Light-mediated controlled and classical polymerizations of less-activated monomers under high-pressure conditions
The innovative combination of light and high pressure allowed us to effectively polymerize for the first time challenging ionic 1,2,4-triazolium-based ionic liquids (ILs) with fluorinate anions (MetTRI/NTF) and non-ionic vinyl acetate (VAc), both classified as less-activated monomers (LAMs). Three d...
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| Veröffentlicht in: | Polymer chemistry 2021-08, Vol.12 (3), p.4418-4427 |
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| container_title | Polymer chemistry |
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| creator | Maksym, Paulina Tarnacka, Magdalena Bernat, Roksana Dzienia, Andrzej Szelwicka, Anna Hachu a, Barbara Chrobok, Anna Paluch, Marian Kami ski, Kamil |
| description | The innovative combination of light and high pressure allowed us to effectively polymerize for the first time challenging ionic 1,2,4-triazolium-based ionic liquids (ILs) with fluorinate anions (MetTRI/NTF) and non-ionic vinyl acetate (VAc), both classified as less-activated monomers (LAMs). Three different synthetic photo-induced protocols comprising controlled metal-free organocatalyzed Atom Transfer Radical Polymerization (
O
-ATRP), chain transfer to solvent free-radical polymerization (CT-FRP), and classical free-radical polymerization (FRP) were investigated. As a result, well-defined polymers with a wide range of molecular weights
M
n
and different concentrations of OH domains incorporated into their polymer backbones in a very short time frame (5-120 min) were produced. Having a series of 1,2,4-triazolium-based poly(ionic liquid)s (PILs), a unique opportunity appeared to study the relationship between their molecular weights, glass transition temperature, and dc conductivity, undoubtedly enriching the library of tailored PILs of enhanced conductivity, a critical parameter determining their serviceability.
An entirely new robust setup combining light and high pressure was applied to polymerize less-activated monomers
via
three different "green" polymerization protocols. |
| doi_str_mv | 10.1039/d1py00738f |
| format | Article |
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O
-ATRP), chain transfer to solvent free-radical polymerization (CT-FRP), and classical free-radical polymerization (FRP) were investigated. As a result, well-defined polymers with a wide range of molecular weights
M
n
and different concentrations of OH domains incorporated into their polymer backbones in a very short time frame (5-120 min) were produced. Having a series of 1,2,4-triazolium-based poly(ionic liquid)s (PILs), a unique opportunity appeared to study the relationship between their molecular weights, glass transition temperature, and dc conductivity, undoubtedly enriching the library of tailored PILs of enhanced conductivity, a critical parameter determining their serviceability.
An entirely new robust setup combining light and high pressure was applied to polymerize less-activated monomers
via
three different "green" polymerization protocols.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/d1py00738f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chain transfer ; Free radical polymerization ; Free radicals ; Glass transition temperature ; Ionic liquids ; Ions ; Molecular weight ; Monomers ; Polymer chemistry ; Polymerization ; Radicals ; Vinyl acetate</subject><ispartof>Polymer chemistry, 2021-08, Vol.12 (3), p.4418-4427</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-aeed97069bed2ce0cca89a9f377b6b36d5583b0f39959e73986724d21718f2e83</citedby><cites>FETCH-LOGICAL-c281t-aeed97069bed2ce0cca89a9f377b6b36d5583b0f39959e73986724d21718f2e83</cites><orcidid>0000-0001-8324-856X ; 0000-0001-9886-1076 ; 0000-0003-2439-4246 ; 0000-0002-9444-3114 ; 0000-0001-7176-7100 ; 0000-0002-7280-8557 ; 0000-0002-5871-0203 ; 0000-0002-9628-0224 ; 0000-0002-8506-7102</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Maksym, Paulina</creatorcontrib><creatorcontrib>Tarnacka, Magdalena</creatorcontrib><creatorcontrib>Bernat, Roksana</creatorcontrib><creatorcontrib>Dzienia, Andrzej</creatorcontrib><creatorcontrib>Szelwicka, Anna</creatorcontrib><creatorcontrib>Hachu a, Barbara</creatorcontrib><creatorcontrib>Chrobok, Anna</creatorcontrib><creatorcontrib>Paluch, Marian</creatorcontrib><creatorcontrib>Kami ski, Kamil</creatorcontrib><title>Light-mediated controlled and classical polymerizations of less-activated monomers under high-pressure conditions</title><title>Polymer chemistry</title><description>The innovative combination of light and high pressure allowed us to effectively polymerize for the first time challenging ionic 1,2,4-triazolium-based ionic liquids (ILs) with fluorinate anions (MetTRI/NTF) and non-ionic vinyl acetate (VAc), both classified as less-activated monomers (LAMs). Three different synthetic photo-induced protocols comprising controlled metal-free organocatalyzed Atom Transfer Radical Polymerization (
O
-ATRP), chain transfer to solvent free-radical polymerization (CT-FRP), and classical free-radical polymerization (FRP) were investigated. As a result, well-defined polymers with a wide range of molecular weights
M
n
and different concentrations of OH domains incorporated into their polymer backbones in a very short time frame (5-120 min) were produced. Having a series of 1,2,4-triazolium-based poly(ionic liquid)s (PILs), a unique opportunity appeared to study the relationship between their molecular weights, glass transition temperature, and dc conductivity, undoubtedly enriching the library of tailored PILs of enhanced conductivity, a critical parameter determining their serviceability.
An entirely new robust setup combining light and high pressure was applied to polymerize less-activated monomers
via
three different "green" polymerization protocols.</description><subject>Chain transfer</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Glass transition temperature</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Molecular weight</subject><subject>Monomers</subject><subject>Polymer chemistry</subject><subject>Polymerization</subject><subject>Radicals</subject><subject>Vinyl acetate</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkM1Lw0AQxRdRsNRevAsBb0J0P5Ld7FGqVaGgBz14Cpvdid2SZNPdRKh_vdtW6lxmBn7vDfMQuiT4lmAm7wzptxgLVtQnaEJELlMpOT09znl2jmYhrHEsRjLK-ARtlvZrNaQtGKsGMIl23eBd08RRdXFtVAhWqybpXbNtwdsfNVjXhcTVSQMhpEoP9nsvbV3nIhGSsTPgk1U0TnsfmdHDztfYvfICndWqCTD761P0sXh8nz-ny9enl_n9MtW0IEOqAIwUmMsKDNWAtVaFVLJmQlS8YtzkecEqXLP4lwTBZMEFzQwlghQ1hYJN0fXBt_duM0IYyrUbfRdPljTPBcsY4zvq5kBp70LwUJe9t63y25Lgcpdq-UDePvepLiJ8dYB90EfuP3X2C2hYdpU</recordid><startdate>20210814</startdate><enddate>20210814</enddate><creator>Maksym, Paulina</creator><creator>Tarnacka, Magdalena</creator><creator>Bernat, Roksana</creator><creator>Dzienia, Andrzej</creator><creator>Szelwicka, Anna</creator><creator>Hachu a, Barbara</creator><creator>Chrobok, Anna</creator><creator>Paluch, Marian</creator><creator>Kami ski, Kamil</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8324-856X</orcidid><orcidid>https://orcid.org/0000-0001-9886-1076</orcidid><orcidid>https://orcid.org/0000-0003-2439-4246</orcidid><orcidid>https://orcid.org/0000-0002-9444-3114</orcidid><orcidid>https://orcid.org/0000-0001-7176-7100</orcidid><orcidid>https://orcid.org/0000-0002-7280-8557</orcidid><orcidid>https://orcid.org/0000-0002-5871-0203</orcidid><orcidid>https://orcid.org/0000-0002-9628-0224</orcidid><orcidid>https://orcid.org/0000-0002-8506-7102</orcidid></search><sort><creationdate>20210814</creationdate><title>Light-mediated controlled and classical polymerizations of less-activated monomers under high-pressure conditions</title><author>Maksym, Paulina ; Tarnacka, Magdalena ; Bernat, Roksana ; Dzienia, Andrzej ; Szelwicka, Anna ; Hachu a, Barbara ; Chrobok, Anna ; Paluch, Marian ; Kami ski, Kamil</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-aeed97069bed2ce0cca89a9f377b6b36d5583b0f39959e73986724d21718f2e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chain transfer</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Glass transition temperature</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Molecular weight</topic><topic>Monomers</topic><topic>Polymer chemistry</topic><topic>Polymerization</topic><topic>Radicals</topic><topic>Vinyl acetate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maksym, Paulina</creatorcontrib><creatorcontrib>Tarnacka, Magdalena</creatorcontrib><creatorcontrib>Bernat, Roksana</creatorcontrib><creatorcontrib>Dzienia, Andrzej</creatorcontrib><creatorcontrib>Szelwicka, Anna</creatorcontrib><creatorcontrib>Hachu a, Barbara</creatorcontrib><creatorcontrib>Chrobok, Anna</creatorcontrib><creatorcontrib>Paluch, Marian</creatorcontrib><creatorcontrib>Kami ski, Kamil</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maksym, Paulina</au><au>Tarnacka, Magdalena</au><au>Bernat, Roksana</au><au>Dzienia, Andrzej</au><au>Szelwicka, Anna</au><au>Hachu a, Barbara</au><au>Chrobok, Anna</au><au>Paluch, Marian</au><au>Kami ski, Kamil</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Light-mediated controlled and classical polymerizations of less-activated monomers under high-pressure conditions</atitle><jtitle>Polymer chemistry</jtitle><date>2021-08-14</date><risdate>2021</risdate><volume>12</volume><issue>3</issue><spage>4418</spage><epage>4427</epage><pages>4418-4427</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>The innovative combination of light and high pressure allowed us to effectively polymerize for the first time challenging ionic 1,2,4-triazolium-based ionic liquids (ILs) with fluorinate anions (MetTRI/NTF) and non-ionic vinyl acetate (VAc), both classified as less-activated monomers (LAMs). Three different synthetic photo-induced protocols comprising controlled metal-free organocatalyzed Atom Transfer Radical Polymerization (
O
-ATRP), chain transfer to solvent free-radical polymerization (CT-FRP), and classical free-radical polymerization (FRP) were investigated. As a result, well-defined polymers with a wide range of molecular weights
M
n
and different concentrations of OH domains incorporated into their polymer backbones in a very short time frame (5-120 min) were produced. Having a series of 1,2,4-triazolium-based poly(ionic liquid)s (PILs), a unique opportunity appeared to study the relationship between their molecular weights, glass transition temperature, and dc conductivity, undoubtedly enriching the library of tailored PILs of enhanced conductivity, a critical parameter determining their serviceability.
An entirely new robust setup combining light and high pressure was applied to polymerize less-activated monomers
via
three different "green" polymerization protocols.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1py00738f</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-8324-856X</orcidid><orcidid>https://orcid.org/0000-0001-9886-1076</orcidid><orcidid>https://orcid.org/0000-0003-2439-4246</orcidid><orcidid>https://orcid.org/0000-0002-9444-3114</orcidid><orcidid>https://orcid.org/0000-0001-7176-7100</orcidid><orcidid>https://orcid.org/0000-0002-7280-8557</orcidid><orcidid>https://orcid.org/0000-0002-5871-0203</orcidid><orcidid>https://orcid.org/0000-0002-9628-0224</orcidid><orcidid>https://orcid.org/0000-0002-8506-7102</orcidid></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Chain transfer Free radical polymerization Free radicals Glass transition temperature Ionic liquids Ions Molecular weight Monomers Polymer chemistry Polymerization Radicals Vinyl acetate |
| title | Light-mediated controlled and classical polymerizations of less-activated monomers under high-pressure conditions |
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