White-light emission in a chiral one-dimensional organic-inorganic hybrid perovskite
Recently, white-light emissions arising from self-trapped excitons in a distorted lattice have attracted significant attention in organic-inorganic hybrid perovskites. Although exciton self-trapping is reported to be easier in lower dimensional structures, one-dimensional organic-inorganic perovskit...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018, Vol.6 (22), p.633-637 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
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| creator | Peng, Yu Yao, Yunpeng Li, Lina Wu, Zhenyue Wang, Sasa Luo, Junhua |
| description | Recently, white-light emissions arising from self-trapped excitons in a distorted lattice have attracted significant attention in organic-inorganic hybrid perovskites. Although exciton self-trapping is reported to be easier in lower dimensional structures, one-dimensional organic-inorganic perovskites with white-light emission are rare. Herein, we report a single-component white-light emissive hybrid perovskite, C
5
H
14
N
2
PbCl
4
·H
2
O (
1
), which adopts a distinct quantum-wire structure formed by edge-shared highly distorted lead chloride octahedra. Notably,
1
shows a color rendering index as high as 93.9, which almost falls around the highest value for hybrid perovskite white-light emissive materials. In addition,
1
is nonlinear and has circularly polarized optical activity induced by the incorporation of pure enantiomeric organic cations. The combination of white-light emission and chirality may pave the way for the design of new white-light emission organic-inorganic perovskites for multifunctional applications.
A chiral one-dimensional organic-inorganic hybrid perovskite exhibits white-light emission with ultrahigh CRI. |
| doi_str_mv | 10.1039/c8tc01150h |
| format | Article |
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5
H
14
N
2
PbCl
4
·H
2
O (
1
), which adopts a distinct quantum-wire structure formed by edge-shared highly distorted lead chloride octahedra. Notably,
1
shows a color rendering index as high as 93.9, which almost falls around the highest value for hybrid perovskite white-light emissive materials. In addition,
1
is nonlinear and has circularly polarized optical activity induced by the incorporation of pure enantiomeric organic cations. The combination of white-light emission and chirality may pave the way for the design of new white-light emission organic-inorganic perovskites for multifunctional applications.
A chiral one-dimensional organic-inorganic hybrid perovskite exhibits white-light emission with ultrahigh CRI.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/c8tc01150h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chirality ; Diodes ; Excitons ; Lead chlorides ; Light ; Light emission ; Optical activity ; Perovskites ; White light</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2018, Vol.6 (22), p.633-637</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-70a3f13dfae0eda7cd3b317a68ef7675c694182241a1593f8f1e92f3349fe3983</citedby><cites>FETCH-LOGICAL-c384t-70a3f13dfae0eda7cd3b317a68ef7675c694182241a1593f8f1e92f3349fe3983</cites><orcidid>0000-0002-7673-7979</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4009,27902,27903,27904</link.rule.ids></links><search><creatorcontrib>Peng, Yu</creatorcontrib><creatorcontrib>Yao, Yunpeng</creatorcontrib><creatorcontrib>Li, Lina</creatorcontrib><creatorcontrib>Wu, Zhenyue</creatorcontrib><creatorcontrib>Wang, Sasa</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><title>White-light emission in a chiral one-dimensional organic-inorganic hybrid perovskite</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>Recently, white-light emissions arising from self-trapped excitons in a distorted lattice have attracted significant attention in organic-inorganic hybrid perovskites. Although exciton self-trapping is reported to be easier in lower dimensional structures, one-dimensional organic-inorganic perovskites with white-light emission are rare. Herein, we report a single-component white-light emissive hybrid perovskite, C
5
H
14
N
2
PbCl
4
·H
2
O (
1
), which adopts a distinct quantum-wire structure formed by edge-shared highly distorted lead chloride octahedra. Notably,
1
shows a color rendering index as high as 93.9, which almost falls around the highest value for hybrid perovskite white-light emissive materials. In addition,
1
is nonlinear and has circularly polarized optical activity induced by the incorporation of pure enantiomeric organic cations. The combination of white-light emission and chirality may pave the way for the design of new white-light emission organic-inorganic perovskites for multifunctional applications.
