJlrukCa0kym-xkX3mhghYcBMfaDwMGGcMl2i9fCJ7DoYM35-m4dkcflzcX41u_n96_r87GZmpFRlpuVcIONOWgSrUGs9CAsDa50EJXUz7zS3zjnGW8BqW6WM4dzyjvGhM_KQHG9iVynW63Pplz4bHEcI67f0QnWN7NpG6EqP3tH7OKVQH7dWnRK64Wv1faNMijkndP0q-SWkp56zft1JfyEuFq-dXFb87S1yGuqvt_RfCRV83YCUzfb0f6nyBQNkkhw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2788729419</pqid></control><display><type>article</type><title>Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Wang, Jinghan ; Cheon, Woo Seok ; Lee, Ju-Yong ; Yan, Wenqian ; Jung, Sunghoon ; Jang, Ho Won ; Shokouhimehr, Mohammadreza</creator><creatorcontrib>Wang, Jinghan ; Cheon, Woo Seok ; Lee, Ju-Yong ; Yan, Wenqian ; Jung, Sunghoon ; Jang, Ho Won ; Shokouhimehr, Mohammadreza</creatorcontrib><description>Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. In this study, a chemically stable, recoverable, eco-friendly, and magnetic h-BN/Pd/Fe
2
O
3
catalyst was prepared by a one-step calcination process, in which Pd and Fe
2
O
3
nanoparticles (NPs) were uniformly decorated on the surface of h-BN
via
a typical adsorption-reduction procedure. In detail, nanosized magnetic (Pd/Fe
2
O
3
) NPs were derived from a Prussian blue analogue prototype, a well-known porous metal-organic framework, and then further surface-engineered to produce magnetic BN nanoplate-supported Pd nanocatalysts. The structural and morphological features of h-BN/Pd/Fe
2
O
3
were investigated by spectroscopic and microscopic characterization techniques. Moreover, the h-BN nanosheets endow it with stability and appropriate chemical anchoring sites which solve the problems of inefficient reaction rate and high consumption caused by the inevitable agglomeration of precious metal NPs. Under mild reaction conditions, the developed nanostructured h-BN/Pd/Fe
2
O
3
as the catalyst shows high yield and efficient reusability in reducing nitroarenes into the corresponding anilines using sodium borohydride (NaBH
4
) as a reductant.
Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt03920f</identifier><identifier>PMID: 36880529</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Aniline ; Aqueous solutions ; Boron nitride ; Catalysts ; Metal-organic frameworks ; Morphology ; Nanoparticles ; Palladium ; Pigments ; Reducing agents ; Stability</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-03, Vol.52 (12), p.3567-3574</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-9362e01f3dead7e999b2dab05f3a73946891dfff015ae362577cc11d1801b8c3</citedby><cites>FETCH-LOGICAL-c337t-9362e01f3dead7e999b2dab05f3a73946891dfff015ae362577cc11d1801b8c3</cites><orcidid>0000-0003-1416-6805 ; 0000-0002-6952-7359</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36880529$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Jinghan</creatorcontrib><creatorcontrib>Cheon, Woo Seok</creatorcontrib><creatorcontrib>Lee, Ju-Yong</creatorcontrib><creatorcontrib>Yan, Wenqian</creatorcontrib><creatorcontrib>Jung, Sunghoon</creatorcontrib><creatorcontrib>Jang, Ho Won</creatorcontrib><creatorcontrib>Shokouhimehr, Mohammadreza</creatorcontrib><title>Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. In this study, a chemically stable, recoverable, eco-friendly, and magnetic h-BN/Pd/Fe
2
O
3
catalyst was prepared by a one-step calcination process, in which Pd and Fe
2
O
3
nanoparticles (NPs) were uniformly decorated on the surface of h-BN
via
a typical adsorption-reduction procedure. In detail, nanosized magnetic (Pd/Fe
2
O
3
) NPs were derived from a Prussian blue analogue prototype, a well-known porous metal-organic framework, and then further surface-engineered to produce magnetic BN nanoplate-supported Pd nanocatalysts. The structural and morphological features of h-BN/Pd/Fe
2
O
3
were investigated by spectroscopic and microscopic characterization techniques. Moreover, the h-BN nanosheets endow it with stability and appropriate chemical anchoring sites which solve the problems of inefficient reaction rate and high consumption caused by the inevitable agglomeration of precious metal NPs. Under mild reaction conditions, the developed nanostructured h-BN/Pd/Fe
2
O
3
as the catalyst shows high yield and efficient reusability in reducing nitroarenes into the corresponding anilines using sodium borohydride (NaBH
4
) as a reductant.
Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability.</description><subject>Aniline</subject><subject>Aqueous solutions</subject><subject>Boron nitride</subject><subject>Catalysts</subject><subject>Metal-organic frameworks</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Palladium</subject><subject>Pigments</subject><subject>Reducing agents</subject><subject>Stability</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpd0c1LHDEYBvBQlPrRXnpvCXiRwtp8zGwm3kRrFZT2sPfhneRNjcwma5JBPPi_m3XtFjy9L-THk4SHkC-cnXAm9Q8rbKlTMPeB7PNGqZkWstnZ7mK-Rw5yvmdMCNaKj2RPzruubnqfPN_C34DFGzrEFAMNviRvkYKNKaClj77c0T-WBghxBanCEfMphUDROW88hkINFBifcqEuJlrukCa0kym-xkX3mhghYcBMfaDwMGGcMl2i9fCJ7DoYM35-m4dkcflzcX41u_n96_r87GZmpFRlpuVcIONOWgSrUGs9CAsDa50EJXUz7zS3zjnGW8BqW6WM4dzyjvGhM_KQHG9iVynW63Pplz4bHEcI67f0QnWN7NpG6EqP3tH7OKVQH7dWnRK64Wv1faNMijkndP0q-SWkp56zft1JfyEuFq-dXFb87S1yGuqvt_RfCRV83YCUzfb0f6nyBQNkkhw</recordid><startdate>20230321</startdate><enddate>20230321</enddate><creator>Wang, Jinghan</creator><creator>Cheon, Woo Seok</creator><creator>Lee, Ju-Yong</creator><creator>Yan, Wenqian</creator><creator>Jung, Sunghoon</creator><creator>Jang, Ho Won</creator><creator>Shokouhimehr, Mohammadreza</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1416-6805</orcidid><orcidid>https://orcid.org/0000-0002-6952-7359</orcidid></search><sort><creationdate>20230321</creationdate><title>Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media</title><author>Wang, Jinghan ; Cheon, Woo Seok ; Lee, Ju-Yong ; Yan, Wenqian ; Jung, Sunghoon ; Jang, Ho Won ; Shokouhimehr, Mohammadreza</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-9362e01f3dead7e999b2dab05f3a73946891dfff015ae362577cc11d1801b8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aniline</topic><topic>Aqueous solutions</topic><topic>Boron nitride</topic><topic>Catalysts</topic><topic>Metal-organic frameworks</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Palladium</topic><topic>Pigments</topic><topic>Reducing agents</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jinghan</creatorcontrib><creatorcontrib>Cheon, Woo Seok</creatorcontrib><creatorcontrib>Lee, Ju-Yong</creatorcontrib><creatorcontrib>Yan, Wenqian</creatorcontrib><creatorcontrib>Jung, Sunghoon</creatorcontrib><creatorcontrib>Jang, Ho Won</creatorcontrib><creatorcontrib>Shokouhimehr, Mohammadreza</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jinghan</au><au>Cheon, Woo Seok</au><au>Lee, Ju-Yong</au><au>Yan, Wenqian</au><au>Jung, Sunghoon</au><au>Jang, Ho Won</au><au>Shokouhimehr, Mohammadreza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-03-21</date><risdate>2023</risdate><volume>52</volume><issue>12</issue><spage>3567</spage><epage>3574</epage><pages>3567-3574</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability. In this study, a chemically stable, recoverable, eco-friendly, and magnetic h-BN/Pd/Fe
2
O
3
catalyst was prepared by a one-step calcination process, in which Pd and Fe
2
O
3
nanoparticles (NPs) were uniformly decorated on the surface of h-BN
via
a typical adsorption-reduction procedure. In detail, nanosized magnetic (Pd/Fe
2
O
3
) NPs were derived from a Prussian blue analogue prototype, a well-known porous metal-organic framework, and then further surface-engineered to produce magnetic BN nanoplate-supported Pd nanocatalysts. The structural and morphological features of h-BN/Pd/Fe
2
O
3
were investigated by spectroscopic and microscopic characterization techniques. Moreover, the h-BN nanosheets endow it with stability and appropriate chemical anchoring sites which solve the problems of inefficient reaction rate and high consumption caused by the inevitable agglomeration of precious metal NPs. Under mild reaction conditions, the developed nanostructured h-BN/Pd/Fe
2
O
3
as the catalyst shows high yield and efficient reusability in reducing nitroarenes into the corresponding anilines using sodium borohydride (NaBH
4
) as a reductant.
Hexagonal boron nitride (h-BN) is an excellent support material for nanocatalysts due to its two-dimensional (2D) architectural morphology and physicochemical stability.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36880529</pmid><doi>10.1039/d2dt03920f</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-1416-6805</orcidid><orcidid>https://orcid.org/0000-0002-6952-7359</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-03, Vol.52 (12), p.3567-3574 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2DT03920F |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aniline Aqueous solutions Boron nitride Catalysts Metal-organic frameworks Morphology Nanoparticles Palladium Pigments Reducing agents Stability |
| title | Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T07%3A56%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Magnetic%20boron%20nitride%20adorned%20with%20Pd%20nanoparticles:%20an%20efficient%20catalyst%20for%20the%20reduction%20of%20nitroarenes%20in%20aqueous%20media&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Wang,%20Jinghan&rft.date=2023-03-21&rft.volume=52&rft.issue=12&rft.spage=3567&rft.epage=3574&rft.pages=3567-3574&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d2dt03920f&rft_dat=%3Cproquest_cross%3E2788729419%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2788729419&rft_id=info:pmid/36880529&rfr_iscdi=true |