Supramolecular self-healing materials from non-covalent cross-linking host-guest interactions

The introduction of non-covalent bonds is effective for achieving self-healing properties because they can be controlled reversibly. One approach to introduce these bonds into supramolecular materials is use of host-guest interactions. This feature article summarizes the development of supramolecula...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-04, Vol.56 (32), p.4381-4395
Hauptverfasser: Sinawang, Garry, Osaki, Motofumi, Takashima, Yoshinori, Yamaguchi, Hiroyasu, Harada, Akira
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container_end_page 4395
container_issue 32
container_start_page 4381
container_title Chemical communications (Cambridge, England)
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creator Sinawang, Garry
Osaki, Motofumi
Takashima, Yoshinori
Yamaguchi, Hiroyasu
Harada, Akira
description The introduction of non-covalent bonds is effective for achieving self-healing properties because they can be controlled reversibly. One approach to introduce these bonds into supramolecular materials is use of host-guest interactions. This feature article summarizes the development of supramolecular materials constructed by non-covalent cross-linking through several approaches, such as host-guest interactions between host polymers and guest polymers, 1 : 2-type host-guest interactions, and host-guest interactions from the polymerization of host-guest inclusion complexes. Host-guest interactions show self-healing functions while also enabling stimuli-responsiveness (redox, pH, and temperature). The self-healing function of supramolecular materials is achieved by stress dispersion arising from host-guest interactions when stress is applied. Reversible bonds based on host-guest interactions have tremendous potential to expand the variety of functional materials. Self-healing materials constructed from host-guest interactions between macrocyclic compounds as host molecules and specific guest molecules.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Bonding
Chemical bonds
Construction materials
Covalence
Covalent bonds
Crosslinking
Functional materials
Host-guest materials
Inclusion complexes
Polymers
Self healing materials
Supramolecular compounds
title Supramolecular self-healing materials from non-covalent cross-linking host-guest interactions
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