One step phenol synthesis from benzene catalysed by nickel() complexes

Nickel( ii )complexes of N 4 -ligands have been synthesized and characterized as efficient catalysts for the hydroxylation of benzene using H 2 O 2 . All the complexes exhibited Ni 2+ → Ni 3+ oxidation potentials of around 0.966-1.051 V vs. Ag/Ag + in acetonitrile. One of the complexes has been stru...

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Veröffentlicht in:	Catalysis science & technology 2019, Vol.9 (21), p.5991-61
Hauptverfasser:	Muthuramalingam, Sethuraman, Anandababu, Karunanithi, Velusamy, Marappan, Mayilmurugan, Ramasamy
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Benzene Catalysts Chemical synthesis Coordination compounds Crystallography Hydrocarbons Hydrogen peroxide Hydroxylation Isotope effect Ligands Mathematical analysis Nickel Oxidation Oxygen Phenols Spectra Spectral methods
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