Structural studies of a manganese() complex with spin-crossover and thermochromic properties

Thermochromism and gradual spin crossover (SCO) were observed in the [Mn III (5-MeO-sal-N-1-5-8-12)]Cl complex. The transition temperature ( T 1/2 ) was determined to be 281 K by the drastic changes in the unit cell. This T 1/2 value is the highest observed for this type of system using the 5-MeO-H...

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Veröffentlicht in:	CrystEngComm 2020-01, Vol.22 (18), p.3221-3233
Hauptverfasser:	Villaman, David, McMonagle, Charles J, Probert, Michael R, Peña, Octavio, Moreno, Yanko, Fuentealba, Mauricio
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Cryogenic temperature Crystallography Imines Manganese Parameters Single crystals Thermochromism Transition temperature Unit cell
Online-Zugang:	Volltext
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