Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores

Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores

Tetra(3-mercaptopropyl)-silsesquioxanes with double-decker (DDSQ) or ladder nano-cores were easily prepared from the corresponding tetraallyl derivatives through fast and convenient thiol-ene reactions. An additional tetrathiol-DDSQ with more flexible arms was also synthesized in high yield from the...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2021-03, Vol.5 (1), p.3473-3478
Hauptverfasser: Liu, Yujia, Kigure, Mana, Okawa, Riho, Takeda, Nobuhiro, Unno, Masafumi, Ouali, Armelle
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Chemical Sciences
Crystallography
Inorganic materials
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Liu, Yujia
Kigure, Mana
Okawa, Riho
Takeda, Nobuhiro
Unno, Masafumi
Ouali, Armelle
description Tetra(3-mercaptopropyl)-silsesquioxanes with double-decker (DDSQ) or ladder nano-cores were easily prepared from the corresponding tetraallyl derivatives through fast and convenient thiol-ene reactions. An additional tetrathiol-DDSQ with more flexible arms was also synthesized in high yield from the corresponding tetrachloro-DDSQ derivative. The three novel tetrathiol silsesquioxanes described represent versatile building blocks for the preparation of hybrid organic-inorganic materials. Novel tetrathiol silsesquioxanes with double-decker or ladder nanocores are readily synthesized from their corresponding allyl counterparts. They constitute versatile building blocks for the preparation of hybrid organic-inorganic materials.
doi_str_mv 10.1039/d1dt00042j
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical Sciences
Crystallography
Inorganic materials
title Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores
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