Polymer mechanochemistry for the release of small cargoes

The field of force-induced release of small cargoes within polymeric materials has experienced rapid growth over the past decade, not only including achieving diversified functional materials that report force, trigger degradation, activate drugs and release catalysts, but also involving investigati...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (31), p.4813-4824
Hauptverfasser: Shen, Hang, Cao, Yunzheng, Lv, Miaojiang, Sheng, Qinxin, Zhang, Zhengbiao
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container_end_page 4824
container_issue 31
container_start_page 4813
container_title Chemical communications (Cambridge, England)
container_volume 58
creator Shen, Hang
Cao, Yunzheng
Lv, Miaojiang
Sheng, Qinxin
Zhang, Zhengbiao
description The field of force-induced release of small cargoes within polymeric materials has experienced rapid growth over the past decade, not only including achieving diversified functional materials that report force, trigger degradation, activate drugs and release catalysts, but also involving investigations on the interesting force-coupled reactivity of mechanophores, such as ferrocenes. In this highlight article, we review the recent progress on polymer mechanochemistry that releases small cargoes, including small molecules and metal ions. Since mechanophores play a key role in force-responsive materials, we introduce the progress by discussing different types of mechanophores and their mechanochemical reactions for the release of acids, gases, fluorophores, drugs, iron ions, and so on. At the end, we provide our perspectives on the remaining challenges and future targets in this growing field. We review the recent progress on polymer mechanochemistry that releases small cargoes, followed by our perspectives on future developments.
doi_str_mv 10.1039/d2cc00147k
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysis
Chemical compounds
Drugs
Ferrocenes
Fluorescent Dyes
Functional materials
Mechanical Phenomena
Polymers
Polymers - chemistry
title Polymer mechanochemistry for the release of small cargoes
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