Substituted benzoate-anchored decanuclear titanium-oxo clusters featuring an unprecedented defective double-cubane geometry
Based on DMF solvent, four titanium-oxo clusters (TOCs) [Ti 10 (μ 3 -O) 12 (L) 6 (O i Pr) 10 (DMF) 2 ] ( Ti-L ) ( L = 4-methylbenzoate ( MB ), 3,5-di- tert -butylbenzoate ( DTBB ), 4-methoxybenzoate ( MOB ) and 4-methyl-3,5-dinitrobenzoate ( MDNB )) with the same coordination environments have been...
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| Veröffentlicht in: | CrystEngComm 2023-03, Vol.25 (11), p.1617-1625 |
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| creator | Pei, Xin-Yue He, Ying Wang, Jia-Yin Wang, Hong-Yan Bo, Qi-Bing |
| description | Based on DMF solvent, four titanium-oxo clusters (TOCs) [Ti
10
(μ
3
-O)
12
(L)
6
(O
i
Pr)
10
(DMF)
2
] (
Ti-L
) (
L
= 4-methylbenzoate (
MB
), 3,5-di-
tert
-butylbenzoate (
DTBB
), 4-methoxybenzoate (
MOB
) and 4-methyl-3,5-dinitrobenzoate (
MDNB
)) with the same coordination environments have been solvothermally synthesized with high yield between benzoic acid derivatives and Ti(O
i
Pr)
4
. Single crystal X-ray diffraction analysis confirmed that
Ti-L
presents an open cage-like structure made up of a substituted benzoate-anchored decanuclear titanium-oxo cluster featuring an unprecedented defective double-cubane geometry. The photophysical performance of
Ti-L
demonstrated that strong electron-withdrawing substituent groups on the benzoate skeleton are beneficial to the redshift of the absorption position and the decrease of the band gap for the TOCs. Due to the synergistic effects of its lowest band gap and open cage-like structure,
Ti-MOB
exhibited effective photocatalytic degradation of rhodamine B.
Four substituted benzoate-anchored decanuclear TOCs featuring an unprecedented defective double-cubane geometry are solvothermally synthesized with high yield based on DMF solvent. |
| doi_str_mv | 10.1039/d2ce01653b |
| format | Article |
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10
(μ
3
-O)
12
(L)
6
(O
i
Pr)
10
(DMF)
2
] (
Ti-L
) (
L
= 4-methylbenzoate (
MB
), 3,5-di-
tert
-butylbenzoate (
DTBB
), 4-methoxybenzoate (
MOB
) and 4-methyl-3,5-dinitrobenzoate (
MDNB
)) with the same coordination environments have been solvothermally synthesized with high yield between benzoic acid derivatives and Ti(O
i
Pr)
4
. Single crystal X-ray diffraction analysis confirmed that
Ti-L
presents an open cage-like structure made up of a substituted benzoate-anchored decanuclear titanium-oxo cluster featuring an unprecedented defective double-cubane geometry. The photophysical performance of
Ti-L
demonstrated that strong electron-withdrawing substituent groups on the benzoate skeleton are beneficial to the redshift of the absorption position and the decrease of the band gap for the TOCs. Due to the synergistic effects of its lowest band gap and open cage-like structure,
Ti-MOB
exhibited effective photocatalytic degradation of rhodamine B.
Four substituted benzoate-anchored decanuclear TOCs featuring an unprecedented defective double-cubane geometry are solvothermally synthesized with high yield based on DMF solvent.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d2ce01653b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Benzoates ; Benzoic acid ; Cages ; Clusters ; Cubane ; Energy gap ; Photodegradation ; Red shift ; Rhodamine ; Single crystals ; Substitutes ; Synergistic effect ; Titanium</subject><ispartof>CrystEngComm, 2023-03, Vol.25 (11), p.1617-1625</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-3d1700c920f0101d71f6903e7d682c8dafce1c233c4d58b8fb5daaba1fe13bf63</cites><orcidid>0000-0001-5142-5461</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Pei, Xin-Yue</creatorcontrib><creatorcontrib>He, Ying</creatorcontrib><creatorcontrib>Wang, Jia-Yin</creatorcontrib><creatorcontrib>Wang, Hong-Yan</creatorcontrib><creatorcontrib>Bo, Qi-Bing</creatorcontrib><title>Substituted benzoate-anchored decanuclear titanium-oxo clusters featuring an unprecedented defective double-cubane geometry</title><title>CrystEngComm</title><description>Based on DMF solvent, four titanium-oxo clusters (TOCs) [Ti
10
(μ
3
-O)
12
(L)
6
(O
i
Pr)
10
(DMF)
2
] (
Ti-L
) (
L
= 4-methylbenzoate (
MB
), 3,5-di-
tert
-butylbenzoate (
DTBB
), 4-methoxybenzoate (
MOB
) and 4-methyl-3,5-dinitrobenzoate (
MDNB
)) with the same coordination environments have been solvothermally synthesized with high yield between benzoic acid derivatives and Ti(O
i
Pr)
4
. Single crystal X-ray diffraction analysis confirmed that
Ti-L
presents an open cage-like structure made up of a substituted benzoate-anchored decanuclear titanium-oxo cluster featuring an unprecedented defective double-cubane geometry. The photophysical performance of
Ti-L
demonstrated that strong electron-withdrawing substituent groups on the benzoate skeleton are beneficial to the redshift of the absorption position and the decrease of the band gap for the TOCs. Due to the synergistic effects of its lowest band gap and open cage-like structure,
Ti-MOB
exhibited effective photocatalytic degradation of rhodamine B.
