Catalyst-free selective N -formylation and N -methylation of amines using CO 2 as a sustainable C1 source
We herein describe catalyst-free selective N -formylation and N -methylation of amines using CO 2 as a sustainable C1 source. By tuning the reaction solvent and temperature, the selective synthesis of formamides and methylamines is achieved in good to excellent yields using sodium borohydride (NaBH...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2020-02, Vol.22 (4), p.1134-1138 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | We herein describe catalyst-free selective
N
-formylation and
N
-methylation of amines using CO
2
as a sustainable C1 source. By tuning the reaction solvent and temperature, the selective synthesis of formamides and methylamines is achieved in good to excellent yields using sodium borohydride (NaBH
4
) as a sustainable reductant. |
|---|---|
| ISSN: | 1463-9262 1463-9270 |
| DOI: | 10.1039/C9GC03637G |