Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal
A combination of flexibility and room temperature phosphorescence (RTPR) in organic crystals is in high demand due to various applications from bio-medical to organic photonic circuit technologies. However, flexible RTPR crystals are scarce. We report the design and synthesis of novel flexible micro...
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| Veröffentlicht in: | CrystEngComm 2021-09, Vol.23 (34), p.5774-5779 |
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| creator | Kumar, Avulu Vinod Rohullah, Mehdi Ravi, Jada Godumala, Mallesham Annadhasan, Mari Chandrasekar, Rajadurai |
| description | A combination of flexibility and room temperature phosphorescence (RTPR) in organic crystals is in high demand due to various applications from bio-medical to organic photonic circuit technologies. However, flexible RTPR crystals are scarce. We report the design and synthesis of novel flexible microcrystals of (
Z
)-3-(4-(10
H
-phenothiazin-10-yl)phenyl)-2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile (PTX-2CF
3
), exhibiting a phosphorescence lifetime of 658 μs and
λ
max
530 nm. The structural basis for the mechanical flexibility and mechanophotonic aspects of the PTX-2CF
3
crystals is studied in detail.
A novel crystal of PTX-2CF
3
exhibits room temperature phosphorescence and mechanical flexibility. This flexible crystal efficiently transduces optical emission both in the straight and bent geometries. |
| doi_str_mv | 10.1039/d1ce00475a |
| format | Article |
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Z
)-3-(4-(10
H
-phenothiazin-10-yl)phenyl)-2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile (PTX-2CF
3
), exhibiting a phosphorescence lifetime of 658 μs and
λ
max
530 nm. The structural basis for the mechanical flexibility and mechanophotonic aspects of the PTX-2CF
3
crystals is studied in detail.
A novel crystal of PTX-2CF
3
exhibits room temperature phosphorescence and mechanical flexibility. This flexible crystal efficiently transduces optical emission both in the straight and bent geometries.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d1ce00475a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Circuit design ; Crystallography ; Crystals ; Flexibility ; Microcrystals ; Organic crystals ; Phosphorescence ; Photonic crystals ; Room temperature</subject><ispartof>CrystEngComm, 2021-09, Vol.23 (34), p.5774-5779</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-e4c5a4df3606f0d3aff78f07ba57895904abf7e223763591e82104886a507a923</citedby><cites>FETCH-LOGICAL-c281t-e4c5a4df3606f0d3aff78f07ba57895904abf7e223763591e82104886a507a923</cites><orcidid>0000-0003-3527-3984</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kumar, Avulu Vinod</creatorcontrib><creatorcontrib>Rohullah, Mehdi</creatorcontrib><creatorcontrib>Ravi, Jada</creatorcontrib><creatorcontrib>Godumala, Mallesham</creatorcontrib><creatorcontrib>Annadhasan, Mari</creatorcontrib><creatorcontrib>Chandrasekar, Rajadurai</creatorcontrib><title>Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal</title><title>CrystEngComm</title><description>A combination of flexibility and room temperature phosphorescence (RTPR) in organic crystals is in high demand due to various applications from bio-medical to organic photonic circuit technologies. However, flexible RTPR crystals are scarce. We report the design and synthesis of novel flexible microcrystals of (
Z
)-3-(4-(10
H
-phenothiazin-10-yl)phenyl)-2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile (PTX-2CF
3
), exhibiting a phosphorescence lifetime of 658 μs and
λ
max
530 nm. The structural basis for the mechanical flexibility and mechanophotonic aspects of the PTX-2CF
3
crystals is studied in detail.
