Elucidation of the properties of discrete oligo(meth)acrylates
Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated via a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transit...
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| Veröffentlicht in: | Polymer chemistry 2019-12, Vol.1 (48), p.654-6544 |
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| container_title | Polymer chemistry |
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| creator | Haven, Joris J De Neve, Jeroen Castro Villavicencio, Andres Junkers, Tanja |
| description | Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transition temperatures and melting points of the discrete oligo(MMA)s (DP 1 to 7) and oligo(DEGEEA)s (DP 1 to 10) are determined, giving insights into fundamental polymer physics in this short chain regime.
Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
a 2-step process of RAFT polymerization and chromatographic separation. |
| doi_str_mv | 10.1039/c9py01494b |
| format | Article |
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via
a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transition temperatures and melting points of the discrete oligo(MMA)s (DP 1 to 7) and oligo(DEGEEA)s (DP 1 to 10) are determined, giving insights into fundamental polymer physics in this short chain regime.
Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
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via
a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transition temperatures and melting points of the discrete oligo(MMA)s (DP 1 to 7) and oligo(DEGEEA)s (DP 1 to 10) are determined, giving insights into fundamental polymer physics in this short chain regime.
Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
a 2-step process of RAFT polymerization and chromatographic separation.</description><subject>Acrylates</subject><subject>Addition polymerization</subject><subject>Chemical industry</subject><subject>Ethylene glycol</subject><subject>Glass transition temperature</subject><subject>Melting points</subject><subject>Physical properties</subject><subject>Polymer chemistry</subject><subject>Polymer physics</subject><subject>Polymethyl methacrylate</subject><subject>Temperature</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LAzEQhoMoWGov3oUFLyqsJplku7kIttQPKOihF09LNpnYLdtmTdJD_71bK3UuM7w8zAwPIZeM3jMK6sGobkeZUKI-IQM2lipXquCnx1mKczKKcUX7AiY4FAPyOGu3prE6NX6TeZelJWZd8B2G1GDcJ7aJJmDCzLfNl79ZY1reahN2rU4YL8iZ023E0V8fksXzbDF9zefvL2_Tp3luQIxTLkptwUpGa6sdOqNQG6UF1ZQrKQUTsrSuRnDSUFmCNQUUsuZKc6ZLx2BIrg9r-9e-txhTtfLbsOkvVhw4MCqhKHrq7kCZ4GMM6KouNGsddhWj1d5QNVUfn7-GJj18dYBDNEfu3yD8AL3FYp0</recordid><startdate>20191228</startdate><enddate>20191228</enddate><creator>Haven, Joris J</creator><creator>De Neve, Jeroen</creator><creator>Castro Villavicencio, Andres</creator><creator>Junkers, Tanja</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-1281-1858</orcidid><orcidid>https://orcid.org/0000-0002-6825-5777</orcidid><orcidid>https://orcid.org/0000-0002-6905-2373</orcidid></search><sort><creationdate>20191228</creationdate><title>Elucidation of the properties of discrete oligo(meth)acrylates</title><author>Haven, Joris J ; De Neve, Jeroen ; Castro Villavicencio, Andres ; Junkers, Tanja</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c347t-48ad3d510bdafefc9eac9a40a0295541458dfbe3f5c0583dc6365b29a21a8f13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acrylates</topic><topic>Addition polymerization</topic><topic>Chemical industry</topic><topic>Ethylene glycol</topic><topic>Glass transition temperature</topic><topic>Melting points</topic><topic>Physical properties</topic><topic>Polymer chemistry</topic><topic>Polymer physics</topic><topic>Polymethyl methacrylate</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Haven, Joris J</creatorcontrib><creatorcontrib>De Neve, Jeroen</creatorcontrib><creatorcontrib>Castro Villavicencio, Andres</creatorcontrib><creatorcontrib>Junkers, Tanja</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Haven, Joris J</au><au>De Neve, Jeroen</au><au>Castro Villavicencio, Andres</au><au>Junkers, Tanja</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Elucidation of the properties of discrete oligo(meth)acrylates</atitle><jtitle>Polymer chemistry</jtitle><date>2019-12-28</date><risdate>2019</risdate><volume>1</volume><issue>48</issue><spage>654</spage><epage>6544</epage><pages>654-6544</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transition temperatures and melting points of the discrete oligo(MMA)s (DP 1 to 7) and oligo(DEGEEA)s (DP 1 to 10) are determined, giving insights into fundamental polymer physics in this short chain regime.
Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated
via
a 2-step process of RAFT polymerization and chromatographic separation.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9py01494b</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-1281-1858</orcidid><orcidid>https://orcid.org/0000-0002-6825-5777</orcidid><orcidid>https://orcid.org/0000-0002-6905-2373</orcidid></addata></record> |
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| ispartof | Polymer chemistry, 2019-12, Vol.1 (48), p.654-6544 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_C9PY01494B |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Acrylates Addition polymerization Chemical industry Ethylene glycol Glass transition temperature Melting points Physical properties Polymer chemistry Polymer physics Polymethyl methacrylate Temperature |
| title | Elucidation of the properties of discrete oligo(meth)acrylates |
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