The role of the molecular formula of ZnCl 2 · n H 2 O on its catalyst activity: a systematic study of zinc chloride hydrates in the catalytic valorisation of cellulosic biomass
We demonstrate the efficient and direct transformation of a range of low value substrates, such as lignocellulose and algal biomass, into significantly higher value chemicals, including low molecular weight reducing saccharides, 5-(hydroxymethyl)furfural, furyl hydroxymethyl ketone and furfural. Thi...
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| Veröffentlicht in: | Catalysis science & technology 2019-08, Vol.9 (17), p.4693-4701 |
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| container_title | Catalysis science & technology |
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| creator | Bodachivskyi, Iurii Kuzhiumparambil, Unnikrishnan Williams, D. Bradley G. |
| description | We demonstrate the efficient and direct transformation of a range of low value substrates, such as lignocellulose and algal biomass, into significantly higher value chemicals, including low molecular weight reducing saccharides, 5-(hydroxymethyl)furfural, furyl hydroxymethyl ketone and furfural. This is based on a systematic study of ZnCl
2
·
n
H
2
O (
n
= 2.5–4.5), in particular the role of the molecular formula (the amount of H
2
O) on its activity in the catalytic transformation of cellulosic materials into value added small molecules. The study includes various model transformations based on refined saccharides and applies the new insights to the highly selective transformation of raw biomass. |
| doi_str_mv | 10.1039/C9CY00846B |
| format | Article |
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O (
n
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·
n
H
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O (
n
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2
O) on its activity in the catalytic transformation of cellulosic materials into value added small molecules. The study includes various model transformations based on refined saccharides and applies the new insights to the highly selective transformation of raw biomass.</abstract><doi>10.1039/C9CY00846B</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-5803-4674</orcidid><orcidid>https://orcid.org/0000-0002-3703-6301</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Catalysis science & technology, 2019-08, Vol.9 (17), p.4693-4701 |
| issn | 2044-4753 2044-4761 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C9CY00846B |
| source | Royal Society Of Chemistry Journals 2008- |
| title | The role of the molecular formula of ZnCl 2 · n H 2 O on its catalyst activity: a systematic study of zinc chloride hydrates in the catalytic valorisation of cellulosic biomass |
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