Solvent influenced synthesis of single-phase SnS 2 nanosheets for solution-processed photodiode fabrication
The effect of variant high boiling point solvent combinations in the synthesis and photo-sensing characteristics of tin disulfide (SnS 2 ) thin nanosheets were investigated. Solvent dependent single-phase formation was observed by powder X-ray diffractometry (XRD), and results were verified with Ram...
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| Veröffentlicht in: | CrystEngComm 2020-01, Vol.22 (3), p.525-533 |
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| creator | Thangaraju, D. Marnadu, R. Santhana, V. Durairajan, A. Kathirvel, P. Chandrasekaran, J. Jayakumar, S. Valente, M. A. Greenidge, Darius C. |
| description | The effect of variant high boiling point solvent combinations in the synthesis and photo-sensing characteristics of tin disulfide (SnS
2
) thin nanosheets were investigated. Solvent dependent single-phase formation was observed by powder X-ray diffractometry (XRD), and results were verified with Raman spectroscopy measurements. Particles synthesized with only oleylamine show a mixed-phase, and two other solvent combinations such as oleylamine + oleic acid +
n
-octadecene, and oleylamine + oleic acid, show single-phase 2H–SnS
2
, without phase contamination. Scanning and transmission electron microscopes were used to verify the orbicular and hexagonal shape of synthesized SnS
2
nanosheets. Well-characterized samples were employed to fabricate heterojunction photosensitive diodes using a p-type silicon substrate. Light-responsive measurement results of fabricated diodes indicate that the oleylamine + oleic acid synthesized sample show very high light-sensitivity, and the fill factor value of a fabricated diode is closer to the ideal diode. |
| doi_str_mv | 10.1039/C9CE01417A |
| format | Article |
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2
) thin nanosheets were investigated. Solvent dependent single-phase formation was observed by powder X-ray diffractometry (XRD), and results were verified with Raman spectroscopy measurements. Particles synthesized with only oleylamine show a mixed-phase, and two other solvent combinations such as oleylamine + oleic acid +
n
-octadecene, and oleylamine + oleic acid, show single-phase 2H–SnS
2
, without phase contamination. Scanning and transmission electron microscopes were used to verify the orbicular and hexagonal shape of synthesized SnS
2
nanosheets. Well-characterized samples were employed to fabricate heterojunction photosensitive diodes using a p-type silicon substrate. Light-responsive measurement results of fabricated diodes indicate that the oleylamine + oleic acid synthesized sample show very high light-sensitivity, and the fill factor value of a fabricated diode is closer to the ideal diode.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/C9CE01417A</identifier><language>eng</language><ispartof>CrystEngComm, 2020-01, Vol.22 (3), p.525-533</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76A-eb33b89f3168dbd7c25db04b5a728e50e7d67c0857e0515b59ee64cecd3b4ea23</citedby><cites>FETCH-LOGICAL-c76A-eb33b89f3168dbd7c25db04b5a728e50e7d67c0857e0515b59ee64cecd3b4ea23</cites><orcidid>0000-0003-1928-3779</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Thangaraju, D.</creatorcontrib><creatorcontrib>Marnadu, R.</creatorcontrib><creatorcontrib>Santhana, V.</creatorcontrib><creatorcontrib>Durairajan, A.</creatorcontrib><creatorcontrib>Kathirvel, P.</creatorcontrib><creatorcontrib>Chandrasekaran, J.</creatorcontrib><creatorcontrib>Jayakumar, S.</creatorcontrib><creatorcontrib>Valente, M. A.</creatorcontrib><creatorcontrib>Greenidge, Darius C.</creatorcontrib><title>Solvent influenced synthesis of single-phase SnS 2 nanosheets for solution-processed photodiode fabrication</title><title>CrystEngComm</title><description>The effect of variant high boiling point solvent combinations in the synthesis and photo-sensing characteristics of tin disulfide (SnS
2
) thin nanosheets were investigated. Solvent dependent single-phase formation was observed by powder X-ray diffractometry (XRD), and results were verified with Raman spectroscopy measurements. Particles synthesized with only oleylamine show a mixed-phase, and two other solvent combinations such as oleylamine + oleic acid +
n
