Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material
Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group C 2 (...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018-11, Vol.6 (45), p.12240-12244 |
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| container_issue | 45 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 6 |
| creator | Li, Yanqiang Zhao, Sangen Shan, Pai Li, Xianfeng Ding, Qingran Liu, Shuai Wu, Zhenyue Wang, Sasa Li, Lina Luo, Junhua |
| description | Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li
8
NaRb
3
(SO
4
)
6
·2H
2
O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group
C
2 (No. 5). Its single-crystal structure features a three-dimensional framework made up of SO
4
and LiO
4
tetrahedra. Powder second-harmonic generation tests demonstrate that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O is phase-matchable with a second-harmonic generation response of about 0.5 × KH
2
PO
4
. Ultraviolet-visible-near-infrared diffuse reflectance spectra illustrate that the ultraviolet cutoff edge of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may be as low as
λ
< 190 nm. Theoretical calculations reveal that the optical properties of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O are mainly attributed to S–O groups. All these results reveal that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may possess potential use in the deep-ultraviolet nonlinear optics field. We believe that the discoveries in our work will attract scientists’ attention to sulfate systems for their potential as deep-ultraviolet nonlinear optical materials. |
| doi_str_mv | 10.1039/C8TC04361B |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C8TC04361B</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1039_C8TC04361B</sourcerecordid><originalsourceid>FETCH-LOGICAL-c76B-a3decc885d30aff56dcefaa52719bea6cd03073210d268629d4e6fa9f930ea573</originalsourceid><addsrcrecordid>eNpFkE9Lw0AUxBdRsNRe_ATvqEJ0_ySb5GiDWiFY0N48hNfdtxDZJmE3Vfxk3v1kRhSdy8xhGIYfY6eCXwquyquq2FQ8VVosD9hM8owneabSw78s9TFbxPjCJxVCF7qcsee6hQIe8HELCs6e1pDCOWj4_JArkLAGjIDQ0RvEvXc4EliiIdn7MeBr23saoes733aEAfphbA162E290KI_YUcOfaTFr8_Z5vZmU62Sen13X13Xicn1MkFlyZiiyKzi6FymrSGHmMlclFtCbSxXPFdScCunz7K0KWmHpSsVJ8xyNWcXP7Mm9DEGcs0Q2h2G90bw5htM8w9GfQFzWVNn</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Li, Yanqiang ; Zhao, Sangen ; Shan, Pai ; Li, Xianfeng ; Ding, Qingran ; Liu, Shuai ; Wu, Zhenyue ; Wang, Sasa ; Li, Lina ; Luo, Junhua</creator><creatorcontrib>Li, Yanqiang ; Zhao, Sangen ; Shan, Pai ; Li, Xianfeng ; Ding, Qingran ; Liu, Shuai ; Wu, Zhenyue ; Wang, Sasa ; Li, Lina ; Luo, Junhua</creatorcontrib><description>Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li
8
NaRb
3
(SO
4
)
6
·2H
2
O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group
C
2 (No. 5). Its single-crystal structure features a three-dimensional framework made up of SO
4
and LiO
4
tetrahedra. Powder second-harmonic generation tests demonstrate that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O is phase-matchable with a second-harmonic generation response of about 0.5 × KH
2
PO
4
. Ultraviolet-visible-near-infrared diffuse reflectance spectra illustrate that the ultraviolet cutoff edge of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may be as low as
λ
< 190 nm. Theoretical calculations reveal that the optical properties of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O are mainly attributed to S–O groups. All these results reveal that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may possess potential use in the deep-ultraviolet nonlinear optics field. We believe that the discoveries in our work will attract scientists’ attention to sulfate systems for their potential as deep-ultraviolet nonlinear optical materials.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/C8TC04361B</identifier><language>eng</language><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2018-11, Vol.6 (45), p.12240-12244</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76B-a3decc885d30aff56dcefaa52719bea6cd03073210d268629d4e6fa9f930ea573</citedby><cites>FETCH-LOGICAL-c76B-a3decc885d30aff56dcefaa52719bea6cd03073210d268629d4e6fa9f930ea573</cites><orcidid>0000-0002-7673-7979 ; 0000-0002-1190-684X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Yanqiang</creatorcontrib><creatorcontrib>Zhao, Sangen</creatorcontrib><creatorcontrib>Shan, Pai</creatorcontrib><creatorcontrib>Li, Xianfeng</creatorcontrib><creatorcontrib>Ding, Qingran</creatorcontrib><creatorcontrib>Liu, Shuai</creatorcontrib><creatorcontrib>Wu, Zhenyue</creatorcontrib><creatorcontrib>Wang, Sasa</creatorcontrib><creatorcontrib>Li, Lina</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><title>Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li
8
NaRb
3
(SO
4
)
6
·2H
