Investigation on the catalytic behavior of a novel thulium-organic framework with a planar tetranuclear {Tm 4 } cluster as the active center for chemical CO 2 fixation

Herein, the exquisite combination of coplanar [Tm (CO ) (μ -OH) (μ -HCO )(OH ) ] clusters ({Tm }) and structure-oriented functional BDCP leads to the highly robust nanoporous {Tm }-organic framework {(Me NH )[Tm (BDCP) (μ -OH) (μ -HCO )(H O) ]·7DMF·5H O} (NUC-37, H BDCP = 2,6-bis(2,4-dicarboxylpheny...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-01, Vol.51 (2), p.532-540
Hauptverfasser:	Chen, Hongtai, Zhang, Zhengguo, Lv, Hongxiao, Liu, Shurong, Zhang, Xiutang
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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