High temperature Fe( iii ) spin crossover behaviours in three unprecedented Fe III –M II –Fe III (M = Fe, Cd) linear trinuclear complexes

High temperature Fe( iii ) spin crossover behaviours in three unprecedented Fe III –M II –Fe III (M = Fe, Cd) linear trinuclear complexes

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III –M II –Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions.

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Veröffentlicht in:Inorganic chemistry frontiers 2020-04, Vol.7 (7), p.1526-1531
Hauptverfasser: Ouyang, Zhi-Jian, Mo, Xiao-Ying, Yang, Meng, Zhong, Li, Chen, Wen-Bin, Gao, Song, Dong, Wen
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container_issue 7
container_start_page 1526
container_title Inorganic chemistry frontiers
container_volume 7
creator Ouyang, Zhi-Jian
Mo, Xiao-Ying
Yang, Meng
Zhong, Li
Chen, Wen-Bin
Gao, Song
Dong, Wen
description An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III –M II –Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions.
doi_str_mv 10.1039/C9QI01560D
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title High temperature Fe( iii ) spin crossover behaviours in three unprecedented Fe III –M II –Fe III (M = Fe, Cd) linear trinuclear complexes
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