On the divalent character of the Eu atoms in the ternary Zintl phases Eu 5 In 2 Pn 6 and Eu 3 MAs 3 (Pn = As–Bi; M = Al, Ga)

Five Zintl phases in the ternary system Eu–M–Pn (M = Al, In; Pn = As, Sb, Bi) were prepared from the elements in tantalum containers. Eu 5 In 2 As 6 and Eu 5 In 2 Sb 6 crystallize in the orthorhombic Ca 5 Ga 2 As 6 type structure ( Pbam , oP 26), while Eu 5 In 2 Bi 6 is isostructural to orthorhombic...

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Veröffentlicht in:	Materials chemistry frontiers 2020-04, Vol.4 (4), p.1231-1248
Hauptverfasser:	Radzieowski, Mathis, Stegemann, Frank, Klenner, Steffen, Zhang, Yuemei, Fokwa, Boniface P. T., Janka, Oliver
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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