Crown ether alkali metal TCNQ complexes revisited - the impact of smaller cation complexes on their solid-state architecture and properties
The solid-state behaviour of four alkali metal TCNQ complexes: (15-crown-5)LiTCNQ ( 1 ), (15-crown-5)NaTCNQ ( 2 ), (15-crown-5)Li(TCNQ) 2 ·H 2 O ( 3 · H 2 O ) and (15-crown-5)Na(TCNQ) 2 ·H 2 O ( 4 · H 2 O ) has been explored by single crystal X-ray diffraction, infrared (IR), Raman and electron para...
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| Veröffentlicht in: | CrystEngComm 2019-05, Vol.21 (21), p.3273-3279 |
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| creator | Yan, Bingjia Horton, Peter N Russell, Andrea E Wedge, Christopher J Weston, Simon C Grossel, Martin C |
| description | The solid-state behaviour of four alkali metal TCNQ complexes: (15-crown-5)LiTCNQ (
1
), (15-crown-5)NaTCNQ (
2
), (15-crown-5)Li(TCNQ)
2
·H
2
O (
3
·
H
2
O
) and (15-crown-5)Na(TCNQ)
2
·H
2
O (
4
·
H
2
O
) has been explored by single crystal X-ray diffraction, infrared (IR), Raman and electron paramagnetic resonance (EPR) measurements. The presence of a small cation and ionophore leads to subtle changes in behaviour compared with their larger alkali metal analogues and in the hydrated salts water bridges form links between the crown-encapsulated cations and neighbouring TCNQ stacks.
Water molecules play a key structure-organising role in the crystallisation of 15-crown-5 complexes of lithium and sodium TCNQ in the presence of excess TCNQ
0
. |
| doi_str_mv | 10.1039/c9ce00234k |
| format | Article |
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1
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2
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2
O (
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Water molecules play a key structure-organising role in the crystallisation of 15-crown-5 complexes of lithium and sodium TCNQ in the presence of excess TCNQ
0
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1
), (15-crown-5)NaTCNQ (
2
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2
·H
2
O (
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·
H
2
O
) and (15-crown-5)Na(TCNQ)
2
·H
2
O (
4
·
H
2
O
) has been explored by single crystal X-ray diffraction, infrared (IR), Raman and electron paramagnetic resonance (EPR) measurements. The presence of a small cation and ionophore leads to subtle changes in behaviour compared with their larger alkali metal analogues and in the hydrated salts water bridges form links between the crown-encapsulated cations and neighbouring TCNQ stacks.
Water molecules play a key structure-organising role in the crystallisation of 15-crown-5 complexes of lithium and sodium TCNQ in the presence of excess TCNQ
0
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1
), (15-crown-5)NaTCNQ (
2
), (15-crown-5)Li(TCNQ)
2
·H
2
O (
3
·
H
2
O
) and (15-crown-5)Na(TCNQ)
2
·H
2
O (
4
·
H
2
O
) has been explored by single crystal X-ray diffraction, infrared (IR), Raman and electron paramagnetic resonance (EPR) measurements. The presence of a small cation and ionophore leads to subtle changes in behaviour compared with their larger alkali metal analogues and in the hydrated salts water bridges form links between the crown-encapsulated cations and neighbouring TCNQ stacks.
Water molecules play a key structure-organising role in the crystallisation of 15-crown-5 complexes of lithium and sodium TCNQ in the presence of excess TCNQ
0
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| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2019-05, Vol.21 (21), p.3273-3279 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C9CE00234K |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Crown ether alkali metal TCNQ complexes revisited - the impact of smaller cation complexes on their solid-state architecture and properties |
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