A DNP-hyperpolarized solid-state water NMR MASER: observation and qualitative analysis

We present observations of an NMR MASER (microwave amplification by stimulated emission of radiation) of hyperpolarized 1 H nuclei by dynamic nuclear polarization (DNP) at 1.2 K and in a magnetic field of 6.7 T. The sustained maser pulses originate from the interplay between radiation damping (RD) due to the large 1 H magnetization, and the remagnetization to a negative value by the DNP process. NMR signals lasting for several tens of seconds are thus observed on an ensemble of dipolar-coupled nuclear spins. Magnetization dynamics are analyzed in terms of the combined Bloch-Maxwell and Provotorov (BMP) equations for RD and DNP. Insight into the long time evolution of the magnetization is provided by a theoretical analysis of this nonlinear dynamical system, and by fitting the NMR signal to a simplified version of the BMP equations. Observation and theoretical analysis of an NMR MASER of hyperpolarized 1 H nuclei by dynamic nuclear polarization (DNP) at 1.2 K and in a magnetic field of 6.7 T are presented in this study.