Easy wide scope access to luminescent fluorophosphoranes
The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by S N Ar cyclization of (2′-F,2-(PR 2 )biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discu...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (44), p.5458-5461 |
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| container_issue | 44 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Ponce-de-León, Jaime Infante, Rebeca Espinet, Pablo |
| description | The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by
S
N
Ar cyclization of (2′-F,2-(PR
2
)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.
Isomerization of easily accessible 2′-F,2-(PR
2
)(biaryl) phosphines, initiated by intramolecular
S
N
Ar reaction, affords luminescent fluorophosporanes in high yield. |
| doi_str_mv | 10.1039/d1cc00976a |
| format | Article |
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S
N
Ar cyclization of (2′-F,2-(PR
2
)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.
Isomerization of easily accessible 2′-F,2-(PR
2
)(biaryl) phosphines, initiated by intramolecular
S
N
Ar reaction, affords luminescent fluorophosporanes in high yield.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc00976a</identifier><identifier>PMID: 33954313</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Crystallography ; Homology ; Isomerization ; NMR ; Nuclear magnetic resonance ; Phosphines ; Reagents ; Synthesis</subject><ispartof>Chemical communications (Cambridge, England), 2021-06, Vol.57 (44), p.5458-5461</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c403t-9743c51eff7a94bc8c9a11ae9a00f1757bba3225c14b8eb6606ee1d6c45bdaa73</citedby><cites>FETCH-LOGICAL-c403t-9743c51eff7a94bc8c9a11ae9a00f1757bba3225c14b8eb6606ee1d6c45bdaa73</cites><orcidid>0000-0001-8649-239X ; 0000-0001-7464-2469 ; 0000-0002-3754-4189</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33954313$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ponce-de-León, Jaime</creatorcontrib><creatorcontrib>Infante, Rebeca</creatorcontrib><creatorcontrib>Espinet, Pablo</creatorcontrib><title>Easy wide scope access to luminescent fluorophosphoranes</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by
S
N
Ar cyclization of (2′-F,2-(PR
2
)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.
Isomerization of easily accessible 2′-F,2-(PR
2
)(biaryl) phosphines, initiated by intramolecular
S
N
Ar reaction, affords luminescent fluorophosporanes in high yield.</description><subject>Crystallography</subject><subject>Homology</subject><subject>Isomerization</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phosphines</subject><subject>Reagents</subject><subject>Synthesis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkU1Lw0AQhhdRbK1evCsBLyJEd7Nf2WOJ9QMKXhS8hc1mgilJN-4mSP-9W1MrODDMMPMwvLyD0DnBtwRTdVcSYzBWUugDNCVUsJiz9P1w23MVS8r4BJ14v8IhCE-P0YRSxRkldIrShfab6KsuIfLGdhBpY8D7qLdRM7T1GryBdR9VzWCd7T6sD-l0GJ-io0o3Hs52dYbeHhav2VO8fHl8zubL2DBM-1hJRg0nUFVSK1aY1ChNiAalMa6I5LIoNE0SbggrUiiEwAKAlMIwXpRaSzpD1-PdztnPAXyft3XQ1DRBhB18nvAkEQmWggX06h-6soNbB3WBohzLVEkaqJuRMs5676DKO1e32m1ygvOtn_k9ybIfP-cBvtydHIoWyj36a2AALkbAebPf_j2EfgP573lg</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Ponce-de-León, Jaime</creator><creator>Infante, Rebeca</creator><creator>Espinet, Pablo</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8649-239X</orcidid><orcidid>https://orcid.org/0000-0001-7464-2469</orcidid><orcidid>https://orcid.org/0000-0002-3754-4189</orcidid></search><sort><creationdate>20210601</creationdate><title>Easy wide scope access to luminescent fluorophosphoranes</title><author>Ponce-de-León, Jaime ; Infante, Rebeca ; Espinet, Pablo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c403t-9743c51eff7a94bc8c9a11ae9a00f1757bba3225c14b8eb6606ee1d6c45bdaa73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Crystallography</topic><topic>Homology</topic><topic>Isomerization</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phosphines</topic><topic>Reagents</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ponce-de-León, Jaime</creatorcontrib><creatorcontrib>Infante, Rebeca</creatorcontrib><creatorcontrib>Espinet, Pablo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ponce-de-León, Jaime</au><au>Infante, Rebeca</au><au>Espinet, Pablo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Easy wide scope access to luminescent fluorophosphoranes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2021-06-01</date><risdate>2021</risdate><volume>57</volume><issue>44</issue><spage>5458</spage><epage>5461</epage><pages>5458-5461</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by
S
N
Ar cyclization of (2′-F,2-(PR
2
)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.
Isomerization of easily accessible 2′-F,2-(PR
2
)(biaryl) phosphines, initiated by intramolecular
S
N
Ar reaction, affords luminescent fluorophosporanes in high yield.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>33954313</pmid><doi>10.1039/d1cc00976a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8649-239X</orcidid><orcidid>https://orcid.org/0000-0001-7464-2469</orcidid><orcidid>https://orcid.org/0000-0002-3754-4189</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-06, Vol.57 (44), p.5458-5461 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D1CC00976A |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystallography Homology Isomerization NMR Nuclear magnetic resonance Phosphines Reagents Synthesis |
| title | Easy wide scope access to luminescent fluorophosphoranes |
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