Designing a new basic ionic liquid [DHIM][OH] as a task specific bifunctional catalyst for facile microwave assisted metal free synthesis of 5-amino-1,2,3-triazoles

Designing a new basic ionic liquid [DHIM][OH] as a task specific bifunctional catalyst for facile microwave assisted metal free synthesis of 5-amino-1,2,3-triazoles

A green protocol for the synthesis of a series of 5-amino-1,2,3-triazoles from benzyl cyanide and phenyl azide derivatives catalyzed by the novel bifunctional ionic liquid [DHIM][OH] under microwave irradiation has been developed. The bifunctional ionic liquid which acts as a catalyst can be accesse...

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Veröffentlicht in:New journal of chemistry 2021-08, Vol.45 (29), p.12792-12797
Hauptverfasser: Dutta, Bidyutjyoti, Garg, Anirban, Phukan, Parmita, Kulshrestha, Akshay, Kumar, Arvind, Sarma, Diganta
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Sprache:eng
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Catalysts
Ionic liquids
Ions
Irradiation
Triazoles
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container_end_page 12797
container_issue 29
container_start_page 12792
container_title New journal of chemistry
container_volume 45
creator Dutta, Bidyutjyoti
Garg, Anirban
Phukan, Parmita
Kulshrestha, Akshay
Kumar, Arvind
Sarma, Diganta
description A green protocol for the synthesis of a series of 5-amino-1,2,3-triazoles from benzyl cyanide and phenyl azide derivatives catalyzed by the novel bifunctional ionic liquid [DHIM][OH] under microwave irradiation has been developed. The bifunctional ionic liquid which acts as a catalyst can be accessed through rapid preparation via incorporation of microwave irradiation. To the best of our knowledge, the present approach is the first method to employ an organocatalyst under microwave irradiation to access rapid assembly of 5-amino-1,2,3-triazoles under mild conditions. Furthermore, small E -factor values associated with the products confirm greener attributes of the current protocol. A green protocol for the synthesis of a series of 5-amino-1,2,3-triazoles from benzyl cyanide and phenyl azide derivatives catalyzed by the novel bifunctional ionic liquid [DHIM][OH] under microwave irradiation has been developed.
doi_str_mv 10.1039/d1nj02391h
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysts
Ionic liquids
Ions
Irradiation
Triazoles
title Designing a new basic ionic liquid [DHIM][OH] as a task specific bifunctional catalyst for facile microwave assisted metal free synthesis of 5-amino-1,2,3-triazoles
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