Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates
A systematic investigation of the system manganese( ii ) salt-H 2 SBA-auxiliary ligand-solvent successfully led to the isolation of six new multidimensional coordination polymers: [Mn 5 (2-pic) 2 (DMA) 4 (SBA) 4 ]·4DMA ( 1 ), [Mn 3 (pyzc) 2 (DMF)(H 2 O)(SBA) 2 ]·DMF·H 2 O ( 2 ), [Mn 5 (pyzc) 2 (DMA)...
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| creator | Balendra Singh, Bharti Banday, Azeem Tewari, Shailabh Kumar, Vineet Murugavel, Sevi Joy, P. A Ramanan, Arunachalam |
| description | A systematic investigation of the system manganese(
ii
) salt-H
2
SBA-auxiliary ligand-solvent successfully led to the isolation of six new multidimensional coordination polymers: [Mn
5
(2-pic)
2
(DMA)
4
(SBA)
4
]·4DMA (
1
), [Mn
3
(pyzc)
2
(DMF)(H
2
O)(SBA)
2
]·DMF·H
2
O (
2
), [Mn
5
(pyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
3
), [Mn
5
(mpyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
4
), [Mn
2
(phen)
2
(H
2
O)(SBA)
2
]·2DMA (
5
) and [Mn
3
(phen)
2
(SBA)
3
]·5DMF (
6
), where SBA = 4,4′-sulfonyldibenzoate 2-pic = 2-picolinate, pyzc = 2-pyrazinecarboxylate acid, mpyzc = 5-methyl-2-pyrazinecarboxylate and phen = 1,10-phenanthroline. The selected use of N-containing ligands to block the coordination sites of manganese enabled us to understand their influence in controlling the nuclearity and the dimensionality of the extended manganese carboxylate coordination networks. Single crystal X-ray crystallography established that the structures of all the solids were built of homometallic clusters varying from monomeric to pentameric manganese(
ii
) carboxylate units. While the solids
1
,
3
and
4
are isostructural, possessing a 2D coordination network containing pentanuclear SBUs of the composition {Mn
5
N
2
O
3
}, the 2D solids
2
and
5
are respectively built from binuclear {Mn
2
N
4
O
7
} and trinuclear {Mn
3
N
2
O
14
} SBUs. The solid
6
is the lone example of a 3D coordination network in this system. Dielectric measurements showed comparable dielectric behavior for the isostructural solids
1
,
3
and
4
with
′ ∼ 17 at room temperature. Relatively lower values observed for
2
and
5
(
′ ∼ 14) were due to a combined effect of strong manganese carboxylate interaction and the presence of ordered polar guest molecules. Significantly higher values for
6
(∼21) could be attributed to disordered guest molecules. All the six solids exhibited antiferromagnetic behavior at lower temperatures. This paper also discusses the growth of the solids in terms of supramolecular aggregation of manganese carboxylate complex species with or without an auxiliary ligand, proposing a mechanistic pathway to trace the chemical events from molecules to the final solid.
Six coordination polymers based on Mn(
ii
) and V-shaped ligand were successfully isolated and their dielectric as well as magnetic behaviours were investigated. The paper also discusses the growth of solids in terms of supramolecular aggregation. |
| doi_str_mv | 10.1039/d1ce00810b |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D1CE00810B</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2579112435</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-52bf5ab86ee9150655db86858d8c76098a7b0405b4579c5ad4095b0290151f423</originalsourceid><addsrcrecordid>eNpNkMtLw0AQxhdRsFYv3oWANzE6k2TTzVFrfUDBg3oO-5jUlLipu5tD_Otdrainme_jNw8-xo4RLhDy6tKgJgCBoHbYBIuyTAXk-e6_fp8deL8GwAIRJkw9jTa8km_9eaLd6IPsEh_coMPgKHqmpY50cK1OpDXJm1xZClFsXL8hF1rySd9E266kJU-JH7qmt2NnWkX2o5eB_CHba2Tn6einTtnL7eJ5fp8uH-8e5lfLVGcCQ8oz1XCpRElUIYeScxOF4MIIPSuhEnKmoACuCj6rNJemgIoryCpAjk2R5VN2ut0bf3sfyId63Q_OxpN1FkcQsyLnkTrbUtr13jtq6o1r36Qba4T6K8P6BueL7wyvI3yyhZ3Xv9xfxvknctNukw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2579112435</pqid></control><display><type>article</type><title>Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Balendra ; Singh, Bharti ; Banday, Azeem ; Tewari, Shailabh ; Kumar, Vineet ; Murugavel, Sevi ; Joy, P. A ; Ramanan, Arunachalam</creator><creatorcontrib>Balendra ; Singh, Bharti ; Banday, Azeem ; Tewari, Shailabh ; Kumar, Vineet ; Murugavel, Sevi ; Joy, P. A ; Ramanan, Arunachalam</creatorcontrib><description>A systematic investigation of the system manganese(
