Guidelines for designing highly concentrated electrolytes for low temperature applications
The redefinition of the commonly named "water-in-salt" clarifies the operating temperatures of the state-of-the-art LiTFSI-based aqueous solutions. An in-depth study shows its mismatch for low temperature applications. In contrast, the recommended strategy is to design an electrolyte with...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (68), p.983-9833 |
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creator | Ah-lung, Guillaume Flamme, Benjamin Ghamouss, Fouad Maréchal, Manuel Jacquemin, Johan |
description | The redefinition of the commonly named "water-in-salt" clarifies the operating temperatures of the state-of-the-art LiTFSI-based aqueous solutions. An in-depth study shows its mismatch for low temperature applications. In contrast, the recommended strategy is to design an electrolyte with an invariant composition, as exemplified by the eutectic water/LiNO
3
that is able to electrochemically cycle down to −23 °C.
The WISS concept for the rational design of aqueous electrolytes for low temperature applications. |
doi_str_mv | 10.1039/d0cc03963b |
format | Article |
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3
that is able to electrochemically cycle down to −23 °C.
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3
that is able to electrochemically cycle down to −23 °C.
The WISS concept for the rational design of aqueous electrolytes for low temperature applications.</description><subject>Analytical chemistry</subject><subject>Aqueous solutions</subject><subject>Chemical Sciences</subject><subject>Electrochemical Techniques</subject><subject>Electrolytes</subject><subject>Electrolytes - chemistry</subject><subject>Low temperature</subject><subject>Operating temperature</subject><subject>or physical chemistry</subject><subject>Salts - chemistry</subject><subject>Solutions - chemistry</subject><subject>Temperature</subject><subject>Theoretical and</subject><subject>Trimethylsilyl Compounds - chemistry</subject><subject>Water - chemistry</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp90c9rFDEUB_AgFvtDL96VES9aGM2vyUyOddVWWPCiIF5CJnnZTclOxmRG2f--WXfdgofm8kLeh_CSL0LPCX5HMJPvLTamVMH6R-iMMMHrhnc_Hu_2jaxbxptTdJ7zLS6LNN0TdMpoSwSn7Rn6eT17C8EPkCsXU2Uh-9Xgh1W19qt12FYmDgaGKekJbAUBzJRi2E4HHuKfaoLNCKU_J6j0OAZv9OTjkJ-iE6dDhmeHeoG-f_70bXFTL79ef1lcLWvDGZtq3jrcSnCkbymjnZTESsDOdD1w0gvXa8M4JVL0ZXgrnDUEROu6xgkg1kh2gd7u713roMbkNzptVdRe3Vwt1e4MMyyEZPI3KfbN3o4p_pohT2rjs4EQ9ABxzoqWT2kobbgo9PV_9DbOaSgvKYqJTuCG4qIu98qkmHMCd5yAYLVLR33Ei8XfdD4U_PJw5dxvwB7pvzgKeLUHKZtj9z5eNVpXzIuHDLsD_PGfiQ</recordid><startdate>20200825</startdate><enddate>20200825</enddate><creator>Ah-lung, Guillaume</creator><creator>Flamme, Benjamin</creator><creator>Ghamouss, Fouad</creator><creator>Maréchal, Manuel</creator><creator>Jacquemin, Johan</creator><general>Royal Society of Chemistry</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-4178-8629</orcidid><orcidid>https://orcid.org/0000-0002-4295-7244</orcidid><orcidid>https://orcid.org/0000-0002-2419-0385</orcidid></search><sort><creationdate>20200825</creationdate><title>Guidelines for designing highly concentrated electrolytes for low temperature applications</title><author>Ah-lung, Guillaume ; 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An in-depth study shows its mismatch for low temperature applications. In contrast, the recommended strategy is to design an electrolyte with an invariant composition, as exemplified by the eutectic water/LiNO
3
that is able to electrochemically cycle down to −23 °C.
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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Analytical chemistry Aqueous solutions Chemical Sciences Electrochemical Techniques Electrolytes Electrolytes - chemistry Low temperature Operating temperature or physical chemistry Salts - chemistry Solutions - chemistry Temperature Theoretical and Trimethylsilyl Compounds - chemistry Water - chemistry |
title | Guidelines for designing highly concentrated electrolytes for low temperature applications |
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