Photocatalytic dual decarboxylative alkenylation mediated by triphenylphosphine and sodium iodide

An efficient photocatalytic dual decarboxylative alkenylation of α,β-unsaturated carboxylic acids and alkyl N -hydroxyphthalimide (NHP) esters mediated by triphenylphosphine and sodium iodide has been developed. This protocol proceeds under 456-nanometer irradiation by visible blue light in the abse...

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Veröffentlicht in:	Organic & biomolecular chemistry 2020-08, Vol.18 (29), p.5589-5593
Hauptverfasser:	Wang, Hong-Yu, Zhong, Long-Jin, Lv, Gui-Fen, Li, Yang, Li, Jin-Heng
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Alkylation Amino acids Carboxylic acids Catalysts Esters Iodides Irradiation Photocatalysis Photoredox catalysis Selectivity Sodium Sodium iodide Styrenes Transition metals
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