Catalytic applications of zwitterionic transition metal compounds
This frontiers article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic catalysts in polymerization reactions, including the carbonylative polymerization of cyclic ethers, carbon-carbon coupl...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-01, Vol.51 (3), p.817-83 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Puerta-Oteo, Raquel Ojeda-Amador, Ana I Jiménez, M. Victoria Pérez-Torrente, Jesús J |
| description | This frontiers article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic catalysts in polymerization reactions, including the carbonylative polymerization of cyclic ethers, carbon-carbon coupling reactions, the asymmetric hydrogenation of unfunctionalized olefins, and the hydrofunctionalization of alkenes are reviewed. In addition, advances in the field of hydrogenation/dehydrogenation reactions related to energy applications, including the hydrogenation of CO
2
and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO
2
with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into γ-valerolactone, are also described.
Transition metal-based zwitterionic catalysts have been applied in a range of catalytic transformations. The relationship of the catalyst structure and potential applications is highlighted. |
| doi_str_mv | 10.1039/d1dt03746c |
| format | Article |
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2
and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO
2
with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into γ-valerolactone, are also described.
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2
and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO
2
with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into γ-valerolactone, are also described.
Transition metal-based zwitterionic catalysts have been applied in a range of catalytic transformations. The relationship of the catalyst structure and potential applications is highlighted.</description><subject>Alkenes</subject><subject>Amines</subject><subject>Carbon dioxide</subject><subject>Carbonyls</subject><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Coordination compounds</subject><subject>Dehydrogenation</subject><subject>Ethers</subject><subject>Formic acid</subject><subject>Hydrogenation</subject><subject>Lactic acid</subject><subject>Levulinic acid</subject><subject>Metal compounds</subject><subject>Polymerization</subject><subject>Transition metal compounds</subject><subject>Zwitterions</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkc1LxDAQxYMo7rp68a4UvIhQzVeT5rh0_YIFL-u5pEkKXdqmJimy_vVm3XUFTzPD-81jeAPAJYL3CBLxoJEOkHDK1BGYIsp5KjChx4ceswk4834NIcYww6dgQqiAlEE-BfNCBtluQqMSOQxto2RobO8TWydfn00IxsUxisHJ3jdbLelM3EiU7QY79tqfg5Natt5c7OsMvD89roqXdPn2_FrMl6kinISUalIpRgw3NUMIZ0hAXeUZY4oponhOM5JjSanKRWV0bjTJK11lUCjKa8wlmYHbne_g7MdofCi7xivTtrI3dvQlZgjCPFqLiN78Q9d2dH28LlIYopwJkUXqbkcpZ713pi4H13TSbUoEy22w5QItVj_BFhG-3luOVWf0Af1NMgJXO8B5dVD_PkO-AT6wfLY</recordid><startdate>20220117</startdate><enddate>20220117</enddate><creator>Puerta-Oteo, Raquel</creator><creator>Ojeda-Amador, Ana I</creator><creator>Jiménez, M. Victoria</creator><creator>Pérez-Torrente, Jesús J</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-3327-0918</orcidid><orcidid>https://orcid.org/0000-0002-0545-9107</orcidid></search><sort><creationdate>20220117</creationdate><title>Catalytic applications of zwitterionic transition metal compounds</title><author>Puerta-Oteo, Raquel ; Ojeda-Amador, Ana I ; Jiménez, M. Victoria ; Pérez-Torrente, Jesús J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-4d3bc63e7ef61125190db8566c6c3c7845382a44c89bed8ed38bdb509c47f27a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkenes</topic><topic>Amines</topic><topic>Carbon dioxide</topic><topic>Carbonyls</topic><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Coordination compounds</topic><topic>Dehydrogenation</topic><topic>Ethers</topic><topic>Formic acid</topic><topic>Hydrogenation</topic><topic>Lactic acid</topic><topic>Levulinic acid</topic><topic>Metal compounds</topic><topic>Polymerization</topic><topic>Transition metal compounds</topic><topic>Zwitterions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Puerta-Oteo, Raquel</creatorcontrib><creatorcontrib>Ojeda-Amador, Ana I</creatorcontrib><creatorcontrib>Jiménez, M. Victoria</creatorcontrib><creatorcontrib>Pérez-Torrente, Jesús J</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Puerta-Oteo, Raquel</au><au>Ojeda-Amador, Ana I</au><au>Jiménez, M. Victoria</au><au>Pérez-Torrente, Jesús J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic applications of zwitterionic transition metal compounds</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2022-01-17</date><risdate>2022</risdate><volume>51</volume><issue>3</issue><spage>817</spage><epage>83</epage><pages>817-83</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>This frontiers article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic catalysts in polymerization reactions, including the carbonylative polymerization of cyclic ethers, carbon-carbon coupling reactions, the asymmetric hydrogenation of unfunctionalized olefins, and the hydrofunctionalization of alkenes are reviewed. In addition, advances in the field of hydrogenation/dehydrogenation reactions related to energy applications, including the hydrogenation of CO
2
and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO
2
with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into γ-valerolactone, are also described.
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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-01, Vol.51 (3), p.817-83 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkenes Amines Carbon dioxide Carbonyls Catalysis Chemical reactions Coordination compounds Dehydrogenation Ethers Formic acid Hydrogenation Lactic acid Levulinic acid Metal compounds Polymerization Transition metal compounds Zwitterions |
| title | Catalytic applications of zwitterionic transition metal compounds |
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