A novel crystal of PTX-2CF
3
exhibits room temperature phosphorescence and mechanical flexibility. This flexible crystal efficiently transduces optical emission both in the straight and bent geometries.</description><subject>Circuit design</subject><subject>Crystallography</subject><subject>Crystals</subject><subject>Flexibility</subject><subject>Microcrystals</subject><subject>Organic crystals</subject><subject>Phosphorescence</subject><subject>Photonic crystals</subject><subject>Room temperature</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkE1LAzEQhoMoWKsX70LAm7A62WST7LHU-gEVL3rxsqTpxG7Z3axJCvbfu7WiHoaZwzMzLw8h5wyuGfDyZsksAghVmAMyYkLKTAPnh__mY3IS4xqACcZgRN6e0K5M5_uVT76rLTWxR5si9Y4aGrxvacK2x2DSJiAdsDhUwGixS9Q1-FkvGqQ-vJvddlvb4G3YxmSaU3LkTBPx7KePyevd7GX6kM2f7x-nk3lmc81ShsIWRiwdlyAdLLlxTmkHamEKpcuiBGEWTmGecyV5UTLUOQOhtTQFKFPmfEwu93f74D82GFO19pvQDS-rvJCq5CBAD9TVnhoCxhjQVX2oWxO2FYNq5666ZdPZt7vJAF_s4RDtL_fnln8Bo3Zr-A</recordid><startdate>20210914</startdate><enddate>20210914</enddate><creator>Kumar, Avulu Vinod</creator><creator>Rohullah, Mehdi</creator><creator>Ravi, Jada</creator><creator>Godumala, Mallesham</creator><creator>Annadhasan, Mari</creator><creator>Chandrasekar, Rajadurai</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-3527-3984</orcidid></search><sort><creationdate>20210914</creationdate><title>Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal</title><author>Kumar, Avulu Vinod ; Rohullah, Mehdi ; Ravi, Jada ; Godumala, Mallesham ; Annadhasan, Mari ; Chandrasekar, Rajadurai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-e4c5a4df3606f0d3aff78f07ba57895904abf7e223763591e82104886a507a923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Circuit design</topic><topic>Crystallography</topic><topic>Crystals</topic><topic>Flexibility</topic><topic>Microcrystals</topic><topic>Organic crystals</topic><topic>Phosphorescence</topic><topic>Photonic crystals</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Avulu Vinod</creatorcontrib><creatorcontrib>Rohullah, Mehdi</creatorcontrib><creatorcontrib>Ravi, Jada</creatorcontrib><creatorcontrib>Godumala, Mallesham</creatorcontrib><creatorcontrib>Annadhasan, Mari</creatorcontrib><creatorcontrib>Chandrasekar, Rajadurai</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Avulu Vinod</au><au>Rohullah, Mehdi</au><au>Ravi, Jada</au><au>Godumala, Mallesham</au><au>Annadhasan, Mari</au><au>Chandrasekar, Rajadurai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal</atitle><jtitle>CrystEngComm</jtitle><date>2021-09-14</date><risdate>2021</risdate><volume>23</volume><issue>34</issue><spage>5774</spage><epage>5779</epage><pages>5774-5779</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>A combination of flexibility and room temperature phosphorescence (RTPR) in organic crystals is in high demand due to various applications from bio-medical to organic photonic circuit technologies. However, flexible RTPR crystals are scarce. We report the design and synthesis of novel flexible microcrystals of (
Z
)-3-(4-(10
H
-phenothiazin-10-yl)phenyl)-2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile (PTX-2CF
3
), exhibiting a phosphorescence lifetime of 658 μs and
λ
max
530 nm. The structural basis for the mechanical flexibility and mechanophotonic aspects of the PTX-2CF
3
crystals is studied in detail.
A novel crystal of PTX-2CF
3
exhibits room temperature phosphorescence and mechanical flexibility. This flexible crystal efficiently transduces optical emission both in the straight and bent geometries.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ce00475a</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-3527-3984</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2021-09, Vol.23 (34), p.5774-5779 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D1CE00475A |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Circuit design Crystallography Crystals Flexibility Microcrystals Organic crystals Phosphorescence Photonic crystals Room temperature |
| title | Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal |
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