Multicolor luminescent supramolecular hydrogels based on cucurbit[8]uril and OPV derivative
Supramolecular hydrogels have received considerable attention because of their various fascinating applications. Herein, an alkyl chain-modified oligo( p -phenylenevinylene) (Py-OPV) derivative was synthesized. When assembled with cucurbit[7]uril, its fluorescence intensity was enhanced without any...
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| Veröffentlicht in: | Soft matter 2019-12, Vol.15 (48), p.9881-9885 |
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| creator | Chang, Yong-Zhen Chen, Yong Liu, Yu |
| description | Supramolecular hydrogels have received considerable attention because of their various fascinating applications. Herein, an alkyl chain-modified oligo(
p
-phenylenevinylene) (Py-OPV) derivative was synthesized. When assembled with cucurbit[7]uril, its fluorescence intensity was enhanced without any change in color. However, the molecules underwent J-type dimerization when encased in the cavity of cucurbit[8]uril, which possessed different emission properties based on the monomer. By simply changing the concentration of cucurbit[8]uril, the fluorescence properties of the assemblies were easily altered. In addition, luminescent supramolecular hydrogels were constructed with Py-OPV and cucurbit[8]uril based on the photopolymerization of acrylamide. By embedding the assembly in the polymer to confine it, hydrogels emitting various tones of blue light were easily constructed. The preparation method of such luminescent hydrogels provides a new reference method for the construction of specific luminescent materials.
Luminescent supramolecular hydrogels were constructed using photopolymerization, which emitted various tones of blue light. |
| doi_str_mv | 10.1039/c9sm02004g |
| format | Article |
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p
-phenylenevinylene) (Py-OPV) derivative was synthesized. When assembled with cucurbit[7]uril, its fluorescence intensity was enhanced without any change in color. However, the molecules underwent J-type dimerization when encased in the cavity of cucurbit[8]uril, which possessed different emission properties based on the monomer. By simply changing the concentration of cucurbit[8]uril, the fluorescence properties of the assemblies were easily altered. In addition, luminescent supramolecular hydrogels were constructed with Py-OPV and cucurbit[8]uril based on the photopolymerization of acrylamide. By embedding the assembly in the polymer to confine it, hydrogels emitting various tones of blue light were easily constructed. The preparation method of such luminescent hydrogels provides a new reference method for the construction of specific luminescent materials.
Luminescent supramolecular hydrogels were constructed using photopolymerization, which emitted various tones of blue light.</description><identifier>ISSN: 1744-683X</identifier><identifier>EISSN: 1744-6848</identifier><identifier>DOI: 10.1039/c9sm02004g</identifier><identifier>PMID: 31790100</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acrylamide ; Dimerization ; Embedding ; Fluorescence ; Hydrogels ; Photopolymerization</subject><ispartof>Soft matter, 2019-12, Vol.15 (48), p.9881-9885</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-8d56afd93bc282c97a3b125ad84d52a1ba00341c51f9dc8d751029334acb9fcb3</citedby><cites>FETCH-LOGICAL-c400t-8d56afd93bc282c97a3b125ad84d52a1ba00341c51f9dc8d751029334acb9fcb3</cites><orcidid>0000-0001-8723-1896</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31790100$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chang, Yong-Zhen</creatorcontrib><creatorcontrib>Chen, Yong</creatorcontrib><creatorcontrib>Liu, Yu</creatorcontrib><title>Multicolor luminescent supramolecular hydrogels based on cucurbit[8]uril and OPV derivative</title><title>Soft matter</title><addtitle>Soft Matter</addtitle><description>Supramolecular hydrogels have received considerable attention because of their various fascinating applications. Herein, an alkyl chain-modified oligo(
p
-phenylenevinylene) (Py-OPV) derivative was synthesized. When assembled with cucurbit[7]uril, its fluorescence intensity was enhanced without any change in color. However, the molecules underwent J-type dimerization when encased in the cavity of cucurbit[8]uril, which possessed different emission properties based on the monomer. By simply changing the concentration of cucurbit[8]uril, the fluorescence properties of the assemblies were easily altered. In addition, luminescent supramolecular hydrogels were constructed with Py-OPV and cucurbit[8]uril based on the photopolymerization of acrylamide. By embedding the assembly in the polymer to confine it, hydrogels emitting various tones of blue light were easily constructed. The preparation method of such luminescent hydrogels provides a new reference method for the construction of specific luminescent materials.
