Role of thiol oxidation by air in the mechanism of the self-initiated thermal thiol-ene polymerization

A spontaneous thiol-ene polymerization has been reported in the literature for a broad range of monomers, generally under conditions avoiding solvents, heating and the intentional formation of radicals. In the search for a mechanism accounting for the self-initiated thiol-ene polymerization, this st...

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Veröffentlicht in:	Polymer chemistry 2021-11, Vol.12 (45), p.6594-665
Hauptverfasser:	Le, Cuong Minh Quoc, Morlet-Savary, Fabrice, Chemtob, Abraham
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Electron transfer Hydrogen bonding Hydrogen bonds NMR spectroscopy Oxidation Oxygen Polarization Polymer chemistry Polymerization Polymers Solvation Solvents
Online-Zugang:	Volltext
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