ii
) salt-H
2
SBA-auxiliary ligand-solvent successfully led to the isolation of six new multidimensional coordination polymers: [Mn
5
(2-pic)
2
(DMA)
4
(SBA)
4
]·4DMA (
1
), [Mn
3
(pyzc)
2
(DMF)(H
2
O)(SBA)
2
]·DMF·H
2
O (
2
), [Mn
5
(pyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
3
), [Mn
5
(mpyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
4
), [Mn
2
(phen)
2
(H
2
O)(SBA)
2
]·2DMA (
5
) and [Mn
3
(phen)
2
(SBA)
3
]·5DMF (
6
), where SBA = 4,4′-sulfonyldibenzoate 2-pic = 2-picolinate, pyzc = 2-pyrazinecarboxylate acid, mpyzc = 5-methyl-2-pyrazinecarboxylate and phen = 1,10-phenanthroline. The selected use of N-containing ligands to block the coordination sites of manganese enabled us to understand their influence in controlling the nuclearity and the dimensionality of the extended manganese carboxylate coordination networks. Single crystal X-ray crystallography established that the structures of all the solids were built of homometallic clusters varying from monomeric to pentameric manganese(
ii
) carboxylate units. While the solids
1
,
3
and
4
are isostructural, possessing a 2D coordination network containing pentanuclear SBUs of the composition {Mn
5
N
2
O
3
}, the 2D solids
2
and
5
are respectively built from binuclear {Mn
2
N
4
O
7
} and trinuclear {Mn
3
N
2
O
14
} SBUs. The solid
6
is the lone example of a 3D coordination network in this system. Dielectric measurements showed comparable dielectric behavior for the isostructural solids
1
,
3
and
4
with
′ ∼ 17 at room temperature. Relatively lower values observed for
2
and
5
(
′ ∼ 14) were due to a combined effect of strong manganese carboxylate interaction and the presence of ordered polar guest molecules. Significantly higher values for
6
(∼21) could be attributed to disordered guest molecules. All the six solids exhibited antiferromagnetic behavior at lower temperatures. This paper also discusses the growth of the solids in terms of supramolecular aggregation of manganese carboxylate complex species with or without an auxiliary ligand, proposing a mechanistic pathway to trace the chemical events from molecules to the final solid.
Six coordination polymers based on Mn(
ii
) and V-shaped ligand were successfully isolated and their dielectric as well as magnetic behaviours were investigated. The paper also discusses the growth of solids in terms of supramolecular aggregation.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d1ce00810b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Antiferromagnetism ; Coordination polymers ; Crystal structure ; Crystallography ; Ligands ; Magnetic properties ; Manganese ; Room temperature ; Single crystals</subject><ispartof>CrystEngComm, 2021-10, Vol.23 (38), p.673-6723</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-52bf5ab86ee9150655db86858d8c76098a7b0405b4579c5ad4095b0290151f423</citedby><cites>FETCH-LOGICAL-c281t-52bf5ab86ee9150655db86858d8c76098a7b0405b4579c5ad4095b0290151f423</cites><orcidid>0000-0002-6860-0817 ; 0000-0002-9847-249X ; 0000-0002-7238-7772 ; 0000-0003-2125-0976 ; 0000-0002-5754-459X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Balendra</creatorcontrib><creatorcontrib>Singh, Bharti</creatorcontrib><creatorcontrib>Banday, Azeem</creatorcontrib><creatorcontrib>Tewari, Shailabh</creatorcontrib><creatorcontrib>Kumar, Vineet</creatorcontrib><creatorcontrib>Murugavel, Sevi</creatorcontrib><creatorcontrib>Joy, P. A</creatorcontrib><creatorcontrib>Ramanan, Arunachalam</creatorcontrib><title>Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates</title><title>CrystEngComm</title><description>A systematic investigation of the system manganese(
ii
) salt-H
2
SBA-auxiliary ligand-solvent successfully led to the isolation of six new multidimensional coordination polymers: [Mn
5
(2-pic)
2
(DMA)
4
(SBA)
4
]·4DMA (
1
), [Mn
3
(pyzc)
2
(DMF)(H
2
O)(SBA)
2
]·DMF·H
2
O (
2
), [Mn
5
(pyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
