The structure of methanol at 5.09 GPa: the fortuitous formation of a new high-pressure phase
The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction. The polymorph crystallises in the monoclinic space group, P 2 1 / c , with twelve molecules in the unit cell, and exhibits a 4-membered hydrogen bonded ring struc...
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| Veröffentlicht in: | CrystEngComm 2022-10, Vol.24 (4), p.713-718 |
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| creator | Aldum, J. Collen Jones, Isabelle McGonigal, Paul R Spagnoli, Dino Stapleton, Nicholas D Turner, Gemma F Moggach, Stephen A |
| description | The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction. The polymorph crystallises in the monoclinic space group,
P
2
1
/
c
, with twelve molecules in the unit cell, and exhibits a 4-membered hydrogen bonded ring structure, never previously observed in any crystal structure of methanol. The phase was also serendipitously seeded by the presence of another crystallite, giving rise to suitable crystallisation conditions 2 GPa lower than previously reported.
The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction. |
| doi_str_mv | 10.1039/d2ce01157c |
| format | Article |
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P
2
1
/
c
, with twelve molecules in the unit cell, and exhibits a 4-membered hydrogen bonded ring structure, never previously observed in any crystal structure of methanol. The phase was also serendipitously seeded by the presence of another crystallite, giving rise to suitable crystallisation conditions 2 GPa lower than previously reported.
The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d2ce01157c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Crystal structure ; Crystallites ; Crystallization ; Methanol ; Ring structures ; Single crystals ; Unit cell</subject><ispartof>CrystEngComm, 2022-10, Vol.24 (4), p.713-718</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c211t-88b47e35fa0394a7c6e8b78894f5cd1398624275c36fe55f73499397b928a1b03</citedby><cites>FETCH-LOGICAL-c211t-88b47e35fa0394a7c6e8b78894f5cd1398624275c36fe55f73499397b928a1b03</cites><orcidid>0000-0002-8538-7579 ; 0000-0001-6367-4748 ; 0000-0001-5339-7070 ; 0000-0002-4315-8815</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27904,27905</link.rule.ids></links><search><creatorcontrib>Aldum, J. Collen</creatorcontrib><creatorcontrib>Jones, Isabelle</creatorcontrib><creatorcontrib>McGonigal, Paul R</creatorcontrib><creatorcontrib>Spagnoli, Dino</creatorcontrib><creatorcontrib>Stapleton, Nicholas D</creatorcontrib><creatorcontrib>Turner, Gemma F</creatorcontrib><creatorcontrib>Moggach, Stephen A</creatorcontrib><title>The structure of methanol at 5.09 GPa: the fortuitous formation of a new high-pressure phase</title><title>CrystEngComm</title><description>The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction. The polymorph crystallises in the monoclinic space group,
P
2
1
/
c
, with twelve molecules in the unit cell, and exhibits a 4-membered hydrogen bonded ring structure, never previously observed in any crystal structure of methanol. The phase was also serendipitously seeded by the presence of another crystallite, giving rise to suitable crystallisation conditions 2 GPa lower than previously reported.
The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction.</description><subject>Crystal structure</subject><subject>Crystallites</subject><subject>Crystallization</subject><subject>Methanol</subject><subject>Ring structures</subject><subject>Single crystals</subject><subject>Unit cell</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpNkM9LwzAcxYMoOKcX70LAm9CZn03iTeqcwkAP8yaUNEtsx9bUJEX8722dqKfvO3ze-_IeAOcYzTCi6npNjEUYc2EOwASzPM8kovTwnz4GJzFuEMIMYzQBr6vawphCb1IfLPQO7myqdeu3UCfIZ0jBxbO-gWnAnA-pb5Lv4yh3OjW-HR0atvYD1s1bnXXBxjgGdbWO9hQcOb2N9uznTsHL_XxVPGTLp8VjcbvMDME4ZVJWTFjKnR4qMC1MbmUlpFTMcbPGVMmcMCK4obmznDtBmVJUiUoRqXGF6BRc7nO74N97G1O58X1oh5clEYSToWs-Uld7ygQfY7Cu7EKz0-GzxKgc1yvvSDH_Xq8Y4Is9HKL55f7WpV-RlGm3</recordid><startdate>20221017</startdate><enddate>20221017</enddate><creator>Aldum, J. Collen</creator><creator>Jones, Isabelle</creator><creator>McGonigal, Paul R</creator><creator>Spagnoli, Dino</creator><creator>Stapleton, Nicholas D</creator><creator>Turner, Gemma F</creator><creator>Moggach, Stephen A</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-8538-7579</orcidid><orcidid>https://orcid.org/0000-0001-6367-4748</orcidid><orcidid>https://orcid.org/0000-0001-5339-7070</orcidid><orcidid>https://orcid.org/0000-0002-4315-8815</orcidid></search><sort><creationdate>20221017</creationdate><title>The structure of methanol at 5.09 GPa: the fortuitous formation of a new high-pressure phase</title><author>Aldum, J. Collen ; Jones, Isabelle ; McGonigal, Paul R ; Spagnoli, Dino ; Stapleton, Nicholas D ; Turner, Gemma F ; Moggach, Stephen A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c211t-88b47e35fa0394a7c6e8b78894f5cd1398624275c36fe55f73499397b928a1b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Crystal structure</topic><topic>Crystallites</topic><topic>Crystallization</topic><topic>Methanol</topic><topic>Ring structures</topic><topic>Single crystals</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aldum, J. Collen</creatorcontrib><creatorcontrib>Jones, Isabelle</creatorcontrib><creatorcontrib>McGonigal, Paul R</creatorcontrib><creatorcontrib>Spagnoli, Dino</creatorcontrib><creatorcontrib>Stapleton, Nicholas D</creatorcontrib><creatorcontrib>Turner, Gemma F</creatorcontrib><creatorcontrib>Moggach, Stephen A</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aldum, J. Collen</au><au>Jones, Isabelle</au><au>McGonigal, Paul R</au><au>Spagnoli, Dino</au><au>Stapleton, Nicholas D</au><au>Turner, Gemma F</au><au>Moggach, Stephen A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The structure of methanol at 5.09 GPa: the fortuitous formation of a new high-pressure phase</atitle><jtitle>CrystEngComm</jtitle><date>2022-10-17</date><risdate>2022</risdate><volume>24</volume><issue>4</issue><spage>713</spage><epage>718</epage><pages>713-718</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction. The polymorph crystallises in the monoclinic space group,
P
2
1
/
c
, with twelve molecules in the unit cell, and exhibits a 4-membered hydrogen bonded ring structure, never previously observed in any crystal structure of methanol. The phase was also serendipitously seeded by the presence of another crystallite, giving rise to suitable crystallisation conditions 2 GPa lower than previously reported.
The crystal structure of a new polymorph of methanol (the polymorph) has been determined at 5.09 GPa by single crystal X-ray diffraction.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2ce01157c</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-8538-7579</orcidid><orcidid>https://orcid.org/0000-0001-6367-4748</orcidid><orcidid>https://orcid.org/0000-0001-5339-7070</orcidid><orcidid>https://orcid.org/0000-0002-4315-8815</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2022-10, Vol.24 (4), p.713-718 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D2CE01157C |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystal structure Crystallites Crystallization Methanol Ring structures Single crystals Unit cell |
| title | The structure of methanol at 5.09 GPa: the fortuitous formation of a new high-pressure phase |
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