A chiral one-dimensional organic-inorganic hybrid perovskite exhibits white-light emission with ultrahigh CRI.</description><subject>Chirality</subject><subject>Diodes</subject><subject>Excitons</subject><subject>Lead chlorides</subject><subject>Light</subject><subject>Light emission</subject><subject>Optical activity</subject><subject>Perovskites</subject><subject>White light</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkNFLwzAQxoMoOOZefBcCvgnRpNc2yaMU3YSBLxMfS5Ze1sytnUkn7L-3dWPey33H_fi4-wi5FfxRcNBPVnWWC5Hx-oKMEp5xJjNIL886ya_JJMY170uJXOV6RBafte-Qbfyq7ihufYy-bahvqKG29sFsaNsgq_wWm2EzzGFlGm-Zb06K1odl8BXdYWh_4ldvd0OunNlEnJz6mHy8viyKGZu_T9-K5zmzoNKOSW7ACaicQY6VkbaCJQhpcoVO5jKzuU6FSpJUGJFpcMoJ1IkDSLVD0ArG5P7ouwvt9x5jV67bfeiPjOXwshYZgOyphyNlQxtjQFfugt-acCgFL4fgykItir_gZj18d4RDtGfuP1j4BQv5akI</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Peng, Yu</creator><creator>Yao, Yunpeng</creator><creator>Li, Lina</creator><creator>Wu, Zhenyue</creator><creator>Wang, Sasa</creator><creator>Luo, Junhua</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7673-7979</orcidid></search><sort><creationdate>2018</creationdate><title>White-light emission in a chiral one-dimensional organic-inorganic hybrid perovskite</title><author>Peng, Yu ; Yao, Yunpeng ; Li, Lina ; Wu, Zhenyue ; Wang, Sasa ; Luo, Junhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-70a3f13dfae0eda7cd3b317a68ef7675c694182241a1593f8f1e92f3349fe3983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chirality</topic><topic>Diodes</topic><topic>Excitons</topic><topic>Lead chlorides</topic><topic>Light</topic><topic>Light emission</topic><topic>Optical activity</topic><topic>Perovskites</topic><topic>White light</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Yu</creatorcontrib><creatorcontrib>Yao, Yunpeng</creatorcontrib><creatorcontrib>Li, Lina</creatorcontrib><creatorcontrib>Wu, Zhenyue</creatorcontrib><creatorcontrib>Wang, Sasa</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Yu</au><au>Yao, Yunpeng</au><au>Li, Lina</au><au>Wu, Zhenyue</au><au>Wang, Sasa</au><au>Luo, Junhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>White-light emission in a chiral one-dimensional organic-inorganic hybrid perovskite</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2018</date><risdate>2018</risdate><volume>6</volume><issue>22</issue><spage>633</spage><epage>637</epage><pages>633-637</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Recently, white-light emissions arising from self-trapped excitons in a distorted lattice have attracted significant attention in organic-inorganic hybrid perovskites. Although exciton self-trapping is reported to be easier in lower dimensional structures, one-dimensional organic-inorganic perovskites with white-light emission are rare. Herein, we report a single-component white-light emissive hybrid perovskite, C
5
H
14
N
2
PbCl
4
·H
2
O (
1
), which adopts a distinct quantum-wire structure formed by edge-shared highly distorted lead chloride octahedra. Notably,
1
shows a color rendering index as high as 93.9, which almost falls around the highest value for hybrid perovskite white-light emissive materials. In addition,
1
is nonlinear and has circularly polarized optical activity induced by the incorporation of pure enantiomeric organic cations. The combination of white-light emission and chirality may pave the way for the design of new white-light emission organic-inorganic perovskites for multifunctional applications.
A chiral one-dimensional organic-inorganic hybrid perovskite exhibits white-light emission with ultrahigh CRI.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8tc01150h</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7673-7979</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2018, Vol.6 (22), p.633-637 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8TC01150H |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Chirality Diodes Excitons Lead chlorides Light Light emission Optical activity Perovskites White light |
| title | White-light emission in a chiral one-dimensional organic-inorganic hybrid perovskite |
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