Copper-catalyzed oxidative decarboxylative alkylation of cinnamic acids with 4-alkyl-1,4-dihydropyridines

We have developed a new oxidative decarboxylation of cinnamic acids with 4-alkyl-1,4-dihydropyridines to construct C(sp 3 )-C(sp 2 ) bonds in the presence of copper catalyst and dicumyl peroxide (DCP). A variety of internal alkenes have been obtained with mild conditions, broad substrate scope and e...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-11, Vol.56 (9), p.1455-1458
Hauptverfasser:	Zhang, Dong, Tang, Zi-Liang, Ouyang, Xuan-Hui, Song, Ren-Jie, Li, Jin-Heng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkylation Cinnamic acid Copper Decarboxylation Dicumyl peroxide Functional groups Halides Substrates
Online-Zugang:	Volltext
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