Shape-controlled mesoporous melamine-formaldehyde polymers by solvent-assisted curing
We report a new strategy, namely solvent-assisted curing, for developing a porous network into polymeric materials. A simple thermal process for nonporous melamine formaldehyde polymers in aprotic solvents affords porous characteristics with an exceptionally high surface area, resulting from the swe...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2022-04, Vol.1 (14), p.825-83 |
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| container_end_page | 83 |
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| container_issue | 14 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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| creator | Kang, Inah Yoon, Young Rok Lee, Seul Ah Kim, Seong Jong Kim, Sang Youl |
| description | We report a new strategy, namely solvent-assisted curing, for developing a porous network into polymeric materials. A simple thermal process for nonporous melamine formaldehyde polymers in aprotic solvents affords porous characteristics with an exceptionally high surface area, resulting from the swelling and exclusion of a part of the polymeric structure aided by the solvent. The porous properties can be determined by selecting solvents and the monomer ratio that affects the degree of crosslinking. Furthermore, by tailoring the shape of precursor materials, we prepared the porous polymer in a variety of forms, such as particles and a monolith. The resulting material was exploited for CO
2
adsorption and proved to be a potential gas sorbent. This versatile approach can be combined with other polymeric materials and provides an approach toward expanding the range of porous materials.
We report a new strategy, namely solvent-assisted curing, for developing a porous network into polymeric materials. |
| doi_str_mv | 10.1039/d1ta10921a |
| format | Article |
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2
adsorption and proved to be a potential gas sorbent. This versatile approach can be combined with other polymeric materials and provides an approach toward expanding the range of porous materials.
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2
adsorption and proved to be a potential gas sorbent. This versatile approach can be combined with other polymeric materials and provides an approach toward expanding the range of porous materials.
We report a new strategy, namely solvent-assisted curing, for developing a porous network into polymeric materials.</description><subject>Carbon dioxide</subject><subject>Crosslinking</subject><subject>Curing</subject><subject>Formaldehyde</subject><subject>Melamine</subject><subject>Polymers</subject><subject>Porous materials</subject><subject>Solvents</subject><subject>Sorbents</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkE1Lw0AQhhdRsGgv3oWAN2F1v5LdPZb6CQUPtuewzU5sSpKNO4mQf2-0Uucy7-F5Z-Ah5IqzO86kvfe8d5xZwd0JmQmWMqqVzU6P2ZhzMkfcs2kMY5m1M7J537kOaBHaPoa6Bp80gKELMQw4xdo1VQu0DLFxtYfd6CHpQj02EDHZjgmG-gvanjrECvupXQyxaj8uyVnpaoT5374gm6fH9fKFrt6eX5eLFS0E5z3lTLgtSKHAC2O847z0NhVbbxXXQqpSama0l96AykCkxkulMy-NcpBqY-UFuTnc7WL4HAD7fB-G2E4vc5GpzDJtjJmo2wNVxIAYocy7WDUujjln-Y-5_IGvF7_mFhN8fYAjFkfu36z8BkDbawg</recordid><startdate>20220405</startdate><enddate>20220405</enddate><creator>Kang, Inah</creator><creator>Yoon, Young Rok</creator><creator>Lee, Seul Ah</creator><creator>Kim, Seong Jong</creator><creator>Kim, Sang Youl</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0001-6229-1657</orcidid><orcidid>https://orcid.org/0000-0003-4106-1996</orcidid><orcidid>https://orcid.org/0000-0002-5988-4942</orcidid></search><sort><creationdate>20220405</creationdate><title>Shape-controlled mesoporous melamine-formaldehyde polymers by solvent-assisted curing</title><author>Kang, Inah ; Yoon, Young Rok ; Lee, Seul Ah ; Kim, Seong Jong ; Kim, Sang Youl</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c211t-102abe324ed288da11fd952bd9417234f37087d3d8e46e258d3476d384ae57893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon dioxide</topic><topic>Crosslinking</topic><topic>Curing</topic><topic>Formaldehyde</topic><topic>Melamine</topic><topic>Polymers</topic><topic>Porous materials</topic><topic>Solvents</topic><topic>Sorbents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kang, Inah</creatorcontrib><creatorcontrib>Yoon, Young Rok</creatorcontrib><creatorcontrib>Lee, Seul Ah</creatorcontrib><creatorcontrib>Kim, Seong Jong</creatorcontrib><creatorcontrib>Kim, Sang Youl</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kang, Inah</au><au>Yoon, Young Rok</au><au>Lee, Seul Ah</au><au>Kim, Seong Jong</au><au>Kim, Sang Youl</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shape-controlled mesoporous melamine-formaldehyde polymers by solvent-assisted curing</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2022-04-05</date><risdate>2022</risdate><volume>1</volume><issue>14</issue><spage>825</spage><epage>83</epage><pages>825-83</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>We report a new strategy, namely solvent-assisted curing, for developing a porous network into polymeric materials. A simple thermal process for nonporous melamine formaldehyde polymers in aprotic solvents affords porous characteristics with an exceptionally high surface area, resulting from the swelling and exclusion of a part of the polymeric structure aided by the solvent. The porous properties can be determined by selecting solvents and the monomer ratio that affects the degree of crosslinking. Furthermore, by tailoring the shape of precursor materials, we prepared the porous polymer in a variety of forms, such as particles and a monolith. The resulting material was exploited for CO
2
adsorption and proved to be a potential gas sorbent. This versatile approach can be combined with other polymeric materials and provides an approach toward expanding the range of porous materials.
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| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2022-04, Vol.1 (14), p.825-83 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_D1TA10921A |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Carbon dioxide Crosslinking Curing Formaldehyde Melamine Polymers Porous materials Solvents Sorbents |
| title | Shape-controlled mesoporous melamine-formaldehyde polymers by solvent-assisted curing |
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