BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure
A new beryllium-free zincoborate, BaZn 3 (BO 3 ) 2 F 2 , with a KBBF-type structure has been synthesized for the first time. The electrostatic force of interaction in BaZn 3 (BO 3 ) 2 F 2 provides better linkage in neighboring [ZnBO 3 F] ∞ single layers. BaZn 3 (BO 3 ) 2 F 2 is the first case of bor...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.50 (38), p.13216-13219 |
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| container_issue | 38 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Qiu, Haotian Xia, Ming Cai, Wenbing Yang, Zhihua Liu, Yanli Mutailipu, Miriding Pan, Shilie |
| description | A new beryllium-free zincoborate, BaZn
3
(BO
3
)
2
F
2
, with a KBBF-type structure has been synthesized for the first time. The electrostatic force of interaction in BaZn
3
(BO
3
)
2
F
2
provides better linkage in neighboring [ZnBO
3
F]
∞
single layers. BaZn
3
(BO
3
)
2
F
2
is the first case of borates with both [ZnO
3
F] tetrahedra and [ZnO
6
] octahedra, enriching the structural chemistry of borate system. All the coplanar [BO
3
] triangles align in the same direction with a high density, which endows BaZn
3
(BO
3
)
2
F
2
with a large birefringence of cal. 0.076 at 1064 nm. This work is of great significance to design beryllium-free borates with a KBBF-type structure. |
| doi_str_mv | 10.1039/D1DT02356J |
| format | Article |
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3
(BO
3
)
2
F
2
, with a KBBF-type structure has been synthesized for the first time. The electrostatic force of interaction in BaZn
3
(BO
3
)
2
F
2
provides better linkage in neighboring [ZnBO
3
F]
∞
single layers. BaZn
3
(BO
3
)
2
F
2
is the first case of borates with both [ZnO
3
F] tetrahedra and [ZnO
6
] octahedra, enriching the structural chemistry of borate system. All the coplanar [BO
3
] triangles align in the same direction with a high density, which endows BaZn
3
(BO
3
)
2
F
2
with a large birefringence of cal. 0.076 at 1064 nm. This work is of great significance to design beryllium-free borates with a KBBF-type structure.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/D1DT02356J</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.50 (38), p.13216-13219</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76J-e59391e943ab4e0c516cc903094d8b71d41b75e7e24d0dc61850a8a5eb4633c63</citedby><cites>FETCH-LOGICAL-c76J-e59391e943ab4e0c516cc903094d8b71d41b75e7e24d0dc61850a8a5eb4633c63</cites><orcidid>0000-0002-1331-0185 ; 0000-0001-8726-7952 ; 0000-0003-4521-4507</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Qiu, Haotian</creatorcontrib><creatorcontrib>Xia, Ming</creatorcontrib><creatorcontrib>Cai, Wenbing</creatorcontrib><creatorcontrib>Yang, Zhihua</creatorcontrib><creatorcontrib>Liu, Yanli</creatorcontrib><creatorcontrib>Mutailipu, Miriding</creatorcontrib><creatorcontrib>Pan, Shilie</creatorcontrib><title>BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A new beryllium-free zincoborate, BaZn
3
(BO
3
)
2
F
2
, with a KBBF-type structure has been synthesized for the first time. The electrostatic force of interaction in BaZn
3
(BO
3
)
2
F
2
provides better linkage in neighboring [ZnBO
3
F]
∞
single layers. BaZn
3
(BO
3
)
2
F
2
is the first case of borates with both [ZnO
3
F] tetrahedra and [ZnO
6
] octahedra, enriching the structural chemistry of borate system. All the coplanar [BO
3
] triangles align in the same direction with a high density, which endows BaZn
3
(BO
3
)
2
F
2
with a large birefringence of cal. 0.076 at 1064 nm. This work is of great significance to design beryllium-free borates with a KBBF-type structure.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkMtKw0AYhQdRsFY3PsEsVRidezLuTGvUWihIVm7CZPIHI2lSZhJK-vRGFF2cy-JwFh9Cl4zeMirM3ZItM8qF0qsjNGMyiojhQh7_da5P0VkIn5RyThWfobfEvrdY4KtkM_k15jiddI8tbmGPC_Bj09TDllQeAB_q1nVF520PeF_3H9PqNUlS0o87wKH3g-sHD-fopLJNgIvfnKMsfcwWz2S9eXpZPKyJi_SKgDLCMDBS2EICdYpp5wwV1MgyLiJWSlZECiLgsqSl0yxW1MZWQSG1EE6LObr5uXW-C8FDle98vbV-zBnNv2Hk_zDEF5csTb8</recordid><startdate>20211005</startdate><enddate>20211005</enddate><creator>Qiu, Haotian</creator><creator>Xia, Ming</creator><creator>Cai, Wenbing</creator><creator>Yang, Zhihua</creator><creator>Liu, Yanli</creator><creator>Mutailipu, Miriding</creator><creator>Pan, Shilie</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1331-0185</orcidid><orcidid>https://orcid.org/0000-0001-8726-7952</orcidid><orcidid>https://orcid.org/0000-0003-4521-4507</orcidid></search><sort><creationdate>20211005</creationdate><title>BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure</title><author>Qiu, Haotian ; Xia, Ming ; Cai, Wenbing ; Yang, Zhihua ; Liu, Yanli ; Mutailipu, Miriding ; Pan, Shilie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76J-e59391e943ab4e0c516cc903094d8b71d41b75e7e24d0dc61850a8a5eb4633c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qiu, Haotian</creatorcontrib><creatorcontrib>Xia, Ming</creatorcontrib><creatorcontrib>Cai, Wenbing</creatorcontrib><creatorcontrib>Yang, Zhihua</creatorcontrib><creatorcontrib>Liu, Yanli</creatorcontrib><creatorcontrib>Mutailipu, Miriding</creatorcontrib><creatorcontrib>Pan, Shilie</creatorcontrib><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qiu, Haotian</au><au>Xia, Ming</au><au>Cai, Wenbing</au><au>Yang, Zhihua</au><au>Liu, Yanli</au><au>Mutailipu, Miriding</au><au>Pan, Shilie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-10-05</date><risdate>2021</risdate><volume>50</volume><issue>38</issue><spage>13216</spage><epage>13219</epage><pages>13216-13219</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new beryllium-free zincoborate, BaZn
3
(BO
3
)
2
F
2
, with a KBBF-type structure has been synthesized for the first time. The electrostatic force of interaction in BaZn
3
(BO
3
)
2
F
2
provides better linkage in neighboring [ZnBO
3
F]
∞
single layers. BaZn
3
(BO
3
)
2
F
2
is the first case of borates with both [ZnO
3
F] tetrahedra and [ZnO
6
] octahedra, enriching the structural chemistry of borate system. All the coplanar [BO
3
] triangles align in the same direction with a high density, which endows BaZn
3
(BO
3
)
2
F
2
with a large birefringence of cal. 0.076 at 1064 nm. This work is of great significance to design beryllium-free borates with a KBBF-type structure.</abstract><doi>10.1039/D1DT02356J</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-1331-0185</orcidid><orcidid>https://orcid.org/0000-0001-8726-7952</orcidid><orcidid>https://orcid.org/0000-0003-4521-4507</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.50 (38), p.13216-13219 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D1DT02356J |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure |
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