2
O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group
C
2 (No. 5). Its single-crystal structure features a three-dimensional framework made up of SO
4
and LiO
4
tetrahedra. Powder second-harmonic generation tests demonstrate that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O is phase-matchable with a second-harmonic generation response of about 0.5 × KH
2
PO
4
. Ultraviolet-visible-near-infrared diffuse reflectance spectra illustrate that the ultraviolet cutoff edge of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may be as low as
λ
< 190 nm. Theoretical calculations reveal that the optical properties of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O are mainly attributed to S–O groups. All these results reveal that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may possess potential use in the deep-ultraviolet nonlinear optics field. We believe that the discoveries in our work will attract scientists’ attention to sulfate systems for their potential as deep-ultraviolet nonlinear optical materials.</description><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkE9Lw0AUxBdRsNRe_ATvqEJ0_ySb5GiDWiFY0N48hNfdtxDZJmE3Vfxk3v1kRhSdy8xhGIYfY6eCXwquyquq2FQ8VVosD9hM8owneabSw78s9TFbxPjCJxVCF7qcsee6hQIe8HELCs6e1pDCOWj4_JArkLAGjIDQ0RvEvXc4EliiIdn7MeBr23saoes733aEAfphbA162E290KI_YUcOfaTFr8_Z5vZmU62Sen13X13Xicn1MkFlyZiiyKzi6FymrSGHmMlclFtCbSxXPFdScCunz7K0KWmHpSsVJ8xyNWcXP7Mm9DEGcs0Q2h2G90bw5htM8w9GfQFzWVNn</recordid><startdate>20181122</startdate><enddate>20181122</enddate><creator>Li, Yanqiang</creator><creator>Zhao, Sangen</creator><creator>Shan, Pai</creator><creator>Li, Xianfeng</creator><creator>Ding, Qingran</creator><creator>Liu, Shuai</creator><creator>Wu, Zhenyue</creator><creator>Wang, Sasa</creator><creator>Li, Lina</creator><creator>Luo, Junhua</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7673-7979</orcidid><orcidid>https://orcid.org/0000-0002-1190-684X</orcidid></search><sort><creationdate>20181122</creationdate><title>Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material</title><author>Li, Yanqiang ; Zhao, Sangen ; Shan, Pai ; Li, Xianfeng ; Ding, Qingran ; Liu, Shuai ; Wu, Zhenyue ; Wang, Sasa ; Li, Lina ; Luo, Junhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76B-a3decc885d30aff56dcefaa52719bea6cd03073210d268629d4e6fa9f930ea573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yanqiang</creatorcontrib><creatorcontrib>Zhao, Sangen</creatorcontrib><creatorcontrib>Shan, Pai</creatorcontrib><creatorcontrib>Li, Xianfeng</creatorcontrib><creatorcontrib>Ding, Qingran</creatorcontrib><creatorcontrib>Liu, Shuai</creatorcontrib><creatorcontrib>Wu, Zhenyue</creatorcontrib><creatorcontrib>Wang, Sasa</creatorcontrib><creatorcontrib>Li, Lina</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yanqiang</au><au>Zhao, Sangen</au><au>Shan, Pai</au><au>Li, Xianfeng</au><au>Ding, Qingran</au><au>Liu, Shuai</au><au>Wu, Zhenyue</au><au>Wang, Sasa</au><au>Li, Lina</au><au>Luo, Junhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2018-11-22</date><risdate>2018</risdate><volume>6</volume><issue>45</issue><spage>12240</spage><epage>12244</epage><pages>12240-12244</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li
8
NaRb
3
(SO
4
)
6
·2H
2
O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group
C
2 (No. 5). Its single-crystal structure features a three-dimensional framework made up of SO
4
and LiO
4
tetrahedra. Powder second-harmonic generation tests demonstrate that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O is phase-matchable with a second-harmonic generation response of about 0.5 × KH
2
PO
4
. Ultraviolet-visible-near-infrared diffuse reflectance spectra illustrate that the ultraviolet cutoff edge of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may be as low as
λ
< 190 nm. Theoretical calculations reveal that the optical properties of Li
8
NaRb
3
(SO
4
)
6
·2H
2
O are mainly attributed to S–O groups. All these results reveal that Li
8
NaRb
3
(SO
4
)
6
·2H
2
O may possess potential use in the deep-ultraviolet nonlinear optics field. We believe that the discoveries in our work will attract scientists’ attention to sulfate systems for their potential as deep-ultraviolet nonlinear optical materials.</abstract><doi>10.1039/C8TC04361B</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7673-7979</orcidid><orcidid>https://orcid.org/0000-0002-1190-684X</orcidid></addata></record> |
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| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2018-11, Vol.6 (45), p.12240-12244 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8TC04361B |
| source | Royal Society Of Chemistry Journals 2008- |
| title | Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material |
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