On the mechanism of inter-cluster alloying reactions: two-stage metal exchange of [Au(PET)] and [Ag(DMBT)] clusters

Alloying is an effective way to tune the physical and chemical properties of metal nanoparticles (NPs) and nanoclusters (NCs). This study revealed the two-stage metal exchange mechanism of the alloying reaction between atomically precise noble metal clusters. It was found that the inter-cluster allo...

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-01, Vol.8 (2), p.1242-1251
Hauptverfasser:	Huang, Baoyu, Pei, Yong
Format:	Artikel
Sprache:	eng
Schlagworte:	Alloying Chemical properties Dimers Exchanging Icosahedral phase Kernels Ligands Metal clusters Metals Nanoparticles Noble metals
Online-Zugang:	Volltext
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