Suzuki-Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis
For more than 30 years, palladium has been extensively employed in the Suzuki-Miyaura cross coupling reaction (SMCR) for the synthesis of C-C coupled products. However, Pd-based reactions are associated with higher cost of the synthetic protocols, tedious work-ups, product contamination and metal le...
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| Veröffentlicht in: | Catalysis science & technology 2021-01, Vol.11 (4), p.1186-1221 |
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| creator | Kadu, Brijesh S |
| description | For more than 30 years, palladium has been extensively employed in the Suzuki-Miyaura cross coupling reaction (SMCR) for the synthesis of C-C coupled products. However, Pd-based reactions are associated with higher cost of the synthetic protocols, tedious work-ups, product contamination and metal leaching. In view of this scenario, other metals such as Ni, Cu, Co, Fe, Rh and Ru have gathered the attention of researchers for their usage in SMCR with a wide range of electrophiles that could lead the synthesis of industrially important compounds with various functional groups. In this review, we have discussed the advancements (within the last 4 years) in catalysis related to SMCR that would be beneficial for researchers in designing synthetic protocols for the preparation of pharmacophores as well as drug molecules.
Suzuki-Miyaura cross coupling reaction (SMCR) - A milestone in the synthesis of C-C coupled compounds. |
| doi_str_mv | 10.1039/d0cy02059a |
| format | Article |
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Suzuki-Miyaura cross coupling reaction (SMCR) - A milestone in the synthesis of C-C coupled compounds.</description><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry, Physical</subject><subject>Copper</subject><subject>Coupling (molecular)</subject><subject>Cross coupling</subject><subject>Functional groups</subject><subject>Iron</subject><subject>Leaching</subject><subject>Nickel</subject><subject>Palladium</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkc9PwyAYhhujicvcxbsJiTdNFQp0xdtSfyYzHtzFi81XSidzoxOopv710s3Mq1x4Q54X8j1E0THBFwRTcVlh2eEEcwF70SDBjMVsnJL9Xeb0MBo5t8BhMUFwlgyi1-f2u33X8aPuoLWApG2cQ7Jp10tt5sgqkF435iokqYxHUH2CkWoVskPaIAkelp3TDoGpUGPnYLRErjP-TYXTo-ighqVTo999GM1ub2b5fTx9unvIJ9NY0oz5uOScMl4JIBgyOa45EEroGKgsSVlWrJR1RQjPSC1EmmZKyRQLwTEGnmWU0mF0ur12bZuPVjlfLJrWmvBikTDBREJS3lNnW2ozpFV1sbZ6BbYrCC56g8U1zl82BicBzrbwlyqb2kmtwti7QjCYJoxj2rvESa499JrypjU-VM__Xw30yZa2Tu6gv6-kP-KTjmA</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Kadu, Brijesh S</creator><general>Royal Soc Chemistry</general><general>Royal Society of Chemistry</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8020-4318</orcidid></search><sort><creationdate>20210101</creationdate><title>Suzuki-Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis</title><author>Kadu, Brijesh S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-b55345d9a10a8c7f5a13137a3cb1bbd4bcfd11581f99668eec6099500a588333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Catalysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry, Physical</topic><topic>Copper</topic><topic>Coupling (molecular)</topic><topic>Cross coupling</topic><topic>Functional groups</topic><topic>Iron</topic><topic>Leaching</topic><topic>Nickel</topic><topic>Palladium</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kadu, Brijesh S</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kadu, Brijesh S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Suzuki-Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis</atitle><jtitle>Catalysis science & technology</jtitle><stitle>CATAL SCI TECHNOL</stitle><date>2021-01-01</date><risdate>2021</risdate><volume>11</volume><issue>4</issue><spage>1186</spage><epage>1221</epage><pages>1186-1221</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>For more than 30 years, palladium has been extensively employed in the Suzuki-Miyaura cross coupling reaction (SMCR) for the synthesis of C-C coupled products. However, Pd-based reactions are associated with higher cost of the synthetic protocols, tedious work-ups, product contamination and metal leaching. In view of this scenario, other metals such as Ni, Cu, Co, Fe, Rh and Ru have gathered the attention of researchers for their usage in SMCR with a wide range of electrophiles that could lead the synthesis of industrially important compounds with various functional groups. In this review, we have discussed the advancements (within the last 4 years) in catalysis related to SMCR that would be beneficial for researchers in designing synthetic protocols for the preparation of pharmacophores as well as drug molecules.
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| source | Royal Society Of Chemistry Journals 2008-; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Catalysis Chemical synthesis Chemistry Chemistry, Physical Copper Coupling (molecular) Cross coupling Functional groups Iron Leaching Nickel Palladium Physical Sciences Science & Technology |
| title | Suzuki-Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis |
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