-octadecene, and oleylamine + oleic acid, show single-phase 2H–SnS
2
, without phase contamination. Scanning and transmission electron microscopes were used to verify the orbicular and hexagonal shape of synthesized SnS
2
nanosheets. Well-characterized samples were employed to fabricate heterojunction photosensitive diodes using a p-type silicon substrate. Light-responsive measurement results of fabricated diodes indicate that the oleylamine + oleic acid synthesized sample show very high light-sensitivity, and the fill factor value of a fabricated diode is closer to the ideal diode.</description><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpNkE9LwzAYh4MoOKcXP0HOQjVpmqY9jjKdMPCw3Uv-vLHRmpS8nbBvr0NBT7_f4eE5PITccnbPmWgfurZbM15xtTojC17VddEwIc7__UtyhfjGThBnC_K-S-MnxJmG6McDRAuO4jHOA2BAmjzFEF9HKKZBI9Bd3NGSRh0TDgAzUp8yxTQe5pBiMeVkAfHbMA1pTi4kB9Rrk4PVJ-CaXHg9Itz87pLsH9f7blNsX56eu9W2sKpeFWCEME3rBa8bZ5yypXSGVUZqVTYgGShXK8saqYBJLo1sAerKgnXCVKBLsSR3P1qbE2IG3085fOh87DnrT5X6v0riC7uDXMI</recordid><startdate>20200121</startdate><enddate>20200121</enddate><creator>Thangaraju, D.</creator><creator>Marnadu, R.</creator><creator>Santhana, V.</creator><creator>Durairajan, A.</creator><creator>Kathirvel, P.</creator><creator>Chandrasekaran, J.</creator><creator>Jayakumar, S.</creator><creator>Valente, M. A.</creator><creator>Greenidge, Darius C.</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1928-3779</orcidid></search><sort><creationdate>20200121</creationdate><title>Solvent influenced synthesis of single-phase SnS 2 nanosheets for solution-processed photodiode fabrication</title><author>Thangaraju, D. ; Marnadu, R. ; Santhana, V. ; Durairajan, A. ; Kathirvel, P. ; Chandrasekaran, J. ; Jayakumar, S. ; Valente, M. A. ; Greenidge, Darius C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76A-eb33b89f3168dbd7c25db04b5a728e50e7d67c0857e0515b59ee64cecd3b4ea23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thangaraju, D.</creatorcontrib><creatorcontrib>Marnadu, R.</creatorcontrib><creatorcontrib>Santhana, V.</creatorcontrib><creatorcontrib>Durairajan, A.</creatorcontrib><creatorcontrib>Kathirvel, P.</creatorcontrib><creatorcontrib>Chandrasekaran, J.</creatorcontrib><creatorcontrib>Jayakumar, S.</creatorcontrib><creatorcontrib>Valente, M. A.</creatorcontrib><creatorcontrib>Greenidge, Darius C.</creatorcontrib><collection>CrossRef</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thangaraju, D.</au><au>Marnadu, R.</au><au>Santhana, V.</au><au>Durairajan, A.</au><au>Kathirvel, P.</au><au>Chandrasekaran, J.</au><au>Jayakumar, S.</au><au>Valente, M. A.</au><au>Greenidge, Darius C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent influenced synthesis of single-phase SnS 2 nanosheets for solution-processed photodiode fabrication</atitle><jtitle>CrystEngComm</jtitle><date>2020-01-21</date><risdate>2020</risdate><volume>22</volume><issue>3</issue><spage>525</spage><epage>533</epage><pages>525-533</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The effect of variant high boiling point solvent combinations in the synthesis and photo-sensing characteristics of tin disulfide (SnS
2
) thin nanosheets were investigated. Solvent dependent single-phase formation was observed by powder X-ray diffractometry (XRD), and results were verified with Raman spectroscopy measurements. Particles synthesized with only oleylamine show a mixed-phase, and two other solvent combinations such as oleylamine + oleic acid +
n
-octadecene, and oleylamine + oleic acid, show single-phase 2H–SnS
2
, without phase contamination. Scanning and transmission electron microscopes were used to verify the orbicular and hexagonal shape of synthesized SnS
2
nanosheets. Well-characterized samples were employed to fabricate heterojunction photosensitive diodes using a p-type silicon substrate. Light-responsive measurement results of fabricated diodes indicate that the oleylamine + oleic acid synthesized sample show very high light-sensitivity, and the fill factor value of a fabricated diode is closer to the ideal diode.</abstract><doi>10.1039/C9CE01417A</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-1928-3779</orcidid></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Solvent influenced synthesis of single-phase SnS 2 nanosheets for solution-processed photodiode fabrication |
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