An organophotocatalytic late-stage N-CH 3 oxidation of trialkylamines to N -formamides with O 2 in continuous flow

We report an organophotocatalytic, N-CH -selective oxidation of trialkylamines in continuous flow. Based on the 9,10-dicyanoanthracene (DCA) core, a new catalyst (DCAS) was designed with solubilizing groups for flow processing. This allowed O to be harnessed as a sustainable oxidant for late-stage p...

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Veröffentlicht in:Chemical science (Cambridge) 2022-02, Vol.13 (7), p.1912-1924
Hauptverfasser: Mandigma, Mark John P, Žurauskas, Jonas, MacGregor, Callum I, Edwards, Lee J, Shahin, Ahmed, d'Heureuse, Ludwig, Yip, Philip, Birch, David J S, Gruber, Thomas, Heilmann, Jörg, John, Matthew P, Barham, Joshua P
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Sprache:eng
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