3
), [Mn
5
(mpyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
4
), [Mn
2
(phen)
2
(H
2
O)(SBA)
2
]·2DMA (
5
) and [Mn
3
(phen)
2
(SBA)
3
]·5DMF (
6
), where SBA = 4,4′-sulfonyldibenzoate 2-pic = 2-picolinate, pyzc = 2-pyrazinecarboxylate acid, mpyzc = 5-methyl-2-pyrazinecarboxylate and phen = 1,10-phenanthroline. The selected use of N-containing ligands to block the coordination sites of manganese enabled us to understand their influence in controlling the nuclearity and the dimensionality of the extended manganese carboxylate coordination networks. Single crystal X-ray crystallography established that the structures of all the solids were built of homometallic clusters varying from monomeric to pentameric manganese(
ii
) carboxylate units. While the solids
1
,
3
and
4
are isostructural, possessing a 2D coordination network containing pentanuclear SBUs of the composition {Mn
5
N
2
O
3
}, the 2D solids
2
and
5
are respectively built from binuclear {Mn
2
N
4
O
7
} and trinuclear {Mn
3
N
2
O
14
} SBUs. The solid
6
is the lone example of a 3D coordination network in this system. Dielectric measurements showed comparable dielectric behavior for the isostructural solids
1
,
3
and
4
with
′ ∼ 17 at room temperature. Relatively lower values observed for
2
and
5
(
′ ∼ 14) were due to a combined effect of strong manganese carboxylate interaction and the presence of ordered polar guest molecules. Significantly higher values for
6
(∼21) could be attributed to disordered guest molecules. All the six solids exhibited antiferromagnetic behavior at lower temperatures. This paper also discusses the growth of the solids in terms of supramolecular aggregation of manganese carboxylate complex species with or without an auxiliary ligand, proposing a mechanistic pathway to trace the chemical events from molecules to the final solid.
Six coordination polymers based on Mn(
ii
) and V-shaped ligand were successfully isolated and their dielectric as well as magnetic behaviours were investigated. The paper also discusses the growth of solids in terms of supramolecular aggregation.</description><subject>Antiferromagnetism</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Ligands</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Room temperature</subject><subject>Single crystals</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkMtLw0AQxhdRsFYv3oWANzE6k2TTzVFrfUDBg3oO-5jUlLipu5tD_Otdrainme_jNw8-xo4RLhDy6tKgJgCBoHbYBIuyTAXk-e6_fp8deL8GwAIRJkw9jTa8km_9eaLd6IPsEh_coMPgKHqmpY50cK1OpDXJm1xZClFsXL8hF1rySd9E266kJU-JH7qmt2NnWkX2o5eB_CHba2Tn6einTtnL7eJ5fp8uH-8e5lfLVGcCQ8oz1XCpRElUIYeScxOF4MIIPSuhEnKmoACuCj6rNJemgIoryCpAjk2R5VN2ut0bf3sfyId63Q_OxpN1FkcQsyLnkTrbUtr13jtq6o1r36Qba4T6K8P6BueL7wyvI3yyhZ3Xv9xfxvknctNukw</recordid><startdate>20211005</startdate><enddate>20211005</enddate><creator>Balendra</creator><creator>Singh, Bharti</creator><creator>Banday, Azeem</creator><creator>Tewari, Shailabh</creator><creator>Kumar, Vineet</creator><creator>Murugavel, Sevi</creator><creator>Joy, P. A</creator><creator>Ramanan, Arunachalam</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6860-0817</orcidid><orcidid>https://orcid.org/0000-0002-9847-249X</orcidid><orcidid>https://orcid.org/0000-0002-7238-7772</orcidid><orcidid>https://orcid.org/0000-0003-2125-0976</orcidid><orcidid>https://orcid.org/0000-0002-5754-459X</orcidid></search><sort><creationdate>20211005</creationdate><title>Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates</title><author>Balendra ; Singh, Bharti ; Banday, Azeem ; Tewari, Shailabh ; Kumar, Vineet ; Murugavel, Sevi ; Joy, P. A ; Ramanan, Arunachalam</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-52bf5ab86ee9150655db86858d8c76098a7b0405b4579c5ad4095b0290151f423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antiferromagnetism</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Ligands</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Room