Substitution at sp 3 boron of a six-membered NHC·BH 3 : convenient access to a dihydroxyborenium cation

Herein, we have undertaken the synthesis and investigated the reactivity of a 6-membered saturated NHC borane adduct (1). Direct electrophilic halogenation of 1 with a stoichiometric amount of I led to NHC boryl iodides, 6-SIDipp·BH I (2) and 6-SIDipp·BHI (3), which were further reacted with various...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3783-3786
Hauptverfasser:	Kundu, Gargi, Ajithkumar, V S, Raj, K Vipin, Vanka, Kumar, Tothadi, Srinu, Sen, Sakya S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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