Highly efficient oxidation of 2,2'-hydrazobis-isobutyronitrile to 2,2'-azobis-isobutyronitrile over a CrO x /TiO 2 catalyst with hydrogen peroxide

Highly efficient oxidation of 2,2'-hydrazobis-isobutyronitrile to 2,2'-azobis-isobutyronitrile over a CrO x /TiO 2 catalyst with hydrogen peroxide

Green oxidation of 2,2'-hydrazobis-isobutyronitrile (HAIBN) to 2,2'-azobis-isobutyronitrile (AIBN) over a recyclable solid catalyst was a significant challenge. A titanium dioxide-supported chromium oxide (CrOx/TiO2) catalyst was, for the first time, developed for oxidation of HAIBN with h...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-05, Vol.57 (37), p.4576-4579
Hauptverfasser: Zhang, Hu, Yue, Shengnan, Zou, Xiujing, Wang, Xueguang, Zou, Xingli, Lu, Xionggang
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container_issue 37
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container_title Chemical communications (Cambridge, England)
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creator Zhang, Hu
Yue, Shengnan
Zou, Xiujing
Wang, Xueguang
Zou, Xingli
Lu, Xionggang
description Green oxidation of 2,2'-hydrazobis-isobutyronitrile (HAIBN) to 2,2'-azobis-isobutyronitrile (AIBN) over a recyclable solid catalyst was a significant challenge. A titanium dioxide-supported chromium oxide (CrOx/TiO2) catalyst was, for the first time, developed for oxidation of HAIBN with hydrogen peroxide and achieved complete conversion of HAIBN with a high (94.8%) yield of AIBN.
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title Highly efficient oxidation of 2,2'-hydrazobis-isobutyronitrile to 2,2'-azobis-isobutyronitrile over a CrO x /TiO 2 catalyst with hydrogen peroxide
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