Large changes in hydricity as a function of charge and not metal in (PNP)M-H (de)hydrogenation catalysts that undergo metal-ligand cooperativity

Pincer-ligated catalysts that can undergo metal-ligand cooperativity (MLC), whereby H 2 is heterolytically cleaved (with proton transfer to the ligand and hydride transfer to the metal), have emerged as potent catalysts for the hydrogenation of CO 2 and organic carbonyls. Despite the plethora of sys...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Catalysis science & technology 2023-03, Vol.13 (5), p.1358-1368
Hauptverfasser:	Schlenker, Kevin, Casselman, Lillee K, VanderLinden, Ryan T, Saouma, Caroline T
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyls Catalysis Catalysts Hydrides Hydrogenation Iron Ligands Manganese Parameters Thermochemical properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!