Luminescent supramolecular hydrogels were constructed using photopolymerization, which emitted various tones of blue light.</description><subject>Acrylamide</subject><subject>Dimerization</subject><subject>Embedding</subject><subject>Fluorescence</subject><subject>Hydrogels</subject><subject>Photopolymerization</subject><issn>1744-683X</issn><issn>1744-6848</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp90UtLxDAQB_Agiu-LdyXiRYRqXm2Toyy-YGUFHwgiJU1S7ZI2a9II--3tuusKHjxlID-Gmf8AsIfRKUZUnCkRGkQQYm8rYBPnjCUZZ3x1WdPnDbAVwhghyhnO1sEGxblAGKFN8HIbbVcrZ52HNjZ1a4IybQdDnHjZOGtUtNLD96n27s3YAEsZjIauhSqq6Mu6e-Gv0dcWylbD0d0T1MbXn7KrP80OWKukDWZ38W6Dx8uLh8F1Mhxd3QzOh4liCHUJ12kmKy1oqQgnSuSSlpikUnOmUyJxKfvBGVYproRWXOcpRkRQyqQqRaVKug2O530n3n1EE7qiqfstrJWtcTEUhBKUUYFZ1tOjP3Tsom_76WaKcULTnPXqZK6UdyF4UxUTXzfSTwuMilnkxUDc335HftXjg0XLWDZGL-lPxj04nAMf1PL392bFRFe92f_P0C_VcZH0</recordid><startdate>20191211</startdate><enddate>20191211</enddate><creator>Chang, Yong-Zhen</creator><creator>Chen, Yong</creator><creator>Liu, Yu</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8723-1896</orcidid></search><sort><creationdate>20191211</creationdate><title>Multicolor luminescent supramolecular hydrogels based on cucurbit[8]uril and OPV derivative</title><author>Chang, Yong-Zhen ; Chen, Yong ; Liu, Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-8d56afd93bc282c97a3b125ad84d52a1ba00341c51f9dc8d751029334acb9fcb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acrylamide</topic><topic>Dimerization</topic><topic>Embedding</topic><topic>Fluorescence</topic><topic>Hydrogels</topic><topic>Photopolymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chang, Yong-Zhen</creatorcontrib><creatorcontrib>Chen, Yong</creatorcontrib><creatorcontrib>Liu, Yu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Soft matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chang, Yong-Zhen</au><au>Chen, Yong</au><au>Liu, Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multicolor luminescent supramolecular hydrogels based on cucurbit[8]uril and OPV derivative</atitle><jtitle>Soft matter</jtitle><addtitle>Soft Matter</addtitle><date>2019-12-11</date><risdate>2019</risdate><volume>15</volume><issue>48</issue><spage>9881</spage><epage>9885</epage><pages>9881-9885</pages><issn>1744-683X</issn><eissn>1744-6848</eissn><abstract>Supramolecular hydrogels have received considerable attention because of their various fascinating applications. Herein, an alkyl chain-modified oligo(
p
-phenylenevinylene) (Py-OPV) derivative was synthesized. When assembled with cucurbit[7]uril, its fluorescence intensity was enhanced without any change in color. However, the molecules underwent J-type dimerization when encased in the cavity of cucurbit[8]uril, which possessed different emission properties based on the monomer. By simply changing the concentration of cucurbit[8]uril, the fluorescence properties of the assemblies were easily altered. In addition, luminescent supramolecular hydrogels were constructed with Py-OPV and cucurbit[8]uril based on the photopolymerization of acrylamide. By embedding the assembly in the polymer to confine it, hydrogels emitting various tones of blue light were easily constructed. The preparation method of such luminescent hydrogels provides a new reference method for the construction of specific luminescent materials.
Luminescent supramolecular hydrogels were constructed using photopolymerization, which emitted various tones of blue light.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31790100</pmid><doi>10.1039/c9sm02004g</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-8723-1896</orcidid></addata></record> |
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| ispartof | Soft matter, 2019-12, Vol.15 (48), p.9881-9885 |
| issn | 1744-683X 1744-6848 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acrylamide Dimerization Embedding Fluorescence Hydrogels Photopolymerization |
| title | Multicolor luminescent supramolecular hydrogels based on cucurbit[8]uril and OPV derivative |
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