Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design

KTiOPO 4 (KTP) is a classic commercial nonlinear optical (NLO) crystal, but its narrow bandgap (3.52 eV) prevents its practical application in the ultraviolet (UV) region. Many trials to widen the narrow bandgap of KTP have failed in the past few decades. A chemical cosubstitution strategy was imple...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-04, Vol.49 (16), p.5276-5282
Hauptverfasser:	He, Fangfang, Ge, Yuwei, Zhao, Xiaoyu, He, Jing, Huang, Ling, Gao, Daojiang, Bi, Jian, Wang, Xin, Zou, Guohong
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Cations Crystallography Crystals Dipole moments Electronegativity Energy gap First principles Mathematical analysis Metal ions Nonlinear optics Optical materials Optics Potassium titanyl orthophosphate Substitutes Transition metals
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