Palladium catalyzed 8-aminoimidazo[1,2-]pyridine (AIP) directed selective β-C(sp)-H arylation

Palladium catalyzed arylation of the inert β-C(sp 2 )-H bond of carboxylic acid derivatives is reported herein for the first time utilizing 8-aminoimidazo[1,2- a ]pyridine (AIP) as an efficacious and new inbuilt 6,5-fused bicyclic removable directing group. This protocol is scalable, exhibits high l...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-01, Vol.19 (2), p.36-364
Hauptverfasser:	Mondal, Biswajit, Ghosh, Prasanjit, Kundu, MrinalKanti, Das, Tapas Kumar, Das, Sajal
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic acids Chemistry Chemistry, Organic Functional groups Hydrogen bonds Palladium Physical Sciences Pyridines Science & Technology Selectivity
Online-Zugang:	Volltext
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