Metal-free transfer hydrochlorination of internal C-C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

The development and application of a transfer hydrochlorination reagent based on a trichlorinated bicyclo[3.1.0]hexane core that transfers two molecules of HCl per molecule of surrogate to a π-basic substrate under B(C 6 F 5 ) 3 catalysis is reported. Lewis acid-assisted chloride abstraction followe...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-01, Vol.58 (7), p.973-976
Hauptverfasser:	Weidkamp, Andreas J, Oestreich, Martin
Format:	Artikel
Sprache:	eng
Schlagworte:	Hexanes Hydrochlorination Hydrogen chloride Lewis acid Organic compounds Reagents Ring opening Substrates
Online-Zugang:	Volltext
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