A strong organic electron donor incorporating highly π-donating triphenylphosphonium ylidyl substituents

The π-electron donor strength of a triphenylphosphonium ylidyl group (Ph 3 P&z.dbd;CH-) was explored through its substitution onto a bispyridinylidene (BPY) scaffold. Electrochemical studies revealed that the new triphenylphosphonium ylidyl-substituted BPY is the most reducing di-substituted der...

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Veröffentlicht in:	Organic & biomolecular chemistry 2019-12, Vol.17 (45), p.9726-9733
Hauptverfasser:	Burgoyne, Morgan M, MacDougall, Thomas M, Haines, Zachary N, Conrad, Jordan W, Calhoun, Larry A, Decken, Andreas, Dyker, C. Adam
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography Data transfer (computers) Electrochemistry Hexachloroethane Isomers NMR Nuclear magnetic resonance Phosphine Pi-electrons Redox potential Substitutes
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