temperature</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Balendra</creatorcontrib><creatorcontrib>Singh, Bharti</creatorcontrib><creatorcontrib>Banday, Azeem</creatorcontrib><creatorcontrib>Tewari, Shailabh</creatorcontrib><creatorcontrib>Kumar, Vineet</creatorcontrib><creatorcontrib>Murugavel, Sevi</creatorcontrib><creatorcontrib>Joy, P. A</creatorcontrib><creatorcontrib>Ramanan, Arunachalam</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Balendra</au><au>Singh, Bharti</au><au>Banday, Azeem</au><au>Tewari, Shailabh</au><au>Kumar, Vineet</au><au>Murugavel, Sevi</au><au>Joy, P. A</au><au>Ramanan, Arunachalam</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates</atitle><jtitle>CrystEngComm</jtitle><date>2021-10-05</date><risdate>2021</risdate><volume>23</volume><issue>38</issue><spage>673</spage><epage>6723</epage><pages>673-6723</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>A systematic investigation of the system manganese(
ii
) salt-H
2
SBA-auxiliary ligand-solvent successfully led to the isolation of six new multidimensional coordination polymers: [Mn
5
(2-pic)
2
(DMA)
4
(SBA)
4
]·4DMA (
1
), [Mn
3
(pyzc)
2
(DMF)(H
2
O)(SBA)
2
]·DMF·H
2
O (
2
), [Mn
5
(pyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
3
), [Mn
5
(mpyzc)
2
(DMA)
4
(SBA)
4
]·4DMA (
4
), [Mn
2
(phen)
2
(H
2
O)(SBA)
2
]·2DMA (
5
) and [Mn
3
(phen)
2
(SBA)
3
]·5DMF (
6
), where SBA = 4,4′-sulfonyldibenzoate 2-pic = 2-picolinate, pyzc = 2-pyrazinecarboxylate acid, mpyzc = 5-methyl-2-pyrazinecarboxylate and phen = 1,10-phenanthroline. The selected use of N-containing ligands to block the coordination sites of manganese enabled us to understand their influence in controlling the nuclearity and the dimensionality of the extended manganese carboxylate coordination networks. Single crystal X-ray crystallography established that the structures of all the solids were built of homometallic clusters varying from monomeric to pentameric manganese(
ii
) carboxylate units. While the solids
1
,
3
and
4
are isostructural, possessing a 2D coordination network containing pentanuclear SBUs of the composition {Mn
5
N
2
O
3
}, the 2D solids
2
and
5
are respectively built from binuclear {Mn
2
N
4
O
7
} and trinuclear {Mn
3
N
2
O
14
} SBUs. The solid
6
is the lone example of a 3D coordination network in this system. Dielectric measurements showed comparable dielectric behavior for the isostructural solids
1
,
3
and
4
with
′ ∼ 17 at room temperature. Relatively lower values observed for
2
and
5
(
′ ∼ 14) were due to a combined effect of strong manganese carboxylate interaction and the presence of ordered polar guest molecules. Significantly higher values for
6
(∼21) could be attributed to disordered guest molecules. All the six solids exhibited antiferromagnetic behavior at lower temperatures. This paper also discusses the growth of the solids in terms of supramolecular aggregation of manganese carboxylate complex species with or without an auxiliary ligand, proposing a mechanistic pathway to trace the chemical events from molecules to the final solid.
Six coordination polymers based on Mn(
ii
) and V-shaped ligand were successfully isolated and their dielectric as well as magnetic behaviours were investigated. The paper also discusses the growth of solids in terms of supramolecular aggregation.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ce00810b</doi><tpages>21</tpages><orcidid>https://orcid.org/0000-0002-6860-0817</orcidid><orcidid>https://orcid.org/0000-0002-9847-249X</orcidid><orcidid>https://orcid.org/0000-0002-7238-7772</orcidid><orcidid>https://orcid.org/0000-0003-2125-0976</orcidid><orcidid>https://orcid.org/0000-0002-5754-459X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2021-10, Vol.23 (38), p.673-6723 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D1CE00810B |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Antiferromagnetism Coordination polymers Crystal structure Crystallography Ligands Magnetic properties Manganese Room temperature Single crystals |
| title | Synthesis, crystal structures, dielectric and magnetic properties of manganese sulfonyldibenzoates |
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