Four substituted benzoate-anchored decanuclear TOCs featuring an unprecedented defective double-cubane geometry are solvothermally synthesized with high yield based on DMF solvent.</description><subject>Benzoates</subject><subject>Benzoic acid</subject><subject>Cages</subject><subject>Clusters</subject><subject>Cubane</subject><subject>Energy gap</subject><subject>Photodegradation</subject><subject>Red shift</subject><subject>Rhodamine</subject><subject>Single crystals</subject><subject>Substitutes</subject><subject>Synergistic effect</subject><subject>Titanium</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkE1LAzEQhoMoWKsX70LAm7CabLa726PW-gEFD-p5SSaTumWb1HyI1T_v2op6mmF45n3hIeSYs3POxPhC54CMlyOhdsiAF2WZ1UyI3X_7PjkIYcEYLzhnA_L5mFSIbUwRNVVoP5yMmEkLL873F40gbYIOpac9JW2blpl7dxS6FCL6QA3KmHxr51RamuzKI6BGGzfPBiG2b0i1S6rDDJKSFukc3RKjXx-SPSO7gEc_c0ieb6ZPk7ts9nB7P7mcZZAXLGZC84oxGOfMMM64rrgpx0xgpcs6h1pLA8ghFwIKPapVbdRIS6kkN8iFMqUYktNt7sq714QhNguXvO0rm7yqy14KF0VPnW0p8C4Ej6ZZ-XYp_brhrPmW21znk-lG7lUPn2xhH-CX-5MvvgD3f3oA</recordid><startdate>20230313</startdate><enddate>20230313</enddate><creator>Pei, Xin-Yue</creator><creator>He, Ying</creator><creator>Wang, Jia-Yin</creator><creator>Wang, Hong-Yan</creator><creator>Bo, Qi-Bing</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5142-5461</orcidid></search><sort><creationdate>20230313</creationdate><title>Substituted benzoate-anchored decanuclear titanium-oxo clusters featuring an unprecedented defective double-cubane geometry</title><author>Pei, Xin-Yue ; He, Ying ; Wang, Jia-Yin ; Wang, Hong-Yan ; Bo, Qi-Bing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-3d1700c920f0101d71f6903e7d682c8dafce1c233c4d58b8fb5daaba1fe13bf63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Benzoates</topic><topic>Benzoic acid</topic><topic>Cages</topic><topic>Clusters</topic><topic>Cubane</topic><topic>Energy gap</topic><topic>Photodegradation</topic><topic>Red shift</topic><topic>Rhodamine</topic><topic>Single crystals</topic><topic>Substitutes</topic><topic>Synergistic effect</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pei, Xin-Yue</creatorcontrib><creatorcontrib>He, Ying</creatorcontrib><creatorcontrib>Wang, Jia-Yin</creatorcontrib><creatorcontrib>Wang, Hong-Yan</creatorcontrib><creatorcontrib>Bo, Qi-Bing</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pei, Xin-Yue</au><au>He, Ying</au><au>Wang, Jia-Yin</au><au>Wang, Hong-Yan</au><au>Bo, Qi-Bing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Substituted benzoate-anchored decanuclear titanium-oxo clusters featuring an unprecedented defective double-cubane geometry</atitle><jtitle>CrystEngComm</jtitle><date>2023-03-13</date><risdate>2023</risdate><volume>25</volume><issue>11</issue><spage>1617</spage><epage>1625</epage><pages>1617-1625</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Based on DMF solvent, four titanium-oxo clusters (TOCs) [Ti
10
(μ
3
-O)
12
(L)
6
(O
i
Pr)
10
(DMF)
2
] (
Ti-L
) (
L
= 4-methylbenzoate (
MB
), 3,5-di-
tert
-butylbenzoate (
DTBB
), 4-methoxybenzoate (
MOB
) and 4-methyl-3,5-dinitrobenzoate (
MDNB
)) with the same coordination environments have been solvothermally synthesized with high yield between benzoic acid derivatives and Ti(O
i
Pr)
4
. Single crystal X-ray diffraction analysis confirmed that
Ti-L
presents an open cage-like structure made up of a substituted benzoate-anchored decanuclear titanium-oxo cluster featuring an unprecedented defective double-cubane geometry. The photophysical performance of
Ti-L
demonstrated that strong electron-withdrawing substituent groups on the benzoate skeleton are beneficial to the redshift of the absorption position and the decrease of the band gap for the TOCs. Due to the synergistic effects of its lowest band gap and open cage-like structure,
Ti-MOB
exhibited effective photocatalytic degradation of rhodamine B.
Four substituted benzoate-anchored decanuclear TOCs featuring an unprecedented defective double-cubane geometry are solvothermally synthesized with high yield based on DMF solvent.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2ce01653b</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-5142-5461</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2023-03, Vol.25 (11), p.1617-1625 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2CE01653B |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzoates Benzoic acid Cages Clusters Cubane Energy gap Photodegradation Red shift Rhodamine Single crystals Substitutes Synergistic effect Titanium |
| title | Substituted benzoate-anchored decanuclear titanium-oxo clusters featuring an unprecedented defective double-